Academic Program [Oral A]

09. Coordination Chemistry, Organometallic Chemistry » Oral A

[K502-3am] 09. Coordination Chemistry, Organometallic Chemistry

Fri. Mar 24, 2023 9:00 AM - 11:20 AM K502 (K502, Lecture Hall Bldg. [5F])

Chair: Kohei Takahashi, Yutaka Saga

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9:00 AM - 9:10 AM

[K502-3am-01] Immobilization of Ru-NHC complexes as oxidation catalysts on solid surface toward improvement of their durability

^○Haruka Seta¹ (1. University of Tsukuba)

[Lang.] Japanese

9:10 AM - 9:20 AM

[K502-3am-02] Photocatalytic substrate oxidation with a heteroaromatic ligand bound to ruthenium complex using dioxygen as a terminal oxidant

^○Taichiro Nishi¹, Tomoya Ishizuka¹, Nanase Namura¹, Takahiko Kojima¹ (1. University of Tsukuba)

[Lang.] Japanese

9:20 AM - 9:30 AM

[K502-3am-03] Synthesis and Photocatalytic Property of Organic–Inorganic Hybrid Ruthenium(II) Complexes with a Linked Rotaxane Structure

^○Qichun JIANG¹, Yuka IMANISHI², Hiromichi MIYAGISHI², Nobutaka YOSHIMURA⁴, Atsushi KOBAYASHI³, Hiroshi MASAI², Shin-ya TAKIZAWA², Tomohiro IWAI², Jun TERAO² (1. Graduate School of Science, The University of Tokyo, 2. Graduate School of Arts and Sciences, The University of Tokyo, 3. Faculty of Science, Hokkaido University, 4. Graduate School of Chemical Sciences and Engineering, Hokkaido University)

[Lang.] English

9:30 AM - 9:40 AM

[K502-3am-04] Reactivity of Diruthenium Bis(μ-ethylidyne) Complex Possessing a Dual Aromatic Ru₂C₂ Core

^○Naoya Noguchi¹, Toshiro Takao¹ (1. Tokyo Institute of Technology)

[Lang.] Japanese

9:40 AM - 9:50 AM

[K502-3am-05] Preparation and Property of a 50-electron Triangular Ruthenium Cluster Containing a µ₃–Methylidyne Ligand

^○Shu Egawa¹, Toshiro Takao¹ (1. Tokyo Institute of Technology)

[Lang.] Japanese

9:50 AM - 10:00 AM

[K502-3am-06] Syntheses and Properties of Triruthenium Polyhydrido Complexes Composed of 1, 2, 3, 4, 5-pentamethylcyclopentadienyl and p-Cymene Ruthenium Units

^○Yuji Shibata¹, Toshiro Takao¹, Takuya Kosukegawa¹ (1. Tokyo Institute of Technology)

[Lang.] Japanese

10:00 AM - 10:10 AM

[K502-3am-07] Substituent Effect on Light-Driven Organic Hydride Storage Reaction of NAD⁺-Type Ru(II) Complexes

^○Kazuki SHIBAHARA¹, Kiyoshi TSUGE¹, Hideki OHTSU¹ (1. Grad. Sch. of Sci. and Eng., Univ. of Toyama)

[Lang.] Japanese

Break (10:10 AM - 10:20 AM)

10:20 AM - 10:30 AM

[K502-3am-08] Visible light driven carbon dioxide reduction in water catalyzed by biologically relevant metal complexes

^○Minoru Hayakawa¹, Kaito Sasaki², Yu Hoshino², Hisashi Shimakoshi² (1. Faculty of Engineering, Kyushu University, 2. Graduate School of Engineering, Kyushu University)

[Lang.] Japanese

10:30 AM - 10:40 AM

[K502-3am-09] Photocatalytic Water Oxidation by Carbon Nitride Modified with a Cobalt Polymolybdate Catalyst

^○Yuki Tomita¹, Natsuki Taira¹, Hironobu Ozawa¹, Ken Sakai¹ (1. Dept. Chem. Kyushu Univ.)

[Lang.] Japanese

10:40 AM - 10:50 AM

[K502-3am-10] Co Porphyrin Catalyst Modified TiO₂ Cathode Toward Low Overpotential CO₂ Reduction

^○Yuki Goya¹, Ken Sakai¹, Hironobu Ozawa¹ (1. Dept. Chem. Kyushu Univ.)

[Lang.] Japanese

10:50 AM - 11:00 AM

[K502-3am-11] Syntheses and Reactivities of Rhodium-Palladium Bimetallic Complexes Utilizing 6,6”-Bisphosphinoterpyridine as a Scaffold for the Metal-Metal Bond

^○Kengo Tanaka¹, Nobuharu Iwasawa¹, Jun Takaya¹ (1. Tokyo Institute of Technology)

[Lang.] Japanese

11:00 AM - 11:10 AM

[K502-3am-12] Reactivity of Heptadentated Schiff-base Ligated Cerium(IV) Enolate Complexes with N-Oxyl and Phenoxy Radicals

^○Daisuke Senga¹, Kazushi Mashima², Hayato Tsurugi¹ (1. Graduate School of Engineering Science, Osaka University, 2. Graduate School of Pharmaceutical Sciences, Osaka University)

[Lang.] Japanese

11:10 AM - 11:20 AM

[K502-3am-13] Hydroaminoalkylation of Allyl Ethers with N-Methylaniline Catalyzed by Half-titanocene Complexes Activated with Organometallic Reagents

^○Tokiya Teraishi¹, Yu Kuroda¹, Mariko Inoue¹, Hayato Tsurugi¹, Kazushi Mashima² (1. Graduate School of Engineering Science, Osaka University, 2. Graduate School of Pharmaceutical Sciences, Osaka University)

[Lang.] Japanese

Session information

[K502-3am] 09. Coordination Chemistry, Organometallic Chemistry

[K502-3am-01] Immobilization of Ru-NHC complexes as oxidation catalysts on solid surface toward improvement of their durability

[K502-3am-02] Photocatalytic substrate oxidation with a heteroaromatic ligand bound to ruthenium complex using dioxygen as a terminal oxidant

[K502-3am-03] Synthesis and Photocatalytic Property of Organic–Inorganic Hybrid Ruthenium(II) Complexes with a Linked Rotaxane Structure

[K502-3am-04] Reactivity of Diruthenium Bis(μ-ethylidyne) Complex Possessing a Dual Aromatic Ru₂C₂ Core

[K502-3am-05] Preparation and Property of a 50-electron Triangular Ruthenium Cluster Containing a µ₃–Methylidyne Ligand

[K502-3am-06] Syntheses and Properties of Triruthenium Polyhydrido Complexes Composed of 1, 2, 3, 4, 5-pentamethylcyclopentadienyl and p-Cymene Ruthenium Units

[K502-3am-07] Substituent Effect on Light-Driven Organic Hydride Storage Reaction of NAD⁺-Type Ru(II) Complexes

[K502-3am-08] Visible light driven carbon dioxide reduction in water catalyzed by biologically relevant metal complexes

[K502-3am-09] Photocatalytic Water Oxidation by Carbon Nitride Modified with a Cobalt Polymolybdate Catalyst

[K502-3am-10] Co Porphyrin Catalyst Modified TiO₂ Cathode Toward Low Overpotential CO₂ Reduction

[K502-3am-11] Syntheses and Reactivities of Rhodium-Palladium Bimetallic Complexes Utilizing 6,6”-Bisphosphinoterpyridine as a Scaffold for the Metal-Metal Bond

[K502-3am-12] Reactivity of Heptadentated Schiff-base Ligated Cerium(IV) Enolate Complexes with N-Oxyl and Phenoxy Radicals

[K502-3am-13] Hydroaminoalkylation of Allyl Ethers with N-Methylaniline Catalyzed by Half-titanocene Complexes Activated with Organometallic Reagents

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