長野大会(第52回石油・石油化学討論会)

講演情報

インターナショナル sess.

[2F01-2F04] インターナショナル sess.(4)

2022年10月28日(金) 09:00 〜 10:00 F会場 (13A会議室)

座長:霜田 直宏(徳島大学)

09:15 〜 09:30

[2F02] Plasmon-assisted hydrogenation and dehydrogenation reactions of noble metal nanoparticles

○Priyanka Verma1, Kohsuke Mori2, Yasutaka Kuwahara2, Ryo Watanabe1, Hiromi Yamashita2, Choji Fukuhara1 (1. Shizuoka University, 2. Osaka University)

キーワード:plasmonic catalyst, visible-light irradiation, noble metal nanoparticles

In the last decade, plasmonic catalysts have been widely researched for their characterization and application in diverse chemical reactions under visible light irradiation conditions. We have focused our research theme on the design of Ag-based hybrid plasmonic catalysts for their application in hydrogenation and dehydrogenation reactions. A significant enhancement in the conversion of ammonia borane dehydrogenation and chemoselective hydrogenation of nitrostyrene to aminostyrene was obtained upon tuning the wavelength and intensity of light irradiation over SBA-15 silica-supported Ag nanoparticles.