Academic Program [Oral A]

15. Organic Chemistry -Aliphatic and Alicyclic Compounds, and New Synthetic Technology- » Oral A

[K704-4am] 15. Organic Chemistry -Aliphatic and Alicyclic Compounds, and New Synthetic Technology-

Sat. Mar 25, 2023 9:00 AM - 11:20 AM K704 (K704, Lecture Hall Bldg. [7F])

Chair: Takeru Torigoe, Tsuyuka Sugiishi

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9:00 AM - 9:10 AM

[K704-4am-01] Metal-Free Visible-Light-Induced Bromo-Perfluoroalkylation of Olefins

^○Koto Tagami¹, Yajima Tomoko¹ (1. Ochanomizu University)

[Lang.] Japanese

9:10 AM - 9:20 AM

[K704-4am-02] The studies of the addition of a trifluoromethyl radical to vinyl triflates

^○Mai Hisayuki¹, Takuji KAWAMOTO¹, Akio KAMIMURA¹ (1. Yamaguchi University)

[Lang.] Japanese

9:20 AM - 9:30 AM

[K704-4am-03] Benzylic Difluorination of 2-Methylbenzenesulfonate Salts using Selectfluor under UV Irradiation

^○Jialin Zeng¹, Takeru Torigoe², Yoichiro Kuninobu¹ (1. Kyushu Univ., 2. Kyoto Inst. of Tech.)

[Lang.] Japanese

9:30 AM - 9:40 AM

[K704-4am-04] Chiral Organoiodine(III)-catalyzed Enantioselective Oxidative Dearomative Fluorination of Arenols

^○Shogo Yamamoto¹, Hiroki Tanaka¹, Muhammet Uyanik¹, Kazuaki Ishihara¹ (1. Nagoya University)

[Lang.] Japanese

9:40 AM - 9:50 AM

[K704-4am-05] Reductive transformation of perfluorocarboxylic acids

^○Shota Suzuki¹, Asuka Chiba¹, Tsuyuka Sugiishi¹, Soshi Shiraishi¹, Hideki Amii¹ (1. Gunma University)

[Lang.] Japanese

9:50 AM - 10:00 AM

[K704-4am-06] Synthetic Applications of Aryl Difluoromethylsilanes with various substituents.

^○Kanami Matsui¹, Toshiki Yamaguchi¹, Tsuyuka Sugiishi¹, Hideki Amii¹ (1. Gunma University)

[Lang.] Japanese

10:00 AM - 10:10 AM

[K704-4am-07] Proline derivatives-mediated asymmetric aldol and Mannich reactions of ethyl trifluoropyruvate

^○Hinata Odaira¹, Naoki Mori¹, Yujiro Hayashi¹ (1. Tohoku Univ.)

[Lang.] English

Break (10:10 AM - 10:20 AM)

10:20 AM - 10:30 AM

[K704-4am-08] Development of recoverable and reusable reagents for aromatic trifluoromethylation (1)

Mizuki Kita¹, Akari Matsuoka¹, Takuto Mimura¹, Sichen Yue¹, Kazuki Komoda¹, Tsuyuka Sugiishi¹, ^○Hideki Amii¹ (1. Gunma University)

[Lang.] Japanese

10:30 AM - 10:40 AM

[K704-4am-09] Development of recoverable and reusable reagents for aromatic trifluoromethylation (2)

^○Akari Matsuoka¹, Mizuki Kita¹, Tuyuka Sugiishi¹, Hideki Amii¹ (1. Gunma University)

[Lang.] Japanese

10:40 AM - 10:50 AM

[K704-4am-10] Lithium Assisted visible light driven Photoreduction of Trifluoromethylarene to Synthesize Difluoroalkane

^○Fua Akutsu¹, Haruna Tani¹, Tatsuhiro Uchikura¹, Takahiko Akiyama¹ (1. Gakushuin University)

[Lang.] Japanese

10:50 AM - 11:00 AM

[K704-4am-11] Multiselective Diels–Alder Reaction of α-Arylacroleins Catalyzed by Boron Tribromide-Assisted Chiral Phosphoric Acids

^○Kai Matsui¹, Manabu Hatano², Kazuaki Ishihara¹ (1. Nagoya University, 2. Kobe Pharmaceutical University)

[Lang.] English

11:00 AM - 11:10 AM

[K704-4am-12] Asymmetric conjugate addition of trialkenylboroxines to enone diesters using a hybrid Cu-catalyst system

^○Noritaka Kunitomo¹, Kento Yasumoto², Taichi Kano¹ (1. Graduate School of Engineering, Tokyo University of Agriculture and Technology, 2. Graduate school of Science, Kyoto University)

[Lang.] Japanese

11:10 AM - 11:20 AM

[K704-4am-13] Lewis Acid-catalyzed Decarboxylative Cyanation of Cyclic Enol Carbonates

^○Haruki Yokoyama¹, Yoichi Dokai¹, Natsuki Kimaru¹, Kodai Saito², Tohru Yamada¹ (1. Keio University, 2. Hokkaido University of Education)

[Lang.] Japanese

Session information

[K704-4am] 15. Organic Chemistry -Aliphatic and Alicyclic Compounds, and New Synthetic Technology-

[K704-4am-01] Metal-Free Visible-Light-Induced Bromo-Perfluoroalkylation of Olefins

[K704-4am-02] The studies of the addition of a trifluoromethyl radical to vinyl triflates

[K704-4am-03] Benzylic Difluorination of 2-Methylbenzenesulfonate Salts using Selectfluor under UV Irradiation

[K704-4am-04] Chiral Organoiodine(III)-catalyzed Enantioselective Oxidative Dearomative Fluorination of Arenols

[K704-4am-05] Reductive transformation of perfluorocarboxylic acids

[K704-4am-06] Synthetic Applications of Aryl Difluoromethylsilanes with various substituents.

[K704-4am-07] Proline derivatives-mediated asymmetric aldol and Mannich reactions of ethyl trifluoropyruvate

[K704-4am-08] Development of recoverable and reusable reagents for aromatic trifluoromethylation (1)

[K704-4am-09] Development of recoverable and reusable reagents for aromatic trifluoromethylation (2)

[K704-4am-10] Lithium Assisted visible light driven Photoreduction of Trifluoromethylarene to Synthesize Difluoroalkane

[K704-4am-11] Multiselective Diels–Alder Reaction of α-Arylacroleins Catalyzed by Boron Tribromide-Assisted Chiral Phosphoric Acids

[K704-4am-12] Asymmetric conjugate addition of trialkenylboroxines to enone diesters using a hybrid Cu-catalyst system

[K704-4am-13] Lewis Acid-catalyzed Decarboxylative Cyanation of Cyclic Enol Carbonates

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