Academic Program [Oral A]

10. Organic Chemistry -Organometallic Compounds- » Oral A

[K406-4pm] 10. Organic Chemistry -Organometallic Compounds-

Sat. Mar 25, 2023 1:30 PM - 3:40 PM K406 (K406, Lecture Hall Bldg. [4F])

Chair: Gen Onodera, Sobi Asako

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1:30 PM - 1:40 PM

[K406-4pm-01] Molybdenum-Catalyzed Directed Activation of Aromatic C–Cl and C–F Bonds

^○Somsuvra Banerjee¹, Naoki Matsushita¹, Sobi Asako¹, Laurean Ilies¹ (1. RIKEN)

[Lang.] English

1:40 PM - 1:50 PM

[K406-4pm-02] Solution Synthesis of DMF-stabilized Manganese Nanoparticles Catalyst for Hydrosilylation

^○Nobuki Katayama¹, Kazuki Tabaru¹, Tatsuki Nagata¹, Miku Yamaguchi¹, Takeyuki Suzuki², Takashi Toyai³, Yuan Jing³, Zen Maeno⁴, Ken-ichi Shimizu³, Yasushi Obora¹ (1. Fac. Chem. Matl. & Bioeng., Kansai Univ., 2. SANKEN, Osaka Univ., 3. Institute for Catalysis, Hokkaido Univ., 4. Kogakuin Univ.)

[Lang.] Japanese

1:50 PM - 2:00 PM

[K406-4pm-03] Mo-Catalyzed Enantioselective Metathesis Dimerization/Desymmetrization of C_s-Symmetric Divinylferrocenes

^○Kakeru Masaoka¹, Haruka Taue¹, Tatsuya Higaki², Yasuhiro Ohki², Masamichi Ogasawara¹ (1. Tokushima University, 2. Kyoto University)

[Lang.] Japanese

2:00 PM - 2:10 PM

[K406-4pm-04] Controlling Stereoselectivity in Asymmetric Borilative Cyclization with Coordinating Leaving Group

^○Kotomi Sawada¹, Yu Ozawa¹, Yuma Shiratori¹, Hajime Ito^1,2 (1. Graduate School oh Engineering, Hokkaido University, 2. WPI-ICReDD)

[Lang.] Japanese

2:10 PM - 2:20 PM

[K406-4pm-05] Ag-catalyzed cyanomethylation of secondary amines via activation of nitromethane

^○Takuya Takashima¹, Taiga Yurino^2,3, Takeshi Ohkuma^2,3 (1. Graduate School of Chemical Sciences and Engineering, Hokkaido University, 2. Faculty of Engineering, Hokkaido University, 3. Frontier Chemistry Center)

[Lang.] Japanese

2:20 PM - 2:30 PM

[K406-4pm-06] Gold-Catalyzed Conia-Ene Reaction by Using Phosphine-Borane Ligand

^○Kaishi Kawasaki¹, Rintaro Kuwahara¹, Gen Onodera¹, Tsutomu Fukuda¹, Norbert Krause², Masanari Kimura¹ (1. The Univ. of Nagasaki, 2. The Univ. of Dortmund)

[Lang.] Japanese

Break (2:30 PM - 2:40 PM)

2:40 PM - 2:50 PM

[K406-4pm-07] Divergent Synthesis of ortho- and meta-Aminophenol derivatives based on Cu-Catalyzed [1,3]-Methoxy Rearrangement

^○Riku Konta¹, Mai Tachibana, Yasuhiro Ishida, Masahiro Terada¹, Itaru Nakamura¹ (1. The University of Tohoku)

[Lang.] Japanese

2:50 PM - 3:00 PM

[K406-4pm-08] Mechanistic studies on copper-catalyzed [1,3]-nitrogen rearrangement reactions of O-aryl ketoximes

^○Mao Suzuki¹, Masahiro Terada¹, Itaru Nakamura¹ (1. Tohoku University)

[Lang.] Japanese

3:00 PM - 3:10 PM

[K406-4pm-09] Development of Dynamic Helical Polymer Ligands Bearing P-Stereogenic Phosphoramidite Units

^○Yusuke Matsumoto¹, Takaya Fujie¹, Takeshi Yamamoto¹, Michinori Suginome¹ (1. Kyoto University)

[Lang.] Japanese

3:10 PM - 3:20 PM

[K406-4pm-10] Synthesis and Catalytic Properties of Fluorinated NHC-Ag(I) Complexes as Alternatives to Au(Ⅰ) Complex Catalysts

^○Maho Yamamoto¹, Kenichi Michigami¹, Mitsuhiro Ueda¹, Masato Ohashi¹ (1. Osaka Metropolitan Univ.)

[Lang.] Japanese

3:20 PM - 3:30 PM

[K406-4pm-11] Enantioselective synthesis of 4-sulfinylisoquinolines via silver-catalyzed cyclization-[1,3]-sulfinyl rearrangement reaction

^○Keiryo Kubota¹, Hiroki Tashiro, Masahiro Terada¹, Itaru Nakamura¹ (1. Tohoku University)

[Lang.] Japanese

3:30 PM - 3:40 PM

[K406-4pm-12] Silver-catalyzed rearrangement reaction of N-aryl sulfenamides to p-sulfenylaniline

^○Ichiro Muranushi¹, Takato Asoh¹, Masahiro Terada¹, Itaru Nakamura¹ (1. Tohoku University)

[Lang.] Japanese

Session information

[K406-4pm] 10. Organic Chemistry -Organometallic Compounds-

[K406-4pm-01] Molybdenum-Catalyzed Directed Activation of Aromatic C–Cl and C–F Bonds

[K406-4pm-02] Solution Synthesis of DMF-stabilized Manganese Nanoparticles Catalyst for Hydrosilylation

[K406-4pm-03] Mo-Catalyzed Enantioselective Metathesis Dimerization/Desymmetrization of C_s-Symmetric Divinylferrocenes

[K406-4pm-04] Controlling Stereoselectivity in Asymmetric Borilative Cyclization with Coordinating Leaving Group

[K406-4pm-05] Ag-catalyzed cyanomethylation of secondary amines via activation of nitromethane

[K406-4pm-06] Gold-Catalyzed Conia-Ene Reaction by Using Phosphine-Borane Ligand

[K406-4pm-07] Divergent Synthesis of ortho- and meta-Aminophenol derivatives based on Cu-Catalyzed [1,3]-Methoxy Rearrangement

[K406-4pm-08] Mechanistic studies on copper-catalyzed [1,3]-nitrogen rearrangement reactions of O-aryl ketoximes

[K406-4pm-09] Development of Dynamic Helical Polymer Ligands Bearing P-Stereogenic Phosphoramidite Units

[K406-4pm-10] Synthesis and Catalytic Properties of Fluorinated NHC-Ag(I) Complexes as Alternatives to Au(Ⅰ) Complex Catalysts

[K406-4pm-11] Enantioselective synthesis of 4-sulfinylisoquinolines via silver-catalyzed cyclization-[1,3]-sulfinyl rearrangement reaction

[K406-4pm-12] Silver-catalyzed rearrangement reaction of N-aryl sulfenamides to p-sulfenylaniline

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