Academic Program [Oral B]

[K703-1am] 14. Organic Chemistry -Aromatic, Heterocyclic, and Heteroatom Compounds-

Wed. Mar 22, 2023 9:00 AM - 11:10 AM K703 (K703, Lecture Hall Bldg. [7F])

Chair: Jumpei Taguchi, Yoshiaki Shoji

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9:00 AM - 9:20 AM

[K703-1am-01] Facile synthesis and evaluation of polyfluoroarylated anthracene derivatives via regio-selective cross-dehydrogenative C-H/C-H coupling reaction

^○Ryota Sato¹, Junpei Kuwabara¹, Takeshi Yasuda², Takaki Kanbara¹ (1. Tsukuba Research Center for Energy Materials Science (TREMS), Graduate School of Pure and Applied Sciences, University of Tsukuba, 2. National Institute for Materials Science)

[Lang.] Japanese

9:20 AM - 9:40 AM

[K703-1am-02] Synthesis of a NHC-Coordinated Germylene with a Biphenylene Unit

^○Shogo Morisako¹, Takahiro Sasamori¹ (1. Faculty of Pure and Applied Sciences, and Tsukuba Research Center for Energy Materials Sciences (TREMS), Univ. of Tsukuba)

[Lang.] Japanese

9:40 AM - 10:00 AM

[K703-1am-03] Comparison of structures, optical properties, and reactivity between linear and cyclic disilane-bridged trimeric framework

^○Yoshinori Yamanoi¹, Teppei Yamada¹ (1. The Univ. of Tokyo)

[Lang.] Japanese

Break （10:00 AM - 10:10 AM）

10:10 AM - 10:30 AM

[K703-1am-04] Iron-Catalyzed C–O Activation/Tandem Tetra-annulation for Synthesis of Carbon-bridged Oligo-(p-arylenevinylene)

^○MENGQING CHEN¹, Rui Shang¹, Eiichi Nakamura¹ (1. The Univ. of Tokyo)

[Lang.] English

10:30 AM - 10:50 AM

[K703-1am-05] Spiro-conjugated 1,4-Dihydropentalenes: Short-step Synthesis by Iron-catalysis and Materials Properties.

^○Aziz Khan¹, Mengqing Chen¹, Rui Shang¹, Eiichi Nakamura¹ (1. The University of Tokyo)

[Lang.] English

10:50 AM - 11:10 AM

[K703-1am-06] Cationic Indium Catalyzed C-O Bond Formation Reaction

^○Mitsuhiro Yoshimatsu¹, Manoka Kikuchi¹, Rintaro Saito¹, Hiroki Goto¹ (1. Department of Chemistry, Faculty of Education, Gifu University)

[Lang.] Japanese

Academic Program [Oral B]

[K703-1pm] 14. Organic Chemistry -Aromatic, Heterocyclic, and Heteroatom Compounds-

Wed. Mar 22, 2023 1:50 PM - 3:40 PM K703 (K703, Lecture Hall Bldg. [7F])

Chair: Shogo Morisako, Yoshinori Yamanoi

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1:50 PM - 2:10 PM

[K703-1pm-01] Development of synthetic methodology for AB₂-type arsines and investigation of catalytic activity utilizing arsa-Buchwald ligands.

^○Akifumi Sumida¹, Kenta Ogawa¹, Hiroaki Imoto¹, Kensuke Naka¹ (1. Kyoto Institute of Technology)

[Lang.] Japanese

2:10 PM - 2:30 PM

[K703-1pm-02] Emission properties of Eu(III) nitrate complexes bearing arsine oxides

^○Toshiki Fujii¹, Yuichi Kitagawa², Yasuchika Hasegawa², Hiroaki Imoto¹, Kensuke Naka¹ (1. Grad. Sch. of Sci. and Tec., Kyoto Inst. of Tech., 2. WPI-ICReDD and Fac. of Eng., Hokkaido Univ.)

[Lang.] Japanese

2:30 PM - 2:50 PM

[K703-1pm-03] Development of Catalytic Arsa-Wittig Reaction and Design Strategy of Arsenic Catalysts

^○Ryoto Inaba¹, Junya Yukiyasu¹, Takashi Yumura¹, Hiroaki Imoto¹, Kensuke Naka¹ (1. Kyoto Institute of Technology)

[Lang.] Japanese

Break （2:50 PM - 3:00 PM）

3:00 PM - 3:20 PM

[K703-1pm-04] Development of Iridium-Catalyzed C(sp³)-C(sp²) [1,5]-Silyl Rearrangement Reaction

^○Jiawei Qiu¹, Tsuyoshi Matsuzaki¹, Makoto Sako¹, kenichi Murai¹, Junichi Uenishi¹, Kazushi Mashima¹, Takeyuki Suzuki¹, Mitsuhiro Arisawa¹ (1. Osaka University)

[Lang.] Japanese

3:20 PM - 3:40 PM

[K703-1pm-05] Design and Synthesis of Spliceostatin A Derivatives: Structure-Activity Relationship Study related to Enone moiety of Spliceostatin A

^○Satoru Hirabayashi¹, Noriko Ohta¹, Yuko Tsuyuguchi¹, Yue Li¹, Yusuke Yoshikawa¹, Banzhong Lin¹, Megumi Fumimoto¹, Junichi Haruta¹, Makoto Sako¹, Kenichi Murai¹, Keisuke Nimura¹, Mitsuhiro Arisawa¹ (1. The Univ. of Osaka)

[Lang.] Japanese

Academic Program [Oral B]

[K703-1vn] 14. Organic Chemistry -Aromatic, Heterocyclic, and Heteroatom Compounds-

Wed. Mar 22, 2023 4:10 PM - 5:30 PM K703 (K703, Lecture Hall Bldg. [7F])

Chair: Akihito Konishi, Kento Iwai

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4:10 PM - 4:30 PM

[K703-1vn-01] Thermal Cyclization of Linear Arylalkynes Facilitated by Folding inside a Molecular Cage

^○Georgi Rosenov Genov¹, Hiroki Takezawa¹, Harumi Hayakawa¹, Makoto Fujita^1,2 (1. University of Tokyo, 2. Institute for Molecular Science)

[Lang.] English

4:30 PM - 4:50 PM

[K703-1vn-02] TEtraQuinoline (TEQ) and Other Cyclic Quinoline Oligomers, a New Family of Macrocycles

^○Wei Xu¹, Haru Nonaka¹, Ryota Yagami¹, Mizuki Nishiwaki¹, Ayami Takeda¹, Naoya Kumagai^1,2 (1. Keio University, 2. Institute of Microbial Chemistry)

[Lang.] English

4:50 PM - 5:10 PM

[K703-1vn-03] Novel synthesis of multi-substituted quinoline derivatives using alkylidenemalononitriles and unsaturated aldehydes by organocatalyst

^○Xiaolei Han¹, Naoki Mori¹, Yujiro Hayashi¹ (1. Tohuku Univ.)

[Lang.] English

5:10 PM - 5:30 PM

[K703-1vn-04] Intramolecular Cyclization Reactions of Arylpropargyl Amides of Electron-deficient α,β-Alkenyl Carboxylates

^○Zhichao Wang¹, Shoko Yamazaki², Tsumoru Morimoto³, Akiya Ogawa¹ (1. Osaka Metropolitan University, 2. Nara University of Education, 3. NARA Institute of Science and Technology)

[Lang.] Japanese

Academic Program [Oral B]

[K703-2am] 14. Organic Chemistry -Aromatic, Heterocyclic, and Heteroatom Compounds-

Thu. Mar 23, 2023 9:00 AM - 11:30 AM K703 (K703, Lecture Hall Bldg. [7F])

Chair: Hiroaki Imoto, Kei Muto

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9:00 AM - 9:20 AM

[K703-2am-01] Skeletal Rearrangement of a Boron-Containing π-Conjugated Macrocycles Caused by Boron–Olefin Proximity Interaction

^○Yukihiro Murata¹, Yoshiaki Shoji¹, Takanori Fukushima¹ (1. CLS, Tokyo Tech.)

[Lang.] Japanese

9:20 AM - 9:40 AM

[K703-2am-02] Synthesis of Unsymmetric Bisphosphine Derivatives by the Strain-Release Three-Component Reaction of Propellane

^○Hideaki Takano^1,2, Hitomi Katsuyama^1,2, Hiroki Hayashi^1,2, Satoshi Maeda^1,2,3, Tsuyoshi Mita^1,2 (1. WPI-ICReDD, Hokkaido Univ., 2. JST-ERATO, 3. Fac. of Sci., Hokkaido Univ.)

[Lang.] Japanese

9:40 AM - 10:00 AM

[K703-2am-03] Photoredox Dearomative Nucleophilic Addition of CO₂ Radial Anion to (Hetero)aromatics

^○Saeesh Rajendra Mangaonkar^1,2, Hiroki Hayashi^1,2, Hideaki Takano^1,2, Wataru Kanna³, Yu Harabuchi^1,2,3, Satoshi Maeda^1,2,3, Tsuyoshi Mita^1,2 (1. WPI-ICReDD, Hokkaido Univ., 2. JST-ERATO, 3. Fac. of Sci., Hokkaido Univ.)

[Lang.] English

Break （10:00 AM - 10:10 AM）

10:10 AM - 10:30 AM

[K703-2am-04] Tailor-made Synthesis of Fully and Differently Arylated Alkenes

^○Kimiya Wada¹, Kento Iwai¹, Nagatoshi Nishiwaki¹ (1. Kochi University of Technology)

[Lang.] Japanese

10:30 AM - 10:50 AM

[K703-2am-05] A Novel Jacobsen Reaction of 1,8-Diiodonaphthalene Induced by Ring Strain

^○Kento Iwai¹, Noa Nishiguchi¹, Nagatoshi Nishiwaki¹ (1. Kochi University of Technology)

[Lang.] Japanese

10:50 AM - 11:10 AM

[K703-2am-06] Regiodivergent Synthesis of Brominated Thienylpyridines Overriding the Inherent Substrate Bias

^○Masahiro Hosoya¹, Kentaro Okano¹, Atsunori Mori^1,2 (1. Department of Chemical Science and Engineering, Kobe University, 2. Research Center for Membrane and Film Technology, Kobe University)

[Lang.] English

11:10 AM - 11:30 AM

[K703-2am-07] Synthesis of π-Expanded Amines via Single-Electron Oxidant-Catalyzed Denitrogenative Benzannulation of Ynamine with Phthalazine

^○Yasuhiro Okuda¹, Takuma Sato¹, Sou Takebe¹, Tomoki Inoue¹, Akihiro Orita¹ (1. Fac. of Eng., Okayama Univ. of Science)

[Lang.] Japanese

Academic Program [Oral B]

[K703-2pm] 14. Organic Chemistry -Aromatic, Heterocyclic, and Heteroatom Compounds-

Thu. Mar 23, 2023 1:10 PM - 3:40 PM K703 (K703, Lecture Hall Bldg. [7F])

Chair: Okano Kentaro, Tsuyoshi Mita

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1:10 PM - 1:30 PM

[K703-2pm-01] Peripheral Functionalization of Antiaromatic 5,15-Dioxaporphyrin

^○Jiping Hao¹, Shigeki Mori², Soji Shimizu¹ (1. Graduate School of Engineering, Kyushu University, 2. Advanced Research Support Center (ADRES), Ehime University)

[Lang.] English

1:30 PM - 1:50 PM

[K703-2pm-02] Development of Heteroatom-Embedding Annulative π-Extension Reaction

^○Kou Kawahara¹, Hideto Ito¹, Kenichiro Itami¹ (1. Nagoya University)

[Lang.] English

1:50 PM - 2:10 PM

[K703-2pm-03] Asymmetric Synthesis of Chiral Sulfimides Through the O-Alkylation of Chiral Sulfinamides

^○Saori Tsuzuki¹, Taichi Kano² (1. Graduate School of Scienece, Kyoto University, 2. Graduate School of Engineering, Tokyo University of Agriculture and Technology)

[Lang.] English

2:10 PM - 2:30 PM

[K703-2pm-04] Deoxygenative Functionalization of Diarylketones

^○Miki B Kurosawa¹, Moriaki Sakihara¹, Kenta Kato¹, Kei Muto¹, Junichiro Yamaguchi¹ (1. Waseda University)

[Lang.] English

Break （2:30 PM - 2:40 PM）

2:40 PM - 3:00 PM

[K703-2pm-05] C₃-Symmetric Cage-shaped Phosphites: Structure Controls of Their Basicity, Chiral Environment, and Application to Rh-Catalyzed Asymmetric 1,4-Addition.

^○Xiao Liu¹, Akihito Konishi¹, Makoto Yasuda¹ (1. Osaka University)

[Lang.] English

3:00 PM - 3:20 PM

[K703-2pm-06] Synthesis and Structure of [8]Heterocirculene by Use of Intramolecular Coupling [7]Thiaheterohelicene Derivatives

^○Tatsuya Nakanishi¹, Hideji Osuga¹, Hidefumi Sakamoto¹ (1. Grad. Sch. Sys. Eng., Wakayama Univ.)

[Lang.] English

3:20 PM - 3:40 PM

[K703-2pm-07] Novel Pathways to Pentafluorosulfanylated Compounds via
Thiolation and Oxidative Fluorination

^○Yue Liu¹, Tim Gatzenmeier¹, Takashi Okazoe^1,2, Kyoko Nozaki¹ (1. The University of Tokyo, 2. AGC Inc.)

[Lang.] English

Sessions

14. Organic Chemistry -Aromatic, Heterocyclic, and Heteroatom Compounds- » Oral B

[K703-1am] 14. Organic Chemistry -Aromatic, Heterocyclic, and Heteroatom Compounds-

[K703-1am-01] Facile synthesis and evaluation of polyfluoroarylated anthracene derivatives via regio-selective cross-dehydrogenative C-H/C-H coupling reaction

[K703-1am-02] Synthesis of a NHC-Coordinated Germylene with a Biphenylene Unit

[K703-1am-03] Comparison of structures, optical properties, and reactivity between linear and cyclic disilane-bridged trimeric framework

[K703-1am-04] Iron-Catalyzed C–O Activation/Tandem Tetra-annulation for Synthesis of Carbon-bridged Oligo-(p-arylenevinylene)

[K703-1am-05] Spiro-conjugated 1,4-Dihydropentalenes: Short-step Synthesis by Iron-catalysis and Materials Properties.

[K703-1am-06] Cationic Indium Catalyzed C-O Bond Formation Reaction

[K703-1pm] 14. Organic Chemistry -Aromatic, Heterocyclic, and Heteroatom Compounds-

[K703-1pm-01] Development of synthetic methodology for AB₂-type arsines and investigation of catalytic activity utilizing arsa-Buchwald ligands.

[K703-1pm-02] Emission properties of Eu(III) nitrate complexes bearing arsine oxides

[K703-1pm-03] Development of Catalytic Arsa-Wittig Reaction and Design Strategy of Arsenic Catalysts

[K703-1pm-04] Development of Iridium-Catalyzed C(sp³)-C(sp²) [1,5]-Silyl Rearrangement Reaction

[K703-1pm-05] Design and Synthesis of Spliceostatin A Derivatives: Structure-Activity Relationship Study related to Enone moiety of Spliceostatin A

[K703-1vn] 14. Organic Chemistry -Aromatic, Heterocyclic, and Heteroatom Compounds-

[K703-1vn-01] Thermal Cyclization of Linear Arylalkynes Facilitated by Folding inside a Molecular Cage

[K703-1vn-02] TEtraQuinoline (TEQ) and Other Cyclic Quinoline Oligomers, a New Family of Macrocycles

[K703-1vn-03] Novel synthesis of multi-substituted quinoline derivatives using alkylidenemalononitriles and unsaturated aldehydes by organocatalyst

[K703-1vn-04] Intramolecular Cyclization Reactions of Arylpropargyl Amides of Electron-deficient α,β-Alkenyl Carboxylates

[K703-2am] 14. Organic Chemistry -Aromatic, Heterocyclic, and Heteroatom Compounds-

[K703-2am-01] Skeletal Rearrangement of a Boron-Containing π-Conjugated Macrocycles Caused by Boron–Olefin Proximity Interaction

[K703-2am-02] Synthesis of Unsymmetric Bisphosphine Derivatives by the Strain-Release Three-Component Reaction of Propellane

[K703-2am-03] Photoredox Dearomative Nucleophilic Addition of CO₂ Radial Anion to (Hetero)aromatics

[K703-2am-04] Tailor-made Synthesis of Fully and Differently Arylated Alkenes

[K703-2am-05] A Novel Jacobsen Reaction of 1,8-Diiodonaphthalene Induced by Ring Strain

[K703-2am-06] Regiodivergent Synthesis of Brominated Thienylpyridines Overriding the Inherent Substrate Bias

[K703-2am-07] Synthesis of π-Expanded Amines via Single-Electron Oxidant-Catalyzed Denitrogenative Benzannulation of Ynamine with Phthalazine

[K703-2pm] 14. Organic Chemistry -Aromatic, Heterocyclic, and Heteroatom Compounds-

[K703-2pm-01] Peripheral Functionalization of Antiaromatic 5,15-Dioxaporphyrin

[K703-2pm-02] Development of Heteroatom-Embedding Annulative π-Extension Reaction

[K703-2pm-03] Asymmetric Synthesis of Chiral Sulfimides Through the O-Alkylation of Chiral Sulfinamides

[K703-2pm-04] Deoxygenative Functionalization of Diarylketones

[K703-2pm-05] C₃-Symmetric Cage-shaped Phosphites: Structure Controls of Their Basicity, Chiral Environment, and Application to Rh-Catalyzed Asymmetric 1,4-Addition.

[K703-2pm-06] Synthesis and Structure of [8]Heterocirculene by Use of Intramolecular Coupling [7]Thiaheterohelicene Derivatives

[K703-2pm-07] Novel Pathways to Pentafluorosulfanylated Compounds via
Thiolation and Oxidative Fluorination

Authentication