[A20-1am] 15. Organic Chemistry -Aliphatic and Alicyclic Compounds, and New Synthetic Technology-

[A20-1am-02] Chemoselective Cleavage of Si–C(sp³) Bonds in Unactivated Tetraalkylsilanes Using Iodine Tris(trifluoroacetate)

^○Keitaro Matsuoka¹, Narumi Komami¹, Keito Watanabe¹, Masahiro Kojima¹, Tsuyoshi Mita^2,3, Kimichi Suzuki^2,3,4, Satoshi Maeda^2,3,4, Tatsuhiko Yoshino¹, Shigeki Matsunaga^1,5 (1. Faculty of Pharmaceutical sciences, Hokkaido University, 2. WPI-ICReDD, 3. JST-ERATO, 4. Faculty of Science, Hokkaido University, 5. GI-CoRE)

[Lang.] English

Keywords:Hypervalent iodine, Organosilane, Cleavage of unactivated bonds, Chemoselectivity, Tamao-oxidation