Academic Program [Oral A]

09. Coordination Chemistry, Organometallic Chemistry » Oral A

[A12-1pm] 09. Coordination Chemistry, Organometallic Chemistry

Fri. Mar 19, 2021 1:00 PM - 3:40 PM Room 12 (Online Meeting)

Chair:Norio Nakata, Shintaro Ishida, Jieun Jung

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1:00 PM - 1:10 PM

[A12-1pm-01] Direct Photoexcitation of Azaboracene-based Organoborate Enabling Alkylradical Generation

^○Yusuke Miyamoto¹, Yuto Sumida¹, Hirohisa Ohmiya^1,2 (1. Grad. Sch. Med. Sci., Kanazawa Univ, 2. JST PRESTO)

[Lang.] Japanese

1:10 PM - 1:20 PM

[A12-1pm-02] Synthesis and Catalytic Activity of Photo-activated Lewis Acid Catalyst Induced by Pyrene Excimer

Daiki Tanaka¹, ^○Yuya Tsutsui¹, Yuka Ikinaga², Yoshiyuki Manabe², Koichi Fukase², Akihito Konishi¹, Makoto Yasuda¹ (1. Graduate School of Engineering, Osaka University, 2. Graduate School of Science, Osaka University)

[Lang.] Japanese

1:20 PM - 1:30 PM

[A12-1pm-03] Development of the Photoredox Activity of Phebox-Al Complexes

^○Shuichi Nakao¹, Yoshihiro Nishimoto¹, Makoto Yasuda¹ (1. Osaka University)

[Lang.] Japanese

1:30 PM - 1:40 PM

[A12-1pm-04] Synthesis and Catalytic Activity of Atrane-type Molecules Having a Cationic Group 14 Center

^○Daiki Tanaka¹, Akihito Konishi¹, Makoto Yasuda¹ (1. Osaka University)

[Lang.] English

1:40 PM - 1:50 PM

[A12-1pm-05] Synthesis and Reactivity of a New Base-Coordinated Silylene

^○Hayato Sasaki¹, Yuki Yokouchi¹, Takeaki Iwamoto¹ (1. Tohoku University)

[Lang.] Japanese

1:50 PM - 2:00 PM

[A12-1pm-06] Reactions of Germabenzenylpotassium with Various Electrophiles

^○Ryuto Sasayama¹, Yoshiyuki Mizuhata¹, Norihiro Tokitoh¹ (1. Institute for Chemical Research, Kyoto Univ.)

[Lang.] Japanese

2:00 PM - 2:10 PM

[A12-1pm-07] Hydroboration reaction of imines with an iminophosphonamido chlorostannylene as precatalyst

^○Kazuki Nakaya¹, Shintaro Takahashi¹, Norio Nakata¹, Akihiko Ishii¹ (1. Graduate School of Science and Engineering, Saitama University)

[Lang.] Japanese

2:10 PM - 2:20 PM

[A12-1pm-08] Alternating copolymerization of CO₂ and epoxide catalyzed by hetero tetranuclear complexes containing calcium and first-row transition metals

^○Saki Matsushiro¹, Haruki Nagae¹, Jun Okuda², Kazushi Mashima¹ (1. Graduate School of Engineering Science, Osaka Univ., 2. RWTH Aachen Univ.)

[Lang.] Japanese

2:20 PM - 2:30 PM

[A12-1pm-09] Catalytic Transformation of Carboxylic Acids by Cerium-containing Heterometallic Clusters as Photocatalysts

^○Sota Tamaki¹, Daisuke Senga¹, Hayato Tsurugi¹, Kazushi Mashima¹ (1. Graduate School of Engineering Science, Osaka Univ.)

[Lang.] Japanese

2:30 PM - 2:40 PM

[A12-1pm-10] Photo-induced Aerobic C-H Oxidation Catalyzed by Hetero Tetranuclear CeNi₃ Complex

^○Kazutaka Sakamoto¹, Sakiko Fujiwara¹, Haruki Nagae¹, Kon Yoshihiro², Sato Kazuhiko², Okuda Jun³, Mashima Kazushi¹ (1. Osaka University, 2. National Institute of Advanced Industrial Science and Technology, 3. RWTH Aachen University)

[Lang.] Japanese

2:40 PM - 2:50 PM

[A12-1pm-11] Aerobic Oxidation of Hydroquinone Derivatives Catalyzed by Tetranuclear CeZn₃ Complexes

^○Sakiko Fujiwara¹, Kazutaka Sakamoto¹, Haruki Nagae¹, Hayato Tsurugi¹, Kazushi Mashima¹ (1. Osaka University)

[Lang.] Japanese

2:50 PM - 3:00 PM

[A12-1pm-12] Hydrogen peroxide generation by two-electron oxidation of water using Ti porphyrin as a visible light responsive photocatalyst

^○Yutaka Ohsaki¹, Tetsuya Shimada¹, Tamao Ishida^1,2, Shinsuke Takagi^1,3, Hiroshi Tachibana¹, Haruo Inoue^1,3 (1. Tokyo Metropolitan Univ., 2. Research Center for Gold Chemistry, 3. Research Center for Hydrogen Energy-based Society)

[Lang.] Japanese

3:00 PM - 3:10 PM

[A12-1pm-13] Low-valent Chromium-catalyzed Olefination of Aldehydes in the Presence of an N,N’-bis(trimethylsilyl)-1,4-dihydropyrazine Derivative

^○Kohei Nishi¹, Hayato Tsurugi¹, Kazushi Mashima¹ (1. Osaka University)

[Lang.] English

3:10 PM - 3:20 PM

[A12-1pm-14] Reactions of a Chromium Silylyne Complex Having an Eind Group with Conjugated Dienes and α, β-Unsaturated Ketones

^○Masahiro Matsuoka¹, Koichi Nagata¹, Ryoma Ohno², Tsukasa Matsuo², Hiromi Tobita¹, Hisako Hashimoto¹ (1. Tohoku University, 2. Kindai University)

[Lang.] Japanese

3:20 PM - 3:30 PM

[A12-1pm-15] Photoreduction of CO₂to HCO₂Husing molybdenum complexes bearing PNNP-type tetradentate ligands as photocatalysts

^○Hiroaki SHIBAYAMA¹, Kenji KAMADA¹, Jieun JUNG¹, Susumu SAITO^1,2 (1. Grad. Sch. Sci., Nagoya Univ., 2. RCMS, Nagoya Univ.)

[Lang.] Japanese

3:30 PM - 3:40 PM

[A12-1pm-16] Substituent Effects on Molybdenum Complexes Bearing PNP-Pincer Ligands for Catalytic Reduction of Dinitrogen into Ammonia.

^○Taichi Mitsumoto¹, Yuya Ashida¹, Kazuya Arashiba¹, Shogo Kuriyama¹, Yoshiaki Nishibayashi¹ (1. School of Engineering, The University of Tokyo)

[Lang.] Japanese

Session information

[A12-1pm] 09. Coordination Chemistry, Organometallic Chemistry

[A12-1pm-01] Direct Photoexcitation of Azaboracene-based Organoborate Enabling Alkylradical Generation

[A12-1pm-02] Synthesis and Catalytic Activity of Photo-activated Lewis Acid Catalyst Induced by Pyrene Excimer

[A12-1pm-03] Development of the Photoredox Activity of Phebox-Al Complexes

[A12-1pm-04] Synthesis and Catalytic Activity of Atrane-type Molecules Having a Cationic Group 14 Center

[A12-1pm-05] Synthesis and Reactivity of a New Base-Coordinated Silylene

[A12-1pm-06] Reactions of Germabenzenylpotassium with Various Electrophiles

[A12-1pm-07] Hydroboration reaction of imines with an iminophosphonamido chlorostannylene as precatalyst

[A12-1pm-08] Alternating copolymerization of CO₂ and epoxide catalyzed by hetero tetranuclear complexes containing calcium and first-row transition metals

[A12-1pm-09] Catalytic Transformation of Carboxylic Acids by Cerium-containing Heterometallic Clusters as Photocatalysts

[A12-1pm-10] Photo-induced Aerobic C-H Oxidation Catalyzed by Hetero Tetranuclear CeNi₃ Complex

[A12-1pm-11] Aerobic Oxidation of Hydroquinone Derivatives Catalyzed by Tetranuclear CeZn₃ Complexes

[A12-1pm-12] Hydrogen peroxide generation by two-electron oxidation of water using Ti porphyrin as a visible light responsive photocatalyst

[A12-1pm-13] Low-valent Chromium-catalyzed Olefination of Aldehydes in the Presence of an N,N’-bis(trimethylsilyl)-1,4-dihydropyrazine Derivative

[A12-1pm-14] Reactions of a Chromium Silylyne Complex Having an Eind Group with Conjugated Dienes and α, β-Unsaturated Ketones

[A12-1pm-15] Photoreduction of CO₂to HCO₂Husing molybdenum complexes bearing PNNP-type tetradentate ligands as photocatalysts

[A12-1pm-16] Substituent Effects on Molybdenum Complexes Bearing PNP-Pincer Ligands for Catalytic Reduction of Dinitrogen into Ammonia.

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