Academic Program [Oral A]

09. Coordination Chemistry, Organometallic Chemistry » Oral A

[K506-1pm] 09. Coordination Chemistry, Organometallic Chemistry

Wed. Mar 22, 2023 1:00 PM - 3:40 PM K506 (K506, Lecture Hall Bldg. [5F])

Chair: Tomohiro Iwai, Yusuke Tamaki

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1:00 PM - 1:10 PM

[K506-1pm-01] Development of novel methanol fuel cell anode catalyst using Fe(III) complex

^○Takahiro Kawaguchi¹, Daisuke Nakane¹, Takashiro Akitsu¹ (1. Tokyo University of Science)

[Lang.] Japanese

1:10 PM - 1:20 PM

[K506-1pm-02] Development of Function-Integrated System for Water Oxidation by Electrochemical Polymerization of Pentanuclear Iron Complexes

^○Takumi Matsuzaki¹, Hikaru IWAMI¹, Yutaka SAGA¹, Mio KONDO^1,2, Sigeyuki MASAOKA¹ (1. Osaka Univ., 2. JST PRESTO)

[Lang.] Japanese

1:20 PM - 1:30 PM

[K506-1pm-03] Photochemical CO₂ Reduction by Iron Porphyrin Complexes with Multi-Proton/Electron Transfer Moieties

^○Maho Imai¹, Kento Kosugi¹, Yutaka Saga¹, Mio Kondo^1,2, Shigeyuki Masaoka¹ (1. Osaka Univ., 2. JST PRESTO)

[Lang.] Japanese

1:30 PM - 1:40 PM

[K506-1pm-04] Substrate oxidation by an iron(IV)-oxo complex bearing a porphyrin ligand with a substrate-trapping site

^○Lianyu Wei¹, shogo tanaka¹, tamoya ishizuka¹, takahiko kojima¹ (1. The Univ. of Tsukuba)

[Lang.] English

1:40 PM - 1:50 PM

[K506-1pm-05] Photocatalytic Reactions Using Water as an Electron Source Driven by Phase-Migrating Electron Mediators

^○Ren Itagaki¹, Akinobu Nakada², Ryu Abe², Ho-Chol Chang¹ (1. Chuo Univ., 2. Kyoto Univ.)

[Lang.] Japanese

1:50 PM - 2:00 PM

[K506-1pm-06] Reactivity of Iron Sandwich Complexes with Oxocyclohexadienyl Ligands toward Proton-Coupled Electron Transfer Reactions

^○Yuye ZHANG¹, Shogo KURIYAMA¹, Yoshiaki NISHIBAYASHI¹ (1. School of Engineering, The University of Tokyo)

[Lang.] English

2:00 PM - 2:10 PM

[K506-1pm-07] Effects of π-Donation from the Axial Ligands on the Reactivity of Iron(IV)-oxide Porphyrin-π-cation Radical Complex toward Alkane Hydroxylation Reactions

^○Toshiya Higashi¹, Yuma Morimoto², Hiroshi Fujii³, Shinobu Itoh¹ (1. Osaka University, 2. Nagoya University, 3. Nara Women's University)

[Lang.] Japanese

2:10 PM - 2:20 PM

[K506-1pm-08] CO₂Reduction Reaction Catalyzed by a Doubly N-confused Hexaphyrin Dinuclear-Iron Complex

^○Daichi Sugawara¹, Takashi Ito¹, Takashi Nakazono², Tohru Wada¹ (1. College of Science, Department of Chemistry, Rikkyo University, 2. Research Center for Artificial Photosynthesis (ReCAP), Osaka Metropolitan University)

[Lang.] Japanese

Break (2:20 PM - 2:30 PM)

2:30 PM - 2:40 PM

[K506-1pm-09] Efficient electrocatalytic CO₂ reduction by base metal complexes with in-plane N₄ ligands.

^○Chiho Narita¹, Yuta Tsubonouchi¹, Norihisa Hoshino¹, Debraj Chandra¹, Zaki Zahran¹, Masayuki Yagi¹ (1. Grad. School of Sci. and Tech., Niigata univ.)

[Lang.] Japanese

2:40 PM - 2:50 PM

[K506-1pm-10] Photocatalytic CO₂ reduction by an iron porphyrin-based framework catalyst constructed by hydrogen bonding

^○XIANJUN LI¹, Maho IMAI¹, Kento KOSUGI¹, Yutaka SAGA¹, Mio KONDO^1,2, Shigeyuki MASAOKA¹ (1. Osaka University, 2. JST PRESTO)

[Lang.] English

2:50 PM - 3:00 PM

[K506-1pm-11] Reaction mechanism of non-heme mononuclear iron-thiolato complex with oxygen

^○Masaki Kubo¹, Daisuke Nakane³, Tomohiro Ozawa¹, Tomohiko Inomata¹, Hideki Masuda^2,1 (1. Graduate School of Engineering, Nagoya Institute of Technology, 2. Aichi Institute of Technology, 3. Tokyo University of Science)

[Lang.] Japanese

3:00 PM - 3:10 PM

[K506-1pm-12] Iron-catalyzed Suzuki-Miyaura Coupling of Propargyl Electrophiles with Organoboron Compounds Derived from Alkenyl Bromides

^○Beiling WU¹, Siming LU¹, Ryosuke AGATA², Hiroshi MATSUDA³, Satoshi AOKI¹, Francesca PINCELLA¹, Katsuhiro ISOZAKI¹, Masaharu NAKAMURA¹ (1. Kyoto Univ., 2. MCG Corp., 3. TSK Corp.)

[Lang.] English

3:10 PM - 3:20 PM

[K506-1pm-13] Earth-Abundant Systems for Photocatalytic CO₂ Reduction using Chromium Complexes Supported by Ferrocenyl Groups for Improving the Performance

^○Taku Wakabayashi¹, Jieun Jung¹, Youhei Kametani², Yoshihito Shiota², Kazunari Yoshizawa², Susumu Saito^1,3 (1. Grad. Sch. Sci., Nagoya Univ., 2. IMCE, Kyushu Univ., 3. IRCCS, Nagoya Univ.)

[Lang.] English

3:20 PM - 3:30 PM

[K506-1pm-14] Theoretical study on proton-coupled electron transfer reaction using metallocene toward nitrogen fixation

^○Yusuke Tsuruta¹, Akihito Egi¹, Hiromasa Tanaka², Yoshiaki Nishibayashi³, Kazunari Yoshizawa¹ (1. Institute for Materials Chemistry and Engineering, Kyushu Univ., 2. School of Liberal Arts and Science, Daido Univ., 3. School of Engineering, The Univ. of Tokyo)

[Lang.] Japanese

3:30 PM - 3:40 PM

[K506-1pm-15] Synthesis of Multi-substituted Cyclopentadiene Derivatives from Tungsten Vinylcarbene Complexes and Internal Alkynes

^○Akira Yamamoto¹, Takuya Akiyama¹, Hayato Tsurugi¹, Kazushi Mashima² (1. Graduate School of Engineering Science, Osaka University, 2. Graduate School of Pharmaceutical Sciences, Osaka University)

[Lang.] Japanese

Session information

[K506-1pm] 09. Coordination Chemistry, Organometallic Chemistry

[K506-1pm-01] Development of novel methanol fuel cell anode catalyst using Fe(III) complex

[K506-1pm-02] Development of Function-Integrated System for Water Oxidation by Electrochemical Polymerization of Pentanuclear Iron Complexes

[K506-1pm-03] Photochemical CO₂ Reduction by Iron Porphyrin Complexes with Multi-Proton/Electron Transfer Moieties

[K506-1pm-04] Substrate oxidation by an iron(IV)-oxo complex bearing a porphyrin ligand with a substrate-trapping site

[K506-1pm-05] Photocatalytic Reactions Using Water as an Electron Source Driven by Phase-Migrating Electron Mediators

[K506-1pm-06] Reactivity of Iron Sandwich Complexes with Oxocyclohexadienyl Ligands toward Proton-Coupled Electron Transfer Reactions

[K506-1pm-07] Effects of π-Donation from the Axial Ligands on the Reactivity of Iron(IV)-oxide Porphyrin-π-cation Radical Complex toward Alkane Hydroxylation Reactions

[K506-1pm-08] CO₂Reduction Reaction Catalyzed by a Doubly N-confused Hexaphyrin Dinuclear-Iron Complex

[K506-1pm-09] Efficient electrocatalytic CO₂ reduction by base metal complexes with in-plane N₄ ligands.

[K506-1pm-10] Photocatalytic CO₂ reduction by an iron porphyrin-based framework catalyst constructed by hydrogen bonding

[K506-1pm-11] Reaction mechanism of non-heme mononuclear iron-thiolato complex with oxygen

[K506-1pm-12] Iron-catalyzed Suzuki-Miyaura Coupling of Propargyl Electrophiles with Organoboron Compounds Derived from Alkenyl Bromides

[K506-1pm-13] Earth-Abundant Systems for Photocatalytic CO₂ Reduction using Chromium Complexes Supported by Ferrocenyl Groups for Improving the Performance

[K506-1pm-14] Theoretical study on proton-coupled electron transfer reaction using metallocene toward nitrogen fixation

[K506-1pm-15] Synthesis of Multi-substituted Cyclopentadiene Derivatives from Tungsten Vinylcarbene Complexes and Internal Alkynes

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