[K506-1pm] 09. Coordination Chemistry, Organometallic Chemistry

[K506-1pm-07] Effects of π-Donation from the Axial Ligands on the Reactivity of Iron(IV)-oxide Porphyrin-π-cation Radical Complex toward Alkane Hydroxylation Reactions

^○Toshiya Higashi¹, Yuma Morimoto², Hiroshi Fujii³, Shinobu Itoh¹ (1. Osaka University, 2. Nagoya University, 3. Nara Women's University)

[Lang.] Japanese

Keywords:Iron(IV)-Oxide Porphyrin π-Cation Radical Complex, Reaction Mechanism, Alkane Hydroxylation, Axial Ligand Effect, π-Donor Ability