[K705-1pm] 15. Organic Chemistry -Aliphatic and Alicyclic Compounds, and New Synthetic Technology-

[K705-1pm-01] Highly Stereoselective Synthesis of γ,δ-Unsaturated Quaternary α-Amino Esters via the Tandem N-Alkylation/Claisen Rearrangement of α-Imino Allylesters

^○Isao Mizota¹, Toshikazu Fukaya¹, Yumi Miwa¹, Yoshinari Kobayashi¹, Tomoki Ejima¹, Mizuki Yamaguchi¹, Makoto Shimizu¹ (1. Mie University)

[Lang.] English

Keywords:α- Iminoallyl Esters, Umpolung Reaction, N-Alkylation, Quaternary Aminoesters, Claisen Rearrangement