Academic Program [Oral A]

10. Organic Chemistry -Organometallic Compounds- » Oral A

[K406-4am] 10. Organic Chemistry -Organometallic Compounds-

Sat. Mar 25, 2023 9:00 AM - 11:40 AM K406 (K406, Lecture Hall Bldg. [4F])

Chair: Itaru Nakamura, Kohei Fuchibe

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9:00 AM - 9:10 AM

[K406-4am-01] Copper-catalyzed anti-selective disilylative cyclization of internal alkynes having a silyl group

^○Ryosuke Kondo¹, Hirokazu Moniwa¹, Ryo Shintani¹ (1. Graduate School of Engineering Science, Osaka University)

[Lang.] Japanese

9:10 AM - 9:20 AM

[K406-4am-02] Stereospecific hydroxylation of chiral tert-alkyl halides using water

^○Ichikaze Iwashita¹ (1. Yamaguchi university)

[Lang.] Japanese

9:20 AM - 9:30 AM

[K406-4am-03] Copper-catalyzed synthesis of five-membered nitrogen-containing heterocycles

^○Kota Hashimoto¹, Daiki Higuchi¹, Satoshi Matsubara², Kei Murakami¹ (1. Kwansei Gakuin University, 2. Nagoya University)

[Lang.] Japanese

9:30 AM - 9:40 AM

[K406-4am-04] Oxidative cleavage of ethylenediamine derivatives

^○Daiki Higuchi¹, Satoshi Matsubara², Kei Murakami¹ (1. Kwansei Gakuin University, 2. Nagoya University)

[Lang.] Japanese

9:40 AM - 9:50 AM

[K406-4am-05] Cu-catalyzed Boracarboxylation of Allenes Using Carbon Dioxide

^○Go YAMAGIWA¹, Katsuya Kiyohara, Tetsuaki Fujihara¹ (1. Graduate School of Engineering, Kyoto University)

[Lang.] Japanese

9:50 AM - 10:00 AM

[K406-4am-06] Synthesis and Coordination Behavior of Anthraquinodimethane-bridged Tetrapyridyl Ligand

^○Yuta Sotome¹, Takahiro Iwamoto¹, Youichi Ishii¹ (1. The Univ. of Chuo)

[Lang.] Japanese

10:00 AM - 10:10 AM

[K406-4am-07] Development of fluoroalkylation reaction using the copper complex

^○Keisuke Nozaki¹, Ryohei Doi¹, Nobutaka Mito¹, Sensuke Ogoshi¹ (1. Osaka University)

[Lang.] Japanese

Break (10:10 AM - 10:30 AM)

10:30 AM - 10:40 AM

[K406-4am-08] Development of carbon-sulfur bond forming reaction using disulfides and norbornene

^○Reo Ikeda¹, Kento Ishida¹, Yohei Ogiwara¹, Norio Sakai¹ (1. Tokyo University of Science)

[Lang.] Japanese

10:40 AM - 10:50 AM

[K406-4am-09] Gold-Catalyzed [2 + 4] Cycloaddition of Difluoroallenes with α,β-Unsaturated Ketones: Regioselective Synthesis of Ring-Fluorinated 3,4-Dihydro-2H-pyrans

^○Leo Eto¹, Daisuke Miyazaki¹, Kohei Fuchibe¹, Junji Ichikawa¹ (1. Univ. of Tsukuba)

[Lang.] Japanese

10:50 AM - 11:00 AM

[K406-4am-10] Synthesis of Chiral 1,4-Dicarbonyl Compounds through Photoinduced Copper-Catalyzed Asymmetric Conjugate Addition of Acylsilanes

^○Yusuke Ueda¹, Aiko Sueki¹, Yusuke Masuda^1,2, Masaya Sawamura^1,2 (1. Hokkaido Universuty Faculty of Science, 2. WPI-ICReDD)

[Lang.] Japanese

11:00 AM - 11:10 AM

[K406-4am-11] Copper-Catalyzed Defluorinative [3 + 2] Annulation of Nitrile Imines with Difluorovinylzinc Complexes: Synthesis of Fluoropyrazoles

^○Kota Ichikawa¹, Takeshi Fujita¹, Junji Ichikawa¹ (1. Univ. of Tsukuba)

[Lang.] Japanese

11:10 AM - 11:20 AM

[K406-4am-12] Development of Asymmetric Bromo- and Chloroimidation of Alkylidenemalononitrile Catalyzed by Chiral Bis(imidazolidine) Pyridine

^○Takaaki Saito¹, Takayoshi Arai¹ (1. Chiba University)

[Lang.] Japanese

11:20 AM - 11:30 AM

[K406-4am-13] Cu-Catalyzed Double C(sp³)-H Functionalization of Ethylarenes to Form Arylethanolamines

^○Naoki Oku¹, Masahiro Murakami¹, Tomoya Miura² (1. Kyoto University , 2. Okayama University)

[Lang.] Japanese

11:30 AM - 11:40 AM

[K406-4am-14] Enantioselective Synthesis of ortho-Quinol Imines by Catalytic [1,3]-Rearrangement

^○Kazuki Masukawa¹, Masahiro Terada¹, Itaru Nakamura¹ (1. Tohoku Unuversity)

[Lang.] Japanese

Session information

[K406-4am] 10. Organic Chemistry -Organometallic Compounds-

[K406-4am-01] Copper-catalyzed anti-selective disilylative cyclization of internal alkynes having a silyl group

[K406-4am-02] Stereospecific hydroxylation of chiral tert-alkyl halides using water

[K406-4am-03] Copper-catalyzed synthesis of five-membered nitrogen-containing heterocycles

[K406-4am-04] Oxidative cleavage of ethylenediamine derivatives

[K406-4am-05] Cu-catalyzed Boracarboxylation of Allenes Using Carbon Dioxide

[K406-4am-06] Synthesis and Coordination Behavior of Anthraquinodimethane-bridged Tetrapyridyl Ligand

[K406-4am-07] Development of fluoroalkylation reaction using the copper complex

[K406-4am-08] Development of carbon-sulfur bond forming reaction using disulfides and norbornene

[K406-4am-09] Gold-Catalyzed [2 + 4] Cycloaddition of Difluoroallenes with α,β-Unsaturated Ketones: Regioselective Synthesis of Ring-Fluorinated 3,4-Dihydro-2H-pyrans

[K406-4am-10] Synthesis of Chiral 1,4-Dicarbonyl Compounds through Photoinduced Copper-Catalyzed Asymmetric Conjugate Addition of Acylsilanes

[K406-4am-11] Copper-Catalyzed Defluorinative [3 + 2] Annulation of Nitrile Imines with Difluorovinylzinc Complexes: Synthesis of Fluoropyrazoles

[K406-4am-12] Development of Asymmetric Bromo- and Chloroimidation of Alkylidenemalononitrile Catalyzed by Chiral Bis(imidazolidine) Pyridine

[K406-4am-13] Cu-Catalyzed Double C(sp³)-H Functionalization of Ethylarenes to Form Arylethanolamines

[K406-4am-14] Enantioselective Synthesis of ortho-Quinol Imines by Catalytic [1,3]-Rearrangement

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