Academic Program [Oral A]

15. Organic Chemistry -Aliphatic and Alicyclic Compounds, and New Synthetic Technology- » Oral A

[A21-2am] 15. Organic Chemistry -Aliphatic and Alicyclic Compounds, and New Synthetic Technology-

Sat. Mar 20, 2021 9:00 AM - 11:40 AM Room 21 (Online Meeting)

Chair:Kazunori Nagao, Kohsuke Ohmatsu, Masahiro Kojima

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9:00 AM - 9:10 AM

[A21-2am-01] N-Heterocyclic Carbene-Catalyzed Radical Cross-Coupling between Aldehydes and α-Bromocarbonyls

^○Takuya Ishii¹, Kazunori Nagao¹, Hirohisa Ohmiya^1,2 (1. Grad. Sch. Med. Sci., Kanazawa Univ., 2. JST PRESTO)

[Lang.] Japanese

9:10 AM - 9:20 AM

[A21-2am-02] Aryl-Mediated N-Heterocyclic Carbene Catalysis Enabling Dehydrogenative C–H Acylation of Secondary Amides

^○Nagisa Ohnishi¹, Kazunori Nagao¹, Hirohisa Ohmiya^1,2 (1. Grad. Sch. Med. Sci., Kanazawa Univ., 2. JST PRESTO)

[Lang.] Japanese

9:20 AM - 9:30 AM

[A21-2am-03] Aryl Radical-Mediated N-Heterocyclic Carbene Catalysis Enabling Vicinal Arylacylation of Alkenes

^○Yuki Matsuki¹, Kazunori Nagao¹, Hirohisa Ohmiya^1,2 (1. Grad. Sch. Med. Sci., Kanazawa Univ., 2. JST PRESTO)

[Lang.] Japanese

9:30 AM - 9:40 AM

[A21-2am-04] Hydrogen-Atom Transfer Catalysis for Fluorine-Substituted Benzylic C−H Functionalization

^○Hiroki Fujita^1,2,3, Kohsuke Ohmatsu^1,2,3, Takashi Ooi^1,2,3 (1. Nagoya University, 2. Institute of Transformative Bio-Molecules, 3. Department of Molecular and Macromolecular Chemistry, Graduate School of Engineering)

[Lang.] Japanese

9:40 AM - 9:50 AM

[A21-2am-05] Photoinduced allylic heteroarylation of enol silyl ethers

^○Haruka Fujimori¹, Kohsuke Ohmatsu^2,3, Takashi Ooi^2,3 (1. Nagoya Univ., 2. Grad. Sch. of Eng., Nagoya Univ., 3. WPI-ITbM, Nagoya Univ.)

[Lang.] Japanese

9:50 AM - 10:00 AM

[A21-2am-06] Mannich-type Allylic C−H Functionalization of Enol Silyl Ethers under Photoredox-Thiol Hybrid Catalysis

^○Tsubasa Nakashima¹, Kohsuke Ohmatsu^1,2, Takashi Ooi^1,2 (1. Grad. Sch. of Eng., Nagoya Univ., 2. WPI-ITbM, Nagoya Univ.)

[Lang.] Japanese

10:00 AM - 10:10 AM

[A21-2am-07] Organophotoredox-Catalyzed Decarboxylative Cross-Coupling between Aliphatic carboxylic acids and a-Ketocarbonyls

^○Kenji Ota¹, Kazunori Nagao¹, Hirohisa Ohmiya^1,2 (1. Grad. Sch. Med. Sci., Kanazawa Univ., 2. JST PRESTO)

[Lang.] Japanese

10:10 AM - 10:20 AM

[A21-2am-08] Organophotoredox-Catalyzed Decarboxylative Semipinacol Rearrangement Reaction

^○Taiga Kodo¹, Kazunori Nagao¹, Hirohisa Ohmiya^1,2 (1. Grad. Sch. Med. Sci., Kanazawa Univ., 2. JST PRESTO)

[Lang.] Japanese

10:20 AM - 10:30 AM

[A21-2am-09] Development of Chiral Iron(III) Salts for Enantioselective Radical Cation-induced [2+2] Cycloaddition under Photoirradiation

^○Kei Katagiri¹, Shuhei Ohmura¹, Takahiro Horibe¹, Kazuaki Ishihara¹ (1. Nagoya University)

[Lang.] Japanese

10:30 AM - 10:40 AM

[A21-2am-10] Development of Chiral Iron(III) Salts for Enantioselective Radical Cation-induced [4+2] Cycloaddition of Anetholes under Photoirradiation

^○Haruna Kato¹, Kei Katagiri¹, Shuhei Ohmura¹, Takahiro Horibe¹, Kazuaki Ishihara¹ (1. Nagoya Univ.)

[Lang.] Japanese

10:40 AM - 10:50 AM

[A21-2am-11] Synthesis of Polysubstituted Enamides by HAT Isomerization using Dual Photoredox and Cobalt Catalysis

^○Yusuke Seino¹, Yuji Kamei², Yuto Yamaguchi¹, Tatsuhiko Yoshino², Masahiro Kojima², Shigeki Matsunaga^2,3 (1. Faculty of Pharmaceutical Sciences, Hokkaido University, 2. Graduate School of Pharmaceutical Sciences, Hokkaido University, 3. Global Institution for Collaborative Research and Education)

[Lang.] Japanese

10:50 AM - 11:00 AM

[A21-2am-12] Radical Allylic Alkylation by the Cobalt / Organophotoredox Dual Catalysis

^○Shunta Sato¹, Tatsuhiko Yoshino¹, Masahiro Kojima¹, Shigeki Matsunaga^1,2 (1. Hokkaido University, 2. GI-Core)

[Lang.] Japanese

11:00 AM - 11:10 AM

[A21-2am-13] C–O bond formation between aryl halides and carboxylates using titanium dioxide photocatalyst and a nickel complex

^○Riku Hashimoto¹, Hiroya Tada¹, Shogo Mori¹, Jieun Jung¹, Susumu Saito^1,2 (1. Grad. Sch. Sci., Nagoya Univ., 2. RCMS, Nagoya Univ.)

[Lang.] Japanese

11:10 AM - 11:20 AM

[A21-2am-14] Hydroxy-perfluoroalkylation using Eosin Y for styrenes

^○Haruko Shibata¹, Moeko Nakayama, Yajima Tomoko¹ (1. Ochanomizu University)

[Lang.] Japanese

11:20 AM - 11:30 AM

[A21-2am-15] Organophotoredox-Catalyzed Decarboxylative Cross-Coupling between Azoles and Aliphatic Carboxylic Acid Derivatives

^○Rino Kobayashi¹, Kazunori Nagao¹, Zenichi Ikeda², Yusuke Sasaki², Hirohisa Ohmiya^1,3 (1. Grad. Sch. Med. Sci., Kanazawa Univ., 2. Takeda Pharmaceutical Company Limited, 3. JST PRESTO)

[Lang.] Japanese

11:30 AM - 11:40 AM

[A21-2am-16] Organophotoredox-Catalyzed Decarboxylative Cross-Coupling between Organosilanes and Aliphatic Carboxylic Acid Derivatives

^○Tomotoki Matsuo¹, Kazunori Nagao¹, Hirohisa Ohmiya^1,2 (1. Grad. Sch. Med. Sci., Kanazawa Univ., 2. JST PRESTO)

[Lang.] Japanese

Session information

[A21-2am] 15. Organic Chemistry -Aliphatic and Alicyclic Compounds, and New Synthetic Technology-

[A21-2am-01] N-Heterocyclic Carbene-Catalyzed Radical Cross-Coupling between Aldehydes and α-Bromocarbonyls

[A21-2am-02] Aryl-Mediated N-Heterocyclic Carbene Catalysis Enabling Dehydrogenative C–H Acylation of Secondary Amides

[A21-2am-03] Aryl Radical-Mediated N-Heterocyclic Carbene Catalysis Enabling Vicinal Arylacylation of Alkenes

[A21-2am-04] Hydrogen-Atom Transfer Catalysis for Fluorine-Substituted Benzylic C−H Functionalization

[A21-2am-05] Photoinduced allylic heteroarylation of enol silyl ethers

[A21-2am-06] Mannich-type Allylic C−H Functionalization of Enol Silyl Ethers under Photoredox-Thiol Hybrid Catalysis

[A21-2am-07] Organophotoredox-Catalyzed Decarboxylative Cross-Coupling between Aliphatic carboxylic acids and a-Ketocarbonyls

[A21-2am-08] Organophotoredox-Catalyzed Decarboxylative Semipinacol Rearrangement Reaction

[A21-2am-09] Development of Chiral Iron(III) Salts for Enantioselective Radical Cation-induced [2+2] Cycloaddition under Photoirradiation

[A21-2am-10] Development of Chiral Iron(III) Salts for Enantioselective Radical Cation-induced [4+2] Cycloaddition of Anetholes under Photoirradiation

[A21-2am-11] Synthesis of Polysubstituted Enamides by HAT Isomerization using Dual Photoredox and Cobalt Catalysis

[A21-2am-12] Radical Allylic Alkylation by the Cobalt / Organophotoredox Dual Catalysis

[A21-2am-13] C–O bond formation between aryl halides and carboxylates using titanium dioxide photocatalyst and a nickel complex

[A21-2am-14] Hydroxy-perfluoroalkylation using Eosin Y for styrenes

[A21-2am-15] Organophotoredox-Catalyzed Decarboxylative Cross-Coupling between Azoles and Aliphatic Carboxylic Acid Derivatives

[A21-2am-16] Organophotoredox-Catalyzed Decarboxylative Cross-Coupling between Organosilanes and Aliphatic Carboxylic Acid Derivatives

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