Academic Program [Oral A]

[K406-1am] 10. Organic Chemistry -Organometallic Compounds-

Wed. Mar 22, 2023 9:00 AM - 11:40 AM K406 (K406, Lecture Hall Bldg. [4F])

Chair: Masakazu Nambo, Tsubasa Omoda

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9:00 AM - 9:10 AM

[K406-1am-01] Application of nickel(0) complex as a catalyst precursor for the coupling reaction of thiophenes (1)

^○Ukyo Ogi¹, Seiha Yamaoka¹, Naoki Noda¹, Kentaro Okano¹, Atsunori Mori^1,2 (1. Department of Chemical Science and Engineering, Kobe University, 2. Research Center for Membrane and Film Technology, Kobe University)

[Lang.] Japanese

9:10 AM - 9:20 AM

[K406-1am-02] Application of nickel(0) complex as a catalyst precursor for the coupling reaction of thiophenes (2)

^○Naoki Noda¹, Ukyo Ogi¹, Seiha Yamaoka¹, Kentaro Okano¹, Atsunori Mori^1,2 (1. Department of Chemical Science and Engineering, Kobe University, 2. Research Center for Membrane and Film Technology, Kobe University)

[Lang.] Japanese

9:20 AM - 9:30 AM

[K406-1am-03] Regio- and Enantioselective Friedel-Crafts Reaction of imine and Phenol Substrates using Bis(imidazolidine)pyridine-Nickel Complex and its Plausible Mechanism

^○Ryoya Tajima¹, Takayoshi Arai¹ (1. Chiba university)

[Lang.] Japanese

9:30 AM - 9:40 AM

[K406-1am-04] Nickel Complexes Bearing Triarylborane and N-Phosphine
Oxide-Substituted Imidazolinylidenes

^○Yutaka Mondori¹, Yasuhiro Yamauchi¹, Yuta Uetake^1,2, Hidehiro Sakurai^1,2, Yoichi Hoshimoto¹, Sensuke Ogoshi¹ (1. Graduate School of Engineering, Osaka Univ., 2. ICS-OTRI, Osaka Univ.)

[Lang.] Japanese

9:40 AM - 9:50 AM

[K406-1am-05] Ni-catalyzed cross coupling reaction to synthesize monofluoro silyl enol ether

^○Taiki Negoro¹, Kajiwara Koki¹, Doi Ryohei¹, Ogoshi Sensuke¹ (1. Osaka University)

[Lang.] Japanese

9:50 AM - 10:00 AM

[K406-1am-06] Synthesis and Structures of Nickel Sheet Sandwich Clusters by Using Cyclooctatetraene

^○Genki Sakai¹, Tsubasa Omoda¹, Koji Yamamoto², Shigeyoshi Sakaki³, Tetsuro Murahashi¹ (1. Tokyo Tech, 2. National Defense Academy, 3. Kyoto Univ.)

[Lang.] Japanese

10:00 AM - 10:10 AM

[K406-1am-07] Nickel-Catalyzed Alkylboration of Styrenes

^○Kazuhiko Semba¹, Yasuhiro Ohtagaki¹, Kouhei Iitsuka¹, Yoshiaki Nakao¹ (1. Graduate School of Engineering, Kyoto University)

[Lang.] Japanese

Break （10:10 AM - 10:30 AM）

10:30 AM - 10:40 AM

[K406-1am-08] Solid-state Yamamoto homocoupling with ball mill

^○Naoki Shizukuishi¹, Koji Kubota^1,2, Hajime Ito^1,2 (1. Graduate School of Engineering, Hokkaido University, 2. WPI-ICReDD, Hokkaido University)

[Lang.] Japanese

10:40 AM - 10:50 AM

[K406-1am-09] Ni-catalyzed Desulfonylative Suzuki–Miyaura Cross-Coupling of Arylsulfones

^○Ryusei Ohkura¹, Masakazu Nanbo¹, Cathleen Crudden^1,2 (1. Nagoya University, 2. Queen’s University)

[Lang.] Japanese

10:50 AM - 11:00 AM

[K406-1am-10] Nickel-Catalyzed Synthesis of Silyl Enol Ethers Using Acylsilanes and Norbornene.

^○Akihisa Matsuura¹, Mamoru Tobisu^1,2 (1. Osaka Univ., 2. Osaka Univ. ICS-OTRI)

[Lang.] Japanese

11:00 AM - 11:10 AM

[K406-1am-11] Visible-light photoredox/nickel dual catalyzed unimolecular fragment coupling of esters via elimination of an oxygen atom

^○Riku Tanimoto¹, Ryoma Shimazumi¹, Mamoru Tobisu^1,2 (1. Osaka univ., 2. ICS-OTRI)

[Lang.] Japanese

11:10 AM - 11:20 AM

[K406-1am-12] Platinum Complex-Catalyzed Synthesis of Carbonyl Compounds from Organic Iodides and Fomyl Compounds without Use of Carbon Monoxide

^○Miu Ohara¹, Nobuyuki Tanaka, Risako Miura¹, Yu KIMURA¹, Teruyuki KONDO¹ (1. Kyoto University)

[Lang.] Japanese

11:20 AM - 11:30 AM

[K406-1am-13] Palladium-Catalyzed Hydroborative Cyclization of 1,n-Dienes with Hydroboranes

^○Shota Kanno¹, Kakiuchi Fumitoshi¹, Kochi Takuya¹ (1. Faculty of Science and Technology, Keio University)

[Lang.] Japanese

11:30 AM - 11:40 AM

[K406-1am-14] Cross-Coupling Reaction with Tri(3-methoxypropyl)-substituted Organostannanes

^○Yoshimasa Oki¹, Hideya Tanaka¹, Masaaki Nakamoto¹, Hiroto Yoshida¹ (1. Hiroshima University)

[Lang.] Japanese

Academic Program [Oral A]

[K406-1vn] 10. Organic Chemistry -Organometallic Compounds-

Wed. Mar 22, 2023 4:10 PM - 6:20 PM K406 (K406, Lecture Hall Bldg. [4F])

Chair: Katsuhiro Isozaki, Takeshi Hata

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4:10 PM - 4:20 PM

[K406-1vn-01] Ruthenium-Catalyzed Cross-Coupling Reaction of Ketones Possessing Pyridine Directing Group as an Alkenyl Electrophile

^○Yuya Kogure¹, Satoshi Ueno¹ (1. Tokyo University of Technology)

[Lang.] Japanese

4:20 PM - 4:30 PM

[K406-1vn-02] Ruthenium Hydride-Catalyzed Oxidative Dehydrogenation of Alcohols Using Carbodiimide as an Hydrogen Acceptor

^○Shunsuke Sueki^1,2, Aina Fujii¹, Yutaro Komiya¹, Masaki Ochi¹, Kosho Makino^1,2, Masahiro Anada^1,2 (1. Fac. Pharm., Musashino Univ., 2. Res. Inst. Pharm. Sci., Musashino Univ.)

[Lang.] Japanese

4:30 PM - 4:40 PM

[K406-1vn-03] Ru-Catalyzed Direct Synthesis and Application of Conjugated Tetraenes from 1,3-Enynes and 1,3-Dienes: Development to Methyl Hydroxydecatetraenoate Synthesis

^○Kanako Maekawa¹, Sayori Kiyota¹, Nobuyuki Komine¹, Masafumi Hirano¹ (1. Tokyo University of Agriculture and Technology)

[Lang.] Japanese

4:40 PM - 4:50 PM

[K406-1vn-04] Asymmetric Cyanation of α-Imino Esters with Ruthenium-Lithium Combined Catalyst Systems

^○ZHEN WU¹, Kazuaki Suzuki¹, Yusuke Sakaguchi¹, Taiga Yurino^2,3, Takeshi Ohkuma^2,3 (1. Graduate School of Chemical Sciences and Engineering, Hokkaido University, 2. Faculty of Engineering, Hokkaido University, 3. Frontier Chemistry Center)

[Lang.] English

4:50 PM - 5:00 PM

[K406-1vn-05] Ruthenium-catalyzed dehydrative allylation of allylic alcohols in water

^○Shota Mizuno¹, Munenori Inoue¹ (1. Sagami Chemical Research Institute)

[Lang.] Japanese

5:00 PM - 5:10 PM

[K406-1vn-06] Computational Mechanistic Insights into Ru-Catalyzed Alder-Ene Type Reaction

^○Nozomi Nobuoka¹, Ken Yamazaki², Tomoya Miura² (1. Okayama University, 2. Graduate School of Natural Science and Technology, Okayama University)

[Lang.] Japanese

5:10 PM - 5:20 PM

[K406-1vn-07] Ruthenium-Catalyzed Alder Ene Reaction of 1-(Boryl)alk-1-ynes and 1,1-Di(boryl)-1-(silyl)alk-3-enes

^○Yuriko Doi¹, Naoki Oku², Tomoya Miura³ (1. Faculty of Engineering, Okayama University, 2. Graduate School of Engineering, Kyoto University, 3. Graduate School of Natural Science and Technology, Okayama University)

[Lang.] Japanese

Break （5:20 PM - 5:40 PM）

5:40 PM - 5:50 PM

[K406-1vn-08] Iron-Catalyzed Preparation of Secondary Amines from Nitro Compounds and Organozinc Reagents via Reductive Coupling Reaction

^○Daiki Goto¹, Koki Nishi¹, Takeshi Hata¹, Hirokazu Urabe¹ (1. Tokyo Institute of Technology)

[Lang.] Japanese

5:50 PM - 6:00 PM

[K406-1vn-09] Iron-Catalyzed Coupling of Organosodium Compounds

^○Ikko Takahashi¹, Sobi Asako¹, Laurean Ilies¹ (1. RIKEN Center for Sustainable Resource Science)

[Lang.] Japanese

6:00 PM - 6:10 PM

[K406-1vn-10] Iron-catalyzed Suzuki-type Csp³-Csp³ cross coupling between benzylboronic esters and unactivated chlorides

^○Litian Chen¹, Siming LU¹, Katsuhiro ISOZAKI¹, Masaharu NAKAMURA¹ (1. Kyoto University)

[Lang.] English

6:10 PM - 6:20 PM

[K406-1vn-11] Iron-Catalyzed Regioselective Selenophenyl C–H/C–H Coupling and Polymerization

^○Yosuke Miyazaki¹, Takahiro Doba¹, Shota Fukuma¹, Rui Shang¹, Eiichi Nakamura¹ (1. The Univ. of Tokyo)

[Lang.] English

Academic Program [Oral A]

[K406-2am] 10. Organic Chemistry -Organometallic Compounds-

Thu. Mar 23, 2023 9:00 AM - 11:40 AM K406 (K406, Lecture Hall Bldg. [4F])

Chair: Mamoru Ito, Takeru Torigoe

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9:00 AM - 9:10 AM

[K406-2am-01] Iridium-catalyzed asymmetric [3+2] annulation of ortho-keto arylboron compounds with 1,3-dienes

^○Ryota Yabe¹, Takahiro Nishimura¹ (1. Osaka Metropolitan University)

[Lang.] Japanese

9:10 AM - 9:20 AM

[K406-2am-02] Iridium-catalyzed enantioselective alkylation of indole derivatives

^○Kentaro Yamakawa¹, Takahiro Nishimura¹ (1. Osaka Metropolitan University)

[Lang.] Japanese

9:20 AM - 9:30 AM

[K406-2am-03] Iridium-Catalyzed Intramolecular Silylene Transfer Leading to Silylene Insertion into sp³ Carbon−Oxygen Bond

^○Yunhao Song¹, Toshimichi Ohmura², Michinori Suginome¹ (1. Kyoto University, 2. Kyoto Institute of Technology)

[Lang.] Japanese

9:30 AM - 9:40 AM

[K406-2am-04] Iridium-Catalyzed Annulative Coupling: C(sp³)–H Addition in Preference to O–H Addition of Phenol

^○Kaito Yagi^1,2, Michinori Suginome¹, Toshimichi Ohmura² (1. Kyoto University, 2. Kyoto Institute of Technology)

[Lang.] Japanese

9:40 AM - 9:50 AM

[K406-2am-05] Ir-Catalyzed Synthesis of Sulfur-Containing Cyclic Compounds via sp² or sp³ C–H Bond Cleavage

^○Takahiro Iwaki¹, Haru Marumo¹, Mamoru Ito¹, Takanori Shibata¹ (1. School of Advanced Science and Engineering, Waseda University)

[Lang.] Japanese

9:50 AM - 10:00 AM

[K406-2am-06] Synthesis of Nitrogen-Containing Polycyclic Compounds by Ir-catalyzed Intramolecular Cyclization Initiated by C-H Activation at the C2 Position of Indoles

^○Taichi Kishi¹, King Hung Nigel Tang¹, Mamoru Ito¹, Takanori Shibata¹ (1. Waseda University)

[Lang.] Japanese

10:00 AM - 10:10 AM

[K406-2am-07] Iridium-Catalyzed Hydroalkylation of Allenes with Malonic Amides

Takahiro Sawano¹, ^○Ayumu Sugiyama¹, Ami Iwasa¹, Ryo Takeuchi¹ (1. Aoyama Gakuin University)

[Lang.] Japanese

Break （10:10 AM - 10:30 AM）

10:30 AM - 10:40 AM

[K406-2am-08] Iridium-Catalyzed Asymmetric Allylation of Azulenes

Takahiro Sawano¹, ^○Yukino Iwashita¹, Noriko Shiowaki¹, Ryo Takeuchi¹ (1. Aoyama Gakuin University)

[Lang.] Japanese

10:40 AM - 10:50 AM

[K406-2am-09] Iridium-catalyzed cyclization of an N-methyl group with divinylsilane via sequential C–H alkylation

^○Katsumasa Tanaka¹, Takahiro Nishimura¹ (1. Osaka Metropolitan University)

[Lang.] Japanese

10:50 AM - 11:00 AM

[K406-2am-10] Iridium-catalyzed intramolecular C(sp³)–H alkenylation reaction

^○Yuki Takahashi¹, Kentaro Yamakawa², Takahiro Nishimura^1,2 (1. Osaka City University, 2. Osaka Metropolitan University)

[Lang.] Japanese

11:00 AM - 11:10 AM

[K406-2am-11] Synthesis of Axially Chiral 2-Pyridones by Iridium-Catalyzed [2+2+2] Cycloaddition of 1,8-Dialkynylnaphthalenes with Isocyanates

Takahiro Sawano¹, ^○Renshi Kudo¹, Ryo Takeuchi¹ (1. Aoyama Gakuin University)

[Lang.] Japanese

11:10 AM - 11:20 AM

[K406-2am-12] Iridium-Catalyzed Regioselective Asymmetric Allylation of Tetrazoles

Takahiro Sawano¹, ^○Chiho Matsumoto¹, Noriko Shiowaki¹, Ryo Takeuchi¹ (1. Aoyama Gakuin University)

[Lang.] Japanese

11:20 AM - 11:30 AM

[K406-2am-13] Iridium-Catalyzed C(sp³)-H/O-H Coupling of o-Alkylphenols

^○Chihiro Maruya¹, Kaito Yagi¹, Takeru Torigoe¹, Toshimichi Ohmura¹ (1. Kyoto Institute of Technology)

[Lang.] Japanese

11:30 AM - 11:40 AM

[K406-2am-14] Iridium-Catalyzed Hydrostyrenylation of Norbornenes Using Styrenes or Ethylbenzenes

^○Tomoka Yasue¹, Yunhao Song², Michinori Suginome², Takeru Torigoe¹, Toshimichi Ohmura¹ (1. Kyoto Institute of Technology , 2. Kyoto University)

[Lang.] Japanese

Academic Program [Oral A]

[K406-2pm] 10. Organic Chemistry -Organometallic Compounds-

Thu. Mar 23, 2023 1:00 PM - 3:40 PM K406 (K406, Lecture Hall Bldg. [4F])

Chair: Takahiro Sawano, Yohei Ogiwara

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1:00 PM - 1:10 PM

[K406-2pm-01] Cobalt-Catalyzed Cycloaddition of Conjugated Trienes with Alkynes giving Bicyclo[3.2.1]octa-2,6-dienes

^○Yusuke TOMITA¹, Sayori KIYOTA¹, Nobuyuki KOMINE¹, Masafumi HIRANO¹ (1. Tokyo University of Agriculture and Technology)

[Lang.] English

1:10 PM - 1:20 PM

[K406-2pm-02] Rhodium(Ⅲ)-Catalyzed Dehydrogenative Coupling of N-Acetylaminothiophenes with Alkynes

^○Mikishiro Hayashi¹, Yoshinosuke Usuki¹, Tetsuya Satoh¹ (1. Osaka Metropolitan Univ., Grad. Sch. Sci.)

[Lang.] Japanese

1:20 PM - 1:30 PM

[K406-2pm-03] Photo-Catalyzed 1,2-Hydrocyanomethylation of Alkenes with Chloroacetonitrile

^○Keito Fuke¹ (1. The Univ. of Okayama)

[Lang.] Japanese

1:30 PM - 1:40 PM

[K406-2pm-04] Rhodium-Catalyzed synthesis of novel azaarsine derivatives using hexaphenylcyclohexaalsine

Masana Yazaki¹, ^○Masashi Miyamoto¹, Keiichiro Ohashi³, Naotaka Yamada², Mieko Arisawa² (1. Grad. Sch. Bioenv Sci., Kyshu Univ, 2. Fac. Agric., Kyushu Univ, 3. Grad. Sch. Pharm Sci., Tohoku Univ)

[Lang.] Japanese

1:40 PM - 1:50 PM

[K406-2pm-05] Synthesis and characterization of DMF-protected cobalt nanoparticles and their use in the hydrosilylation reaction

^○Mana Yamamoto¹, Kazuki Tabaru¹, Tatsuki Nagata¹, Yushi Kuroda¹, Takeyuki Suzuki², Tatsuo Yajima¹, Takashi Toyao³, Yuan Jing³, Zen Maeno⁴, Ken-ichi Shimizu³, Yasushi Obora¹ (1. Fac. Chem. Matl. & Bioeng., Kansai Univ., 2. SANKEN, Osaka Univ., 3. Institute for Catalysis, Hokkaido Univ., 4. Kogakuin Univ.)

[Lang.] Japanese

1:50 PM - 2:00 PM

[K406-2pm-06] Borane-Protecting Strategy for Hydrosilylation of Phosphorus-Containing Olefins

^○Yuki Naganawa^1,2, Akira Fujita¹, Kei Sakamoto¹, Shinji Tanaka¹, Kazuhiko Sato¹, Yumiko Nakajima¹ (1. National Institute of Advanced Industrial Science and Technology, 2. JST-PRESTO)

[Lang.] Japanese

2:00 PM - 2:10 PM

[K406-2pm-07] Synthesis of 1,3-diarylpropanes by utilizing cobalt-catalyzed [4 + 2]-cycloaddition of 1,3-dienes and 1,6-diynes

^○Shu Mizusawa¹, Kento Ishida¹, Yohei Ogiwara¹, Norio Sakai¹ (1. Tokyo University of Science)

[Lang.] Japanese

Break （2:10 PM - 2:30 PM）

2:30 PM - 2:40 PM

[K406-2pm-08] Denitrative Cyanation of Nitroarenes with Organocyanides by a Palladium Catalyst

^○Keiichiro Iizumi¹, Hiroki Tanaka¹, Kei Muto¹, Junichiro Yamaguchi¹ (1. Waseda University)

[Lang.] Japanese

2:40 PM - 2:50 PM

[K406-2pm-09] Pd-Catalyzed Intramolecular Denitrative Mizoroki–Heck Reaction

^○Kotaro Asahara¹, Kei MUTO¹, Junichiro YAMAGUCHI¹ (1. Waseda University)

[Lang.] Japanese

2:50 PM - 3:00 PM

[K406-2pm-10] Lewis acidity-controlled aryl oxazaborolidinones for iterative amination reactions

^○Takaki Nojiri¹, Naoki Tuchiya¹, Takashi Nishikata¹ (1. Yamaguchi University)

[Lang.] Japanese

3:00 PM - 3:10 PM

[K406-2pm-11] Synthesis of NHC Adorned Pd₃ Nanoclusters Through Transmetalation and Their Characterization.

^○Joseph Felix DeJesus^1,2, Cathleen M. Crudden^1,2 (1. Institute of Transformative Bio-Molecules, Nagoya University, 2. Department of Chemistry, Queen’s University)

[Lang.] English

3:10 PM - 3:20 PM

[K406-2pm-12] Dinuclear Pd Addition to Mono-olefins Possessing Directing Groups

^○So Sugimoto¹, Kota Sasaki¹, Koji Yamamoto², Tsubasa Omoda¹, Tetsuro Murahashi¹ (1. Tokyo Tech, 2. National Defense Academy)

[Lang.] Japanese

3:20 PM - 3:30 PM

[K406-2pm-13] Palladium-Catalyzed 1,1-Acyloxyalkynylation of 2-Vinylbenzoates Using Bromoalkynes.

Yusuke Ano¹, ^○Sakura Takahashi¹, Naoto Chatani¹ (1. Graduate School of Engineering, Osaka University)

[Lang.] Japanese

3:30 PM - 3:40 PM

[K406-2pm-14] Palladium-Catalyzed anti-Michael Addition of Indoles

^○Ryota Moro¹, Hirotsugu Suzuki², Takanari Matsuda¹ (1. Tokyo Univ. of Science, 2. Univ. of Fukui)

[Lang.] Japanese

Academic Program [Oral A]

[K406-2vn] 10. Organic Chemistry -Organometallic Compounds-

Thu. Mar 23, 2023 4:10 PM - 5:10 PM K406 (K406, Lecture Hall Bldg. [4F])

Chair: Kento Ishida, Yusuke Ano

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4:10 PM - 4:20 PM

[K406-2vn-01] Development of novel chiral ligand and its application in Pd-catalyzed synthesis of chiral natural allenes

^○Masahito Horie¹, Eri Sawano¹, Yukari Tani¹, Tatsuya Higaki², Yasuhiro Ohki², Masamichi Ogasawara¹ (1. Tokushima University, 2. Kyoto University)

[Lang.] Japanese

4:20 PM - 4:30 PM

[K406-2vn-02] Palladium-Catalyzed Synthesis of Morpholines from 1,3-Dienes and Amino Alcohols

^○Ayumi Yamaguchi¹, Kazuki Tabaru¹, Tetsuaki Fujihara², Yasushi Obora¹ (1. Fac. Chem. Matl. & Bioeng., Kansai Univ., 2. Grad. Sch. Eng., Kyoto Univ.)

[Lang.] English

4:30 PM - 4:40 PM

[K406-2vn-03] Synthesis of regio- and stereoselective tetrasubstituted alkenes via difunctionalization of 1,3-diene with carboxylic acid and disilane

^○Ryo Kanishi¹, Kazuki Tabaru¹, Lam Cheuk Cheung¹, Kazuyuki Torii¹, Tetsuaki Fujihara², Yasushi Obora¹ (1. Fac. Chem. Matl. & Bioeng., Kansai Univ, 2. Grad. Sch. Eng., Kyoto Univ.)

[Lang.] English

4:40 PM - 4:50 PM

[K406-2vn-04] Synthesis of Dihydrobenzosilole Derivatives under Palladium Catalysis Involving a C–Pd/C–Si Bond

^○Daigo Hayashi¹, Tomohiro Tsuda¹, Ryo Shintani¹ (1. Graduate School of Engineering Science, Osaka University)

[Lang.] Japanese

4:50 PM - 5:00 PM

[K406-2vn-05] Regiodivergent Hydrosilylation of Borylated Conjugated-Trienes

^○TAKUYA TANAKA¹, NOBUYUKI KOMINE¹, MASAFUMI HIRANO¹ (1. Tokyo University of Agriculture and Technology)

[Lang.] Japanese

5:00 PM - 5:10 PM

[K406-2vn-06] Palladium-Catalyzed Carbothiolation with Thioester

^○Yoshifumi Okura¹, Ryunosuke Ito¹, Masahisa Nakada¹ (1. Waseda University)

[Lang.] Japanese

Academic Program [Oral A]

[K406-3am] 10. Organic Chemistry -Organometallic Compounds-

Fri. Mar 24, 2023 9:00 AM - 11:40 AM K406 (K406, Lecture Hall Bldg. [4F])

Chair: Akihito Konishi, Koji Kubota

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9:00 AM - 9:10 AM

[K406-3am-01] 1-Arylallyloxysilanes as Precursors of Ketone Homoenolate Equivalents: Synthesis of 3-Functionalized Silyl Enol Ethers

^○Shuto Okuda¹, Yutaka Narita¹, Rikuo Hayashi¹, Masahiro Sai¹ (1. Faculty of Engineering, Gifu University)

[Lang.] Japanese

9:10 AM - 9:20 AM

[K406-3am-02] Stereoselective Synthesis of 1,3-Diols via Asymmetric Aldol–Tishchenko Reaction Catalyzed by a Chiral Crown Ether-Ligated Potassium Base

^○Yusaku Ito¹, Takatoki Mizuno¹, Masahiro Sai¹ (1. Faculty of Engineering, Gifu University)

[Lang.] Japanese

9:20 AM - 9:30 AM

[K406-3am-03] Asymmetric α-Hydroxylation of β-Ketoesters Catalyzed by a Chiral Crown Ether-Ligated Sodium Base

^○Nao Yamakoshi¹, Takatoki Mizuno¹, Masahiro Sai¹ (1. Faculty of Engineering, Gifu University)

[Lang.] Japanese

9:30 AM - 9:40 AM

[K406-3am-04] Generation of Vinyllithium Species from Silyl Enol Ethers

^○Ziwei Zhang¹, Fumiya Takahashi¹, Hideki Yorimitsu¹ (1. Kyoto University)

[Lang.] Japanese

9:40 AM - 9:50 AM

[K406-3am-05] Zinc-Catalyzed Hydroisothiocyanation of Alkenes using Thiocyanate

^○Nobukazu Taniguchi¹ (1. Osaka Metropolitan University)

[Lang.] Japanese

9:50 AM - 10:00 AM

[K406-3am-06] Development of Cage-Shaped Aluminum Complexes for Highly Stereoselective Glycosylation

^○Tatsuya Nishitani¹, Akihito Konishi¹, Yuka Yokoyama², Yoshiyuki Manabe², Koichi Fukase², Makoto Yasuda¹ (1. Graduate School of Engineering, Osaka University, 2. Graduate School of Science, Osaka University)

[Lang.] Japanese

10:00 AM - 10:10 AM

[K406-3am-07] Investigation of Asymmetric conjugate cyanation of α,β-unsaturated imides using self-assembly Al(III)-salen catalyst

^○Hiroto Iwasaki¹, Hirotaka Sugiyama, Yusuke Kitahara, Tatushi Imahori¹ (1. Tokyo University of Science)

[Lang.] Japanese

Break （10:10 AM - 10:30 AM）

10:30 AM - 10:40 AM

[K406-3am-08] Development of efficient Diels-Alder reaction with assembly bimetallic catalyst system

^○Ryo Endo¹, Tatsushi Imahori¹, Kousuke Tunogaya (1. Tokyo Univ. of Science)

[Lang.] Japanese

10:40 AM - 10:50 AM

[K406-3am-09] Visible Light-Driven Boron Catalyzed α-Amination of Carboxylic Acids

^○Tsubasa Oyama¹, Takuto Morisawa¹, Yohei Shimizu^1,2, Masaya Sawamura^1,2 (1. Hokkaido University, Department of Chemistry, Faculty of Science , 2. WPI-ICReDD)

[Lang.] Japanese

10:50 AM - 11:00 AM

[K406-3am-10] Triarylborane-Catalyzed Reductive Alkylation of Amino Acids with H₂

^○Yusei Hisata¹, Sensuke Ogoshi¹, Yoichi Hoshimoto¹ (1. Osaka University)

[Lang.] Japanese

11:00 AM - 11:10 AM

[K406-3am-11] Formation of Germacycle via Chereotropic Reaction and Its Stereoselective Conversion to Polyfunctional Compounds

Akihito Konishi¹, ^○Taishi Nojima¹, Makoto Yasuda¹ (1. Graduate School of Engineering, Osaka University)

[Lang.] Japanese

11:10 AM - 11:20 AM

[K406-3am-12] Lewis-Acid-Catalyzed Dealkoxylation of Electron-Rich Alkoxyheteroarenes by Nucleophilic Aromatic Substitution

^○Renjyu Sakamoto¹, Teruhisa Tsuchimoto¹ (1. Meiji University)

[Lang.] Japanese

11:20 AM - 11:30 AM

[K406-3am-13] Mechanochemistry-enabled Generation of Arylbarium Nucleophiles from Unactivated Barium Metal

^○Sota Kawamura¹, Koji Kubota^1,2, Hajime Ito^1,2 (1. Graduate School of Engineering, Hokkaido University, 2. WPI-ICReDD, Hokkaido University)

[Lang.] Japanese

11:30 AM - 11:40 AM

[K406-3am-14] Mechanochemical synthesis of Grignard reagents and their application to organic synthesis

^○Shunta Kumagai¹, Rina Takahashi¹, Koji Kubota^1,2, Hajime Ito^1,2 (1. Graduate School of Engineering, Hokkaido University, 2. WPI-ICReDD, Hokkaido University)

[Lang.] Japanese

Academic Program [Oral A]

[K404-3vn] 10. Organic Chemistry -Organometallic Compounds-

Fri. Mar 24, 2023 4:10 PM - 5:20 PM K404 (K404, Lecture Hall Bldg. [4F])

Chair: Satoshi Ueno, Takuya Kodama

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4:10 PM - 4:20 PM

[K404-3vn-01] Mixed-Ligand Catalysts for Direct Arylation of Thiophenes with Aryl Chlorides: Research on elucidating the Roles of Ligands

^○Masayuki Wakioka¹, Keisuke Hatakeyama², Takehito Seki¹, Yooichiroh Maruyama³ (1. Sagami Chemical Research Institute, 2. Kitasato Univ., 3. JSR)

[Lang.] Japanese

4:20 PM - 4:30 PM

[K404-3vn-02] Palladium-Catalyzed Allylation of 1-(cyanomethyl)naphthalenes at the 4-Position

^○Rina Muto¹, Kenji Nagata¹, Yoshiki Nakazumi¹, Kaho Nakamura¹, Satoshi Ueno¹ (1. Tokyo University of Technology)

[Lang.] Japanese

4:30 PM - 4:40 PM

[K404-3vn-03] Palladium-Catalyzed C–H Alkenylation and Alkynylation of Benzophospholes

^○Yu Tokura¹, Shibo Xu², Yuki Kojima¹, Koji Hirano¹ (1. Graduate School of Engineering, Osaka University, 2. Innovative Catalysis Science Division, Institute for Open and Transdisciplinary Research Initiatives (ICS-OTRI), Osaka University)

[Lang.] Japanese

4:40 PM - 4:50 PM

[K404-3vn-04] Synthesis of benzosilacyclobutenes via palladium-catalyzed position-selective C(sp³)–H activation

^○Naoya Hamada¹, Ryo Shintani¹ (1. Osaka University )

[Lang.] Japanese

4:50 PM - 5:00 PM

[K404-3vn-05] Regiospecific cross-dehydrogenative coupling reaction and details of reductive elimination

^○Tomoki Iida¹, Ryota Sato¹, Junpei Kuwabara¹, Takaki Kanbara¹ (1. Univ. of Tsukuba TREMS)

[Lang.] Japanese

5:00 PM - 5:10 PM

[K404-3vn-06] Addition of Carbon-Silicon Bonds in Acylsilanes across Alkynes Using a Palladium Catalyst.

^○Takahiro Ando¹, Tetsuya Inagaki¹, Shun Sakurai¹, Masahiro Yamanaka², Mamoru Tobisu^1,3 (1. Osaka University, 2. Rikkyo University, 3. ICS-OTRI, Osaka University)

[Lang.] Japanese

5:10 PM - 5:20 PM

[K404-3vn-07] Palladium-catalyzed synthesis of β-lactams by the reaction of acylsilanes, imines and carbon monoxide

^○Tetsuya Inagaki¹, Takuya Kodama^1,2, Mamoru Tobisu^1,2 (1. Osaka University, 2. ICS-OTRI, Osaka University)

[Lang.] Japanese

Academic Program [Oral A]

[K406-3vn] 10. Organic Chemistry -Organometallic Compounds-

Fri. Mar 24, 2023 4:10 PM - 5:20 PM K406 (K406, Lecture Hall Bldg. [4F])

Chair: Ryohei Doi, Takashi Nishikata

+Add all to schedule

4:10 PM - 4:20 PM

[K406-3vn-01] Copper-Catalyzed Regio- and Enantioselective Hydroboration of 1-Trifluoromethylthioalkenes

^○Yuki Kojima¹, Koji Hirano¹ (1. Graduate School of Engineering, Osaka University)

[Lang.] Japanese

4:20 PM - 4:30 PM

[K406-3vn-02] Copper-Catalyzed Regio- and Enantioselective Hydroamination of α,β-Unsaturated Phosphonates

^○Shogo Nakamura¹, Soshi Nishino¹, Koji Hirano¹ (1. Graduate School of Engineering, Osaka university)

[Lang.] Japanese

4:30 PM - 4:40 PM

[K406-3vn-03] Copper-Catalyzed Acylboration of α,β-Unsaturated Esters

^○Soshi Nishino¹, Koji Hirano¹ (1. Graduate School of Engineering, Osaka university)

[Lang.] Japanese

4:40 PM - 4:50 PM

[K406-3vn-04] Homologation of fluoroalkyl copper complex

^○Yuyang Zhou¹, Ryohei Doi¹, Sensuke Ogoshi¹ (1. Osaka University)

[Lang.] Japanese

4:50 PM - 5:00 PM

[K406-3vn-05] Copper-catalyzed trans-selective arylsilylation of internal alkynes via C–H bond activation

^○Hirokazu Moniwa¹, Ryo Shintani¹ (1. Graduate school of Engineering Science, Osaka University)

[Lang.] Japanese

5:00 PM - 5:10 PM

[K406-3vn-06] Applied research of cyclohexadienone derivatives for iterative coupling

^○Naoki Tsuchiya¹, Ayane Oku¹, Takashi Nishikata¹ (1. The Univ. of Yamaguchi)

[Lang.] Japanese

5:10 PM - 5:20 PM

[K406-3vn-07] Borylation of C(sp³)–O bonds of alkyl esters by supported Au catalyst

^○Masafumi Doi¹, Hiroki Miura^1,2,3, Tetsuya Shishido^1,2,3 (1. Tokyo Metropolitan Univ., 2. Research Center for Hydrogen Energy-based Society, 3. ESICB Kyoto University)

[Lang.] Japanese

Academic Program [Oral A]

[K404-4am] 10. Organic Chemistry -Organometallic Compounds-

Sat. Mar 25, 2023 9:00 AM - 11:30 AM K404 (K404, Lecture Hall Bldg. [4F])

Chair: Shunsuke Sueki, Yuki Nagashima

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9:00 AM - 9:10 AM

[K404-4am-01] Development of azobenzene-linked bipyridine-Ir/Al catalyst for switching the positionality of aromatic C-H boration reaction

^○Kanta Ohmori¹, Tatushi Imahori¹ (1. Tokyo University of Science)

[Lang.] Japanese

9:10 AM - 9:20 AM

[K404-4am-02] Improvement of the efficiency of Ir-catalyzed mechanochemical C-H borylation under solid-state conditions

^○Keisuke Kondo Kondo¹, Koji Kubota^1,2, Hajime Ito^1,2 (1. Graduate School of Engineering, Hokkaido University, 2. WPI-ICReDD, Hokkaido University)

[Lang.] Japanese

9:20 AM - 9:30 AM

[K404-4am-03] Mechanochemical solid-state synthesis of luminescent Ir(III) complexes

^○Tsubura Endo¹, Koji Kubota^1,2, Hajime Ito^1,2 (1. Graduate School of Engineering, Hokkaido University, 2. WPI-ICReDD, Hokkaido University)

[Lang.] Japanese

9:30 AM - 9:40 AM

[K404-4am-04] Chemical Recycling of Polyurea Resins by Iridium-Catalyzed Selective Hydrogenolysis into Diformamides and Diamines

^○Kazuki Tsuge¹, Naoki Naito¹, Takanori Iwasaki¹, Kyoko Nozaki¹ (1. Graduate School of Engineering, The University of Tokyo)

[Lang.] Japanese

9:40 AM - 9:50 AM

[K404-4am-05] Catalytic Construction of Silicon-Containing Rings Based on a Rhodium Silylenoid Formed from Chlorodisilane

^○Akika Kon¹, Ikuo Sasaki², Jiaying Li², Michinori Suginome², Takeru Torigoe¹, Toshimichi Ohmura¹ (1. Kyoto Institute of Technology, 2. Kyoto University)

[Lang.] Japanese

9:50 AM - 10:00 AM

[K404-4am-06] Dynamic Chirality Control of Helical Polymer-based C₂–symmetric Bidentate Phosphorus Ligands for Rh-catalyzed Asymmetric Hydrogenation

^○Takuya Ogita¹, Takeshi Yamamoto¹, Michinori Suginome¹ (1. The Univ. of Kyoto)

[Lang.] Japanese

10:00 AM - 10:10 AM

[K404-4am-07] Development of Photocatalytic 3-Component Acylcarboxylation of Alkenes Using CO₂ Gas

^○Taito Watanabe¹, Yutaka Saga¹, Mio Kondo^1,2, Shigeyuki Masaoka¹ (1. Osaka University, 2. JST PRESTO)

[Lang.] Japanese

Break （10:10 AM - 10:30 AM）

10:30 AM - 10:40 AM

[K404-4am-08] Enantioselective construction of quaternary carbon stereocenters by rhodium-catalyzed hydroalkenylation of 1,6-enynes

^○Shunsuke Emi¹, Futo Morita¹, Yuki Nagashima¹, Ken Tanaka¹ (1. Tokyo Institute of Technology)

[Lang.] Japanese

10:40 AM - 10:50 AM

[K404-4am-09] Enantioselective Construction of Tetrahydroindole Skeletons via Rh-Catalyzed [2+2+2] Cycloaddition

^○Kairi Yamashiro¹, Fujii Kohei¹, Koji Masutomi¹, Ryota Shimotsukue¹, Ryo Arai¹, Yuki Nagashima¹, Ken Tanaka¹ (1. Tokyo Institute of Technology)

[Lang.] Japanese

10:50 AM - 11:00 AM

[K404-4am-10] Synthesis of Benzofulvene Derivatives by Rhodium-Catalyzed Hydroaminative Cyclization of 1,5-Diynes

^○Hibiki Goto¹, Takuya Kochi¹, Fumitoshi Kakiuchi¹ (1. Keio University)

[Lang.] Japanese

11:00 AM - 11:10 AM

[K404-4am-11] Dinuclear Rh(II) Complex-Catalyzed Synthesis of Sulfonamides via Cycloisomerization of Enynes

^○Kana Kinjo¹, Ryo Yonai¹, Hayato Shiraki¹, Kosho Makino^1,2, Shunsuke Sueki^1,2, Masahiro Anada^1,2 (1. Fac. Pharm., Musashino Univ., 2. Res. Inst. Pharm. Sci., Musashino Univ.)

[Lang.] Japanese

11:10 AM - 11:20 AM

[K404-4am-12] Rhodium-Catalyzed synthesis of peptide polysulfides by insertion of sulfur into unprotected peptide disulfides.

^○Kohei Fukumoto¹, Masana Yazaki¹, Mieko Arisawa² (1. Grad. Sch. Bioenv Sci., Kyushu Univ., 2. Fac. Agric., Kyushu Univ.)

[Lang.] Japanese

11:20 AM - 11:30 AM

[K404-4am-13] Rhodium-catalyzed Insertion Reaction of Perfluoroarenes into Unprotected Peptide Disulfides

Kohei Fukumoto¹, ^○Masana Yazaki¹, Mieko Arisawa² (1. Grad. Sch. Bioenv Sci., Kyushu Univ., 2. Fac. Agric., Kyushu Univ.)

[Lang.] Japanese

Academic Program [Oral A]

[K406-4am] 10. Organic Chemistry -Organometallic Compounds-

Sat. Mar 25, 2023 9:00 AM - 11:40 AM K406 (K406, Lecture Hall Bldg. [4F])

Chair: Itaru Nakamura, Kohei Fuchibe

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9:00 AM - 9:10 AM

[K406-4am-01] Copper-catalyzed anti-selective disilylative cyclization of internal alkynes having a silyl group

^○Ryosuke Kondo¹, Hirokazu Moniwa¹, Ryo Shintani¹ (1. Graduate School of Engineering Science, Osaka University)

[Lang.] Japanese

9:10 AM - 9:20 AM

[K406-4am-02] Stereospecific hydroxylation of chiral tert-alkyl halides using water

^○Ichikaze Iwashita¹ (1. Yamaguchi university)

[Lang.] Japanese

9:20 AM - 9:30 AM

[K406-4am-03] Copper-catalyzed synthesis of five-membered nitrogen-containing heterocycles

^○Kota Hashimoto¹, Daiki Higuchi¹, Satoshi Matsubara², Kei Murakami¹ (1. Kwansei Gakuin University, 2. Nagoya University)

[Lang.] Japanese

9:30 AM - 9:40 AM

[K406-4am-04] Oxidative cleavage of ethylenediamine derivatives

^○Daiki Higuchi¹, Satoshi Matsubara², Kei Murakami¹ (1. Kwansei Gakuin University, 2. Nagoya University)

[Lang.] Japanese

9:40 AM - 9:50 AM

[K406-4am-05] Cu-catalyzed Boracarboxylation of Allenes Using Carbon Dioxide

^○Go YAMAGIWA¹, Katsuya Kiyohara, Tetsuaki Fujihara¹ (1. Graduate School of Engineering, Kyoto University)

[Lang.] Japanese

9:50 AM - 10:00 AM

[K406-4am-06] Synthesis and Coordination Behavior of Anthraquinodimethane-bridged Tetrapyridyl Ligand

^○Yuta Sotome¹, Takahiro Iwamoto¹, Youichi Ishii¹ (1. The Univ. of Chuo)

[Lang.] Japanese

10:00 AM - 10:10 AM

[K406-4am-07] Development of fluoroalkylation reaction using the copper complex

^○Keisuke Nozaki¹, Ryohei Doi¹, Nobutaka Mito¹, Sensuke Ogoshi¹ (1. Osaka University)

[Lang.] Japanese

Break （10:10 AM - 10:30 AM）

10:30 AM - 10:40 AM

[K406-4am-08] Development of carbon-sulfur bond forming reaction using disulfides and norbornene

^○Reo Ikeda¹, Kento Ishida¹, Yohei Ogiwara¹, Norio Sakai¹ (1. Tokyo University of Science)

[Lang.] Japanese

10:40 AM - 10:50 AM

[K406-4am-09] Gold-Catalyzed [2 + 4] Cycloaddition of Difluoroallenes with α,β-Unsaturated Ketones: Regioselective Synthesis of Ring-Fluorinated 3,4-Dihydro-2H-pyrans

^○Leo Eto¹, Daisuke Miyazaki¹, Kohei Fuchibe¹, Junji Ichikawa¹ (1. Univ. of Tsukuba)

[Lang.] Japanese

10:50 AM - 11:00 AM

[K406-4am-10] Synthesis of Chiral 1,4-Dicarbonyl Compounds through Photoinduced Copper-Catalyzed Asymmetric Conjugate Addition of Acylsilanes

^○Yusuke Ueda¹, Aiko Sueki¹, Yusuke Masuda^1,2, Masaya Sawamura^1,2 (1. Hokkaido Universuty Faculty of Science, 2. WPI-ICReDD)

[Lang.] Japanese

11:00 AM - 11:10 AM

[K406-4am-11] Copper-Catalyzed Defluorinative [3 + 2] Annulation of Nitrile Imines with Difluorovinylzinc Complexes: Synthesis of Fluoropyrazoles

^○Kota Ichikawa¹, Takeshi Fujita¹, Junji Ichikawa¹ (1. Univ. of Tsukuba)

[Lang.] Japanese

11:10 AM - 11:20 AM

[K406-4am-12] Development of Asymmetric Bromo- and Chloroimidation of Alkylidenemalononitrile Catalyzed by Chiral Bis(imidazolidine) Pyridine

^○Takaaki Saito¹, Takayoshi Arai¹ (1. Chiba University)

[Lang.] Japanese

11:20 AM - 11:30 AM

[K406-4am-13] Cu-Catalyzed Double C(sp³)-H Functionalization of Ethylarenes to Form Arylethanolamines

^○Naoki Oku¹, Masahiro Murakami¹, Tomoya Miura² (1. Kyoto University , 2. Okayama University)

[Lang.] Japanese

11:30 AM - 11:40 AM

[K406-4am-14] Enantioselective Synthesis of ortho-Quinol Imines by Catalytic [1,3]-Rearrangement

^○Kazuki Masukawa¹, Masahiro Terada¹, Itaru Nakamura¹ (1. Tohoku Unuversity)

[Lang.] Japanese

Academic Program [Oral A]

[K404-4pm] 10. Organic Chemistry -Organometallic Compounds-

Sat. Mar 25, 2023 1:00 PM - 3:40 PM K404 (K404, Lecture Hall Bldg. [4F])

Chair: Hiroto Yoshida, Jun Shimokawa

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1:00 PM - 1:10 PM

[K404-4pm-01] Reductive anti-Dizincation of Alkynes

^○Haruka Yamaguchi¹, Fumiya Takahashi¹, Takashi Kurogi¹, Hideki Yorimitsu¹ (1. Kyoto University)

[Lang.] Japanese

1:10 PM - 1:20 PM

[K404-4pm-02] Formation of Spiropentanes and Alkylidenecyclopropanes by a Chromium Carbide Complex

^○Asato Inoue¹, Takashi Kurogi¹, Hideki Yorimitsu¹ (1. Kyoto University)

[Lang.] Japanese

1:20 PM - 1:30 PM

[K404-4pm-03] Copper-Catalyzed Synthesis of Stannine Derivatives with Arynes

^○Kaho Kanehira¹, Masaaki Nakamoto¹, Hiroto Yoshida¹ (1. Hiroshima University)

[Lang.] Japanese

1:30 PM - 1:40 PM

[K404-4pm-04] Synthesis and Transformation of Trioctyltin Compounds Based on Stannylpotassium

^○Yuta Hiraoka¹, Nakamoto Masaaki¹, Yoshida Hiroto¹ (1. Hiroshima University)

[Lang.] Japanese

1:40 PM - 1:50 PM

[K404-4pm-05] Addition Reaction of Carbon and Tin Nucleophiles to 2H-Azirines

^○Yohei Yamanaka¹, Yu-ya Takenaka, Itaru Suzuki², Ikuya Shibata^1,2 (1. Osaka Univ., 2. Osaka Univ. Environmental Safety Center)

[Lang.] Japanese

1:50 PM - 2:00 PM

[K404-4pm-06] Reduction of amides with strontium metal

^○Tatsuya Watanabe¹, Satoshi D. Ohmura², Masaharu Ueno¹, Norikazu Miyoshi¹ (1. Faculty of Science and Technology, Tokushima University, 2. National Institute of Technology, Niihama College)

[Lang.] Japanese

2:00 PM - 2:10 PM

[K404-4pm-07] Catalytic cyclotrimerization of aromatic nitriles by low-valent species generated by the magnesium reduction of group 4 transition metal chlorido complexes

^○Karin Oikawa¹, Keiichiro Saito ², Tomoyuki Toda³, Masaaki Okazaki², Shun Ohta² (1. Fac. of Sci. and Tech., Hirosaki Univ., 2. Grad. Sch. of Sci. and Tech., Hirosaki Univ., 3. Dept. of Mater. Sci. and Bioeng., Nagaoka Univ. of Tech.)

[Lang.] Japanese

Break （2:10 PM - 2:30 PM）

2:30 PM - 2:40 PM

[K404-4pm-08] Catalytic Synthesis of L-Lactiates from Poly-L-lactic Acid as the Chiral Building-block

^○Natsumi Kobayashi¹, Nobuyuki Komine¹, Hiroshi Hirano², Masafumi Hirano¹ (1. Tokyo University of Agriculture and Technology, 2. Osaka Research Institute of Industrial Science and Technology)

[Lang.] Japanese

2:40 PM - 2:50 PM

[K404-4pm-09] La(III)-Catalyzed Degradation of Polycarbonate to Dimethyl Carbonate and Bisphenol A

^○Kazuki Yamada¹, Nobuyuki Komine¹, Masafumi Hirano¹ (1. Tokyo University of Agriculture and Technology)

[Lang.] Japanese

2:50 PM - 3:00 PM

[K404-4pm-10] Cross-Coupling Reaction Between Alcohols and Alkenyl Triflates by Low-Valent Titanium-Mediated C-OH Bond Homolysis

^○Miki Kondo¹, Yuuki Takahashi¹, Takuya Suga¹, Yutaka Ukaji¹ (1. The Univ. of Kanazawa)

[Lang.] Japanese

3:00 PM - 3:10 PM

[K404-4pm-11] Cyclotrimerization of terminal alkynes using a bis(indolyl)-coordinated titanium diamido complex as a catalytic precursor

^○Shun Ohta¹, Yuki Kawahara¹, Masaaki Okazaki¹ (1. Grad. Sch. of Sci. and Tech., Hirosaki Univ.)

[Lang.] Japanese

3:10 PM - 3:20 PM

[K404-4pm-12] Ring-Opening Metathesis Polymerization of norbornene using niobium pentaalkoxide complexes

^○Moegi Nomura¹, Tatsuki Nagata¹, Shunsuke Aratani¹, Maito Fuji¹, Taichi Sotani¹, Hiromitsu Sogawa¹, Fumio Sanda¹, Tatsuo Yajima¹, Yasushi Obora¹ (1. Fac. Chem. Matl. & Bioeng., Kansai Univ)

[Lang.] English

3:20 PM - 3:30 PM

[K404-4pm-13] Retro 1,2-Brook Rearrangement Induced by the Reduction of Silyl Enol Ethers

^○Ban Kinoshita¹, Fumiya Takahashi¹, Hideki Yorimitsu¹ (1. Kyoto University)

[Lang.] Japanese

3:30 PM - 3:40 PM

[K404-4pm-14] Synthesis of Unsymmetric Silanediols from Tetraalkoxysilanes Having Seven-Membered Ring Strucutre

^○Kento Teranishi¹, Kenshiro Hitoshio¹, Hiroki Maeda¹, Jun Shimokawa¹, Hideki Yorimitsu¹ (1. Kyoto University)

[Lang.] Japanese

Academic Program [Oral A]

[K406-4pm] 10. Organic Chemistry -Organometallic Compounds-

Sat. Mar 25, 2023 1:30 PM - 3:40 PM K406 (K406, Lecture Hall Bldg. [4F])

Chair: Gen Onodera, Sobi Asako

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1:30 PM - 1:40 PM

[K406-4pm-01] Molybdenum-Catalyzed Directed Activation of Aromatic C–Cl and C–F Bonds

^○Somsuvra Banerjee¹, Naoki Matsushita¹, Sobi Asako¹, Laurean Ilies¹ (1. RIKEN)

[Lang.] English

1:40 PM - 1:50 PM

[K406-4pm-02] Solution Synthesis of DMF-stabilized Manganese Nanoparticles Catalyst for Hydrosilylation

^○Nobuki Katayama¹, Kazuki Tabaru¹, Tatsuki Nagata¹, Miku Yamaguchi¹, Takeyuki Suzuki², Takashi Toyai³, Yuan Jing³, Zen Maeno⁴, Ken-ichi Shimizu³, Yasushi Obora¹ (1. Fac. Chem. Matl. & Bioeng., Kansai Univ., 2. SANKEN, Osaka Univ., 3. Institute for Catalysis, Hokkaido Univ., 4. Kogakuin Univ.)

[Lang.] Japanese

1:50 PM - 2:00 PM

[K406-4pm-03] Mo-Catalyzed Enantioselective Metathesis Dimerization/Desymmetrization of C_s-Symmetric Divinylferrocenes

^○Kakeru Masaoka¹, Haruka Taue¹, Tatsuya Higaki², Yasuhiro Ohki², Masamichi Ogasawara¹ (1. Tokushima University, 2. Kyoto University)

[Lang.] Japanese

2:00 PM - 2:10 PM

[K406-4pm-04] Controlling Stereoselectivity in Asymmetric Borilative Cyclization with Coordinating Leaving Group

^○Kotomi Sawada¹, Yu Ozawa¹, Yuma Shiratori¹, Hajime Ito^1,2 (1. Graduate School oh Engineering, Hokkaido University, 2. WPI-ICReDD)

[Lang.] Japanese

2:10 PM - 2:20 PM

[K406-4pm-05] Ag-catalyzed cyanomethylation of secondary amines via activation of nitromethane

^○Takuya Takashima¹, Taiga Yurino^2,3, Takeshi Ohkuma^2,3 (1. Graduate School of Chemical Sciences and Engineering, Hokkaido University, 2. Faculty of Engineering, Hokkaido University, 3. Frontier Chemistry Center)

[Lang.] Japanese

2:20 PM - 2:30 PM

[K406-4pm-06] Gold-Catalyzed Conia-Ene Reaction by Using Phosphine-Borane Ligand

^○Kaishi Kawasaki¹, Rintaro Kuwahara¹, Gen Onodera¹, Tsutomu Fukuda¹, Norbert Krause², Masanari Kimura¹ (1. The Univ. of Nagasaki, 2. The Univ. of Dortmund)

[Lang.] Japanese

Break （2:30 PM - 2:40 PM）

2:40 PM - 2:50 PM

[K406-4pm-07] Divergent Synthesis of ortho- and meta-Aminophenol derivatives based on Cu-Catalyzed [1,3]-Methoxy Rearrangement

^○Riku Konta¹, Mai Tachibana, Yasuhiro Ishida, Masahiro Terada¹, Itaru Nakamura¹ (1. The University of Tohoku)

[Lang.] Japanese

2:50 PM - 3:00 PM

[K406-4pm-08] Mechanistic studies on copper-catalyzed [1,3]-nitrogen rearrangement reactions of O-aryl ketoximes

^○Mao Suzuki¹, Masahiro Terada¹, Itaru Nakamura¹ (1. Tohoku University)

[Lang.] Japanese

3:00 PM - 3:10 PM

[K406-4pm-09] Development of Dynamic Helical Polymer Ligands Bearing P-Stereogenic Phosphoramidite Units

^○Yusuke Matsumoto¹, Takaya Fujie¹, Takeshi Yamamoto¹, Michinori Suginome¹ (1. Kyoto University)

[Lang.] Japanese

3:10 PM - 3:20 PM

[K406-4pm-10] Synthesis and Catalytic Properties of Fluorinated NHC-Ag(I) Complexes as Alternatives to Au(Ⅰ) Complex Catalysts

^○Maho Yamamoto¹, Kenichi Michigami¹, Mitsuhiro Ueda¹, Masato Ohashi¹ (1. Osaka Metropolitan Univ.)

[Lang.] Japanese

3:20 PM - 3:30 PM

[K406-4pm-11] Enantioselective synthesis of 4-sulfinylisoquinolines via silver-catalyzed cyclization-[1,3]-sulfinyl rearrangement reaction

^○Keiryo Kubota¹, Hiroki Tashiro, Masahiro Terada¹, Itaru Nakamura¹ (1. Tohoku University)

[Lang.] Japanese

3:30 PM - 3:40 PM

[K406-4pm-12] Silver-catalyzed rearrangement reaction of N-aryl sulfenamides to p-sulfenylaniline

^○Ichiro Muranushi¹, Takato Asoh¹, Masahiro Terada¹, Itaru Nakamura¹ (1. Tohoku University)

[Lang.] Japanese

Sessions

10. Organic Chemistry -Organometallic Compounds- » Oral A

[K406-1am] 10. Organic Chemistry -Organometallic Compounds-

[K406-1vn] 10. Organic Chemistry -Organometallic Compounds-

[K406-2am] 10. Organic Chemistry -Organometallic Compounds-

[K406-2pm] 10. Organic Chemistry -Organometallic Compounds-

[K406-2vn] 10. Organic Chemistry -Organometallic Compounds-

[K406-3am] 10. Organic Chemistry -Organometallic Compounds-

[K404-3vn] 10. Organic Chemistry -Organometallic Compounds-

[K406-3vn] 10. Organic Chemistry -Organometallic Compounds-

[K404-4am] 10. Organic Chemistry -Organometallic Compounds-

[K406-4am] 10. Organic Chemistry -Organometallic Compounds-

[K404-4pm] 10. Organic Chemistry -Organometallic Compounds-

[K406-4pm] 10. Organic Chemistry -Organometallic Compounds-