[K404-2am] 10. Organic Chemistry -Organometallic Compounds-

[K404-2am-05] Experimental and DFT study on electrophilic and carbene-like reactivity of magnesium alkylidene carbenoids

^○Koto Sekiguchi¹, Tsutomu Kimura¹ (1. Graduate School of Science, Tokyo University of Science)

[Lang.] English

Keywords:magnesium alkylidene carbenoid, 1-chlorovinyl p-tolyl sulfoxide, DFT calculation, nucleophilic substitution at vinylic carbon, Fritsch–Buttenberg–Wiechell rearrangement