[P1-1am] 09. Coordination Chemistry, Organometallic Chemistry

[P1-1am-96] Highly Regio- and Enantioselective Rhodium-catalyzed 1,4-Addition of Arylboronic Acids to β,γ-Unsaturated-α-ketoamides Using (R,S_S)-Sulfoxide-MOPLigand

^○Eriko Shibata¹, Yutaro Ueyama¹, Akina Inaba², Takashi Hoshi², Toshio Suzuki² (1. Graduate School of Science and Technology, 2. Faculty of Engineering)

[Lang.] Japanese

Keywords:rhodium-catalyzed asymmetric 1,4-addition, Sulfoxide-MOP ligand, β,γ-unsaturated-α-ketoamide, γ-diatyl-α-ketoamide, arylboronic acid