Academic Program [Oral A]

15. Organic Chemistry -Aliphatic and Alicyclic Compounds, and New Synthetic Technology- » Oral A

[K705-3am] 15. Organic Chemistry -Aliphatic and Alicyclic Compounds, and New Synthetic Technology-

Fri. Mar 24, 2023 9:00 AM - 11:40 AM K705 (K705, Lecture Hall Bldg. [7F])

Chair: Haruki Mizoguchi, Shuhei Kusumoto

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9:00 AM - 9:10 AM

[K705-3am-01] Chiral Iron(III)-catalyzed Enantioselective Oxidative [3+2] Cycloaddition of Phenols with Anethole

^○Kohsuke Nomura¹, Shuhei Ohmura¹, Kazuaki Ishihara¹ (1. The Univ. of Nagoya)

[Lang.] Japanese

9:10 AM - 9:20 AM

[K705-3am-02] Site-, Regio-, and Enantioselective [4+2] Cycloaddition of Oxidatively Generated ortho-Quinone Methides

^○Takaharu Morino¹, Takehiro Kato¹, Muhammet Uyanik¹, Kazuaki Ishihara¹ (1. Nagoya University)

[Lang.] Japanese

9:20 AM - 9:30 AM

[K705-3am-03] Cu/I Hybrid Catalysis for Enantioselective Aerobic Oxidative γ-Lactonization of δ-Oxocarboxylic Acids

^○Shunki Matsuyama¹, Soki Ihara¹, Takehiro Kato¹, Muhammet Uyanik¹, Kazuaki Ishihara¹ (1. Nagoya University)

[Lang.] Japanese

9:30 AM - 9:40 AM

[K705-3am-04] Enantioselective Aromatic Claisen Rearrangemnt of Allyl 2-Naphthyl Ethers Catalyzed by π–Cu(II) complexes

^○Kazuaki Ishihara¹, Lu Yao¹, Kazuki Takeda¹, Kaori Ando², Natsuhisa Oka² (1. Nagoya University, 2. Gifu University)

[Lang.] English

9:40 AM - 9:50 AM

[K705-3am-05] Carbon–carbon bond cleavage in alcoholysis of acetophenone mediated by europium complexes

^○Haruki Takarai¹, Soichiro Kohara¹, Shuhei Kusumoto¹, Kyoko Nozaki¹ (1. The University of Tokyo)

[Lang.] Japanese

9:50 AM - 10:00 AM

[K705-3am-06] Asymmetric iodoetherification using chiral multinuclear Zn bis(aminoimino)binaphthoxide complex with phenol substrates as nucleophiles

^○Yuki Namba¹, Takayoshi Arai¹ (1. Chiba university)

[Lang.] Japanese

10:00 AM - 10:10 AM

[K705-3am-07] Asymmetric Direct Mannich Reaction of α-Ketoesters Catalyzed by Sulfonamide-substituted Chiral Lewis Acid Catalyst

^○Takeru Abe¹, Haruki Mizoguchi¹, Akira Sakakura¹ (1. The Univ. of Okayama)

[Lang.] Japanese

10:10 AM - 10:20 AM

[K705-3am-08] One-pot catalytic reactions of phosphite diesters toward the synthesis of oligonucleotides

^○Akira Matsunaga¹, Dario Mrdović¹, Yuki Saito¹, Shū Kobayashi¹ (1. the University of Tokyo)

[Lang.] Japanese

Break (10:20 AM - 10:30 AM)

10:30 AM - 10:40 AM

[K705-3am-09] Design of Chiral Iron(III) Catalyst for Enantioselective Radical Cation [4+2] Cycloaddition of α,β-Unsaturated Carboxylic Acid Derivatives

^○Hayato Akao¹, Kei Katagiri¹, Shuhei Ohmura¹ (1. Nagoya University)

[Lang.] Japanese

10:40 AM - 10:50 AM

[K705-3am-10] Silver-catalyzed CO₂ Incorporation into Propargylic Amides

^○Seiya Uema¹, Tohru Yamada¹ (1. Keio University)

[Lang.] Japanese

10:50 AM - 11:00 AM

[K705-3am-11] Silver Catalyzed Formylation of Amines using Carbon Dioxide

^○Kenshiro Sekine¹, Ryotaro Aoshima¹, Seiya Uema¹, Kodai Saito², Tohru Yamada¹ (1. Keio University, 2. Hokkaido University of Education)

[Lang.] Japanese

11:00 AM - 11:10 AM

[K705-3am-12] Palladium-Catalyzed Intramolecular Allylation of Aldehydes through in Situ Generation of Allylsilanes

^○Haruya Hirano¹, Ayumu Natsubori¹, Yoshikazu Horino¹ (1. Chitose Inst. Sci. Tech.)

[Lang.] Japanese

11:10 AM - 11:20 AM

[K705-3am-13] Development and Catalytic Application of Novel Chiral Halonium Salts with Hydroxy Group

^○Shunki Tanaka¹, Yasushi Yoshida¹, Takashi Mino¹ (1. Faculty of Engineering, Chiba University)

[Lang.] Japanese

11:20 AM - 11:30 AM

[K705-3am-14] Decarboxylative Cyclization of Cyclic Carbonates for Stereoselective Preparation of Bicyclo[3.3.0]octane Skeleton

Risa Yamaguchi¹, ^○Tsukasa Amemiya¹, Yoichi Dokai¹, Tohru Yamada¹, Kodai Saito² (1. Keio University, 2. Hokkaido University of Education)

[Lang.] Japanese

11:30 AM - 11:40 AM

[K705-3am-15] Decarboxylative Coupling Reaction of Cyclic Carbonates and Ketene Silyl Acetals

^○Yoichi Dokai¹, Aoi Fujioka¹, Kodai Saito², Tohru Yamada¹ (1. Keio Univ., 2. Hokkaido Univ. of Education)

[Lang.] Japanese

Session information

[K705-3am] 15. Organic Chemistry -Aliphatic and Alicyclic Compounds, and New Synthetic Technology-

[K705-3am-01] Chiral Iron(III)-catalyzed Enantioselective Oxidative [3+2] Cycloaddition of Phenols with Anethole

[K705-3am-02] Site-, Regio-, and Enantioselective [4+2] Cycloaddition of Oxidatively Generated ortho-Quinone Methides

[K705-3am-03] Cu/I Hybrid Catalysis for Enantioselective Aerobic Oxidative γ-Lactonization of δ-Oxocarboxylic Acids

[K705-3am-04] Enantioselective Aromatic Claisen Rearrangemnt of Allyl 2-Naphthyl Ethers Catalyzed by π–Cu(II) complexes

[K705-3am-05] Carbon–carbon bond cleavage in alcoholysis of acetophenone mediated by europium complexes

[K705-3am-06] Asymmetric iodoetherification using chiral multinuclear Zn bis(aminoimino)binaphthoxide complex with phenol substrates as nucleophiles

[K705-3am-07] Asymmetric Direct Mannich Reaction of α-Ketoesters Catalyzed by Sulfonamide-substituted Chiral Lewis Acid Catalyst

[K705-3am-08] One-pot catalytic reactions of phosphite diesters toward the synthesis of oligonucleotides

[K705-3am-09] Design of Chiral Iron(III) Catalyst for Enantioselective Radical Cation [4+2] Cycloaddition of α,β-Unsaturated Carboxylic Acid Derivatives

[K705-3am-10] Silver-catalyzed CO₂ Incorporation into Propargylic Amides

[K705-3am-11] Silver Catalyzed Formylation of Amines using Carbon Dioxide

[K705-3am-12] Palladium-Catalyzed Intramolecular Allylation of Aldehydes through in Situ Generation of Allylsilanes

[K705-3am-13] Development and Catalytic Application of Novel Chiral Halonium Salts with Hydroxy Group

[K705-3am-14] Decarboxylative Cyclization of Cyclic Carbonates for Stereoselective Preparation of Bicyclo[3.3.0]octane Skeleton

[K705-3am-15] Decarboxylative Coupling Reaction of Cyclic Carbonates and Ketene Silyl Acetals

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