Academic Program [Oral B]

[K705-1pm] 15. Organic Chemistry -Aliphatic and Alicyclic Compounds, and New Synthetic Technology-

Wed. Mar 22, 2023 1:00 PM - 3:40 PM K705 (K705, Lecture Hall Bldg. [7F])

Chair: Ryo Yazaki, Yoshihiro Nishimoto

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1:50 PM - 2:10 PM

[K705-1pm-01] Highly Stereoselective Synthesis of γ,δ-Unsaturated Quaternary α-Amino Esters via the Tandem N-Alkylation/Claisen Rearrangement of α-Imino Allylesters

^○Isao Mizota¹, Toshikazu Fukaya¹, Yumi Miwa¹, Yoshinari Kobayashi¹, Tomoki Ejima¹, Mizuki Yamaguchi¹, Makoto Shimizu¹ (1. Mie University)

[Lang.] English

2:10 PM - 2:30 PM

[K705-1pm-02] Selective Defluoroaminoxylation of perfluoroalkylarenes by organic photoredox catalysis

^○Naoki Sugihara¹, Yoshihiro Nishimoto¹, Makoto Yasuda¹ (1. Graduate School of Engineering, Osaka University)

[Lang.] English

2:30 PM - 2:50 PM

[K705-1pm-03] 1,4-Addition Reaction of 2H-Heptafluoropropane to Unsaturated C-C bond

^○Yusuke Higashi¹, Kotono Shima¹, Mikiya Suzuki¹, Moe Hosokawa², Kiyomi Kakiuchi¹, Tsuyoshi Kawai¹, Tsumoru Morimoto¹ (1. Nara Institute of Science and Technology, 2. Daikin Industries, Ltd.)

[Lang.] English

Break （2:50 PM - 3:00 PM）

3:00 PM - 3:20 PM

[K705-1pm-04] α-Amino acid and peptide synthesis using catalytic cross-dehydrogenative coupling

^○Taro Tsuji¹, Kayoko Hashiguchi¹, Mana Yoshida¹, Tetsu Ikeda¹, Yunosuke Koga¹, Yusaku Honda¹, Tsukushi Tanaka¹, Suyong Re², Kenji Mizuguchi^2,3, Daisuke Takahashi¹, Ryo Yazaki¹, Takashi Ohshima¹ (1. The Univ. of Kyushu, 2. NIBIOHN, 3. The Univ. of Osaka)

[Lang.] English

3:20 PM - 3:40 PM

[K705-1pm-05] Oxidative Dearomative Coupling Reaction of Arenols Using Hypohalite Catalysis

^○Takehiro Kato¹, Muhammet Uyanik¹, Kazuaki Ishihara¹ (1. Nagoya University)

[Lang.] English

Academic Program [Oral B]

[K705-2pm] 15. Organic Chemistry -Aliphatic and Alicyclic Compounds, and New Synthetic Technology-

Thu. Mar 23, 2023 1:10 PM - 3:40 PM K705 (K705, Lecture Hall Bldg. [7F])

Chair: Shintaro Kawamura, Takatsugu Murata

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1:10 PM - 1:30 PM

[K705-2pm-01] Stereoselective Addition of Sulfenate Species to Electrophiles as a Versatile Synthetic Method of Chiral Sulfoxides

^○Jian Zhang¹, Keisuke Suzuki², Ken Ohmori¹ (1. Department of Chemistry, School of Science, Tokyo Institute of Technology., 2. Institute of Innovative Research, Tokyo Institute of Technology.)

[Lang.] English

1:30 PM - 1:50 PM

[K705-2pm-02] The Effect of Water in the Esterification Mediated by MNBA, Highly Efficient Dehydration Condensation Reagent

Takatsugu Murata¹, ^○Nao Takabayashi¹, Isamu Shiina¹ (1. Tokyo University of Science)

[Lang.] Japanese

1:50 PM - 2:10 PM

[K705-2pm-03] Z-Enamide Synthesis by Stereoselective Radical Fluoroalkylation Reaction

^○Takuma Tagami¹, Daisuke Sekine², Yuma Aoki¹, Shintaro Kawamura^1,2, Mikiko Sodeoka^1,2 (1. RIKEN CSRS, 2. RIKEN CPR)

[Lang.] English

2:10 PM - 2:30 PM

[K705-2pm-04] Carboxylic Acid-Cooperative-Ru(bpga)-Catalyzed Highly Site-Selective C–H Oxygenation

^○Daiki Doiuchi¹, Nanako Shimoda¹, Tatsuya Uchida^1,2,3,4 (1. Grad. Sch. Sci., Kyushu Univ., 2. Fac. Arts and Sci., Kyushu Univ., 3. WPI-I2CNER, Kyushu Univ., 4. JST-PRESTO)

[Lang.] English

Break （2:30 PM - 2:40 PM）

2:40 PM - 3:00 PM

[K705-2pm-05] Visible-Light-Induced Carboamination of Styrenes with Carboxylic Acids and (Diarylmethylene)aminobenziodoxolones

^○Daichi Okumatsu¹, Kensuke Kiyokawa¹, Satoshi Minakata¹ (1. Graduate School of Engineering, Osaka University)

[Lang.] English

3:00 PM - 3:20 PM

[K705-2pm-06] Tandem Enantioselective [2+2], [3+2] and [4+2] Cycloaddition Reactions of In Situ-generated N-Allenoylpyrazoles Induced by Chiral π–Cu(II) Catalysts

^○Weiwei Guo¹, Masahiro Hori¹, Yoshihiro Ogura¹, Kazuki Nishimura¹, Kazuaki Ishihara¹ (1. Nagoya University)

[Lang.] English

3:20 PM - 3:40 PM

[K705-2pm-07] Enantioselective Radical Cation [2+2] and [4+2] Cycloadditions Using Chiral Iron(III) Catalyst with Photoirradiation

^○Kei Katagiri¹, Haruna Kato¹, Shuhei Ohmura¹, Takahiro Horibe¹, Kazuaki Ishihara¹ (1. Nagoya University)

[Lang.] English

Academic Program [Oral B]

[K705-2vn] 15. Organic Chemistry -Aliphatic and Alicyclic Compounds, and New Synthetic Technology-

Thu. Mar 23, 2023 4:10 PM - 6:40 PM K705 (K705, Lecture Hall Bldg. [7F])

Chair: Muhammet Uyanik, Yuuya Kawasaki

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4:10 PM - 4:30 PM

[K705-2vn-01] Magnesium(II) and Sodium(I) Bisphenoxide Catalysts for Transesterification of Methyl (Meth)acrylate and Their Reaction Mechanisms

^○Kazumasa Kon¹, Xue Zhao², Manussada Ratanasak³, Chie Joko², Jun-ya Hasegawa³, Kazuaki Ishihara² (1. Nagoya University Venture Business Laboratory, 2. Nagoya University, 3. Hokkaido University)

[Lang.] English

4:30 PM - 4:50 PM

[K705-2vn-02] Development of DACN based Multi-Molecular Connector and Its Application for Hybridization of Peptides

^○Tomoya Hayashibara¹, Yuuki Seto¹, Yuutaro Taniguchi¹, Kazunobu Igawa², Kawasaki Yuuya³, Katsuhiko Tomooka^1,3 (1. IMCE, Kyushu Univ., 2. FAST, Kumamoto Univ., 3. IGSES, Kyushu Univ.)

[Lang.] Japanese

4:50 PM - 5:10 PM

[K705-2vn-03] Synthesis of polyhalogenated molecules by a general Cu-catalyzed halo-halofluoroalkylation of alkenes/alkynes with fluorinated carboxylic anhydrides

^○SUBRATA MUKHERJEE¹, YUMA AOKI¹, SHINTARO KAWAMURA^1,2, MIKIKO SODEOKA^1,2 (1. RIKEN CSRS, 2. RIKEN CPR)

[Lang.] English

5:10 PM - 5:30 PM

[K705-2vn-04] E-Selective Elongation Reaction of Aldehydes by Weinreb Amide-type Horner–Wadsworth–Emmons Reagent

^○Hisazumi Tsutsui¹, Takatsugu Murata¹, Shintaro Hiraishi¹, Daiki Usukura¹, Hiroki Okano¹, Isamu Shiina¹ (1. Tokyo University of Science)

[Lang.] English

Break （5:30 PM - 5:40 PM）

5:40 PM - 6:00 PM

[K705-2vn-05] Et₂Zn-Mediated Cross-coupling Reactions between Dibromoketones and Monobromo Carbonyl Compounds

^○Aika Takeshima^1,2, Taichi Kano¹ (1. Graduate School of Engineering, Tokyo University of Agriculture and Technology, 2. Graduate School of Science, Kyoto University)

[Lang.] English

6:00 PM - 6:20 PM

[K705-2vn-06] Design and synthesis of novel bifunctional organocatalysts for an enantioselective rearrangement of α-acyloxy-β-keto sulfides to α-acyloxy thioesters

^○Julie Kong^1,2, Chloée Bournaud¹, Yasuhiro Yamashita², Shū Kobayashi², Giang Vo-Thanh¹ (1. Université Paris-Saclay, Institut de Chimie Moléculaire et des Matériaux d'Orsay, 2. The University of Tokyo, Department of Chemistry, School of Science)

[Lang.] English

6:20 PM - 6:40 PM

[K705-2vn-07] Development of Efficient Synthetic Method of Latanoprost Using an Organocatalyst

^○Genki Kawauchi¹, Yurina Suga¹, Shunsuke Toda¹, Yujiro Hayashi¹ (1. Tohoku Univ.)

[Lang.] English

Academic Program [Oral B]

[K705-3pm] 15. Organic Chemistry -Aliphatic and Alicyclic Compounds, and New Synthetic Technology-

Fri. Mar 24, 2023 1:10 PM - 3:40 PM K705 (K705, Lecture Hall Bldg. [7F])

Chair: Kazunobu Igawa, Keisuke Asano

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1:10 PM - 1:30 PM

[K705-3pm-01] Photocatalytic transfer hydrogenation from water to carbon–carbon multiple bonds of unsaturated carboxylic acids

^○Farzaneh SOLEYMANIMOVAHED¹, Shogo Mori¹, Daling Lu², Takashi Hisatomi², Kazunari Domen², Susumu Saito¹ (1. Nagoya University, 2. Shinshu University)

[Lang.] English

1:30 PM - 1:50 PM

[K705-3pm-02] Development of Photoinduced α-Alkylation Reactions of Carbonyl Compounds with Alkenes

^○Yasuhiro Yamashita¹, Shu Kobayashi¹ (1. The University of Tokyo)

[Lang.] Japanese

1:50 PM - 2:10 PM

[K705-3pm-03] Modular Synthesis of 1,4-Dicarbonyl Compounds via Sequential Photocatalysis Using Ambiphilic Radical Linchpin

^○Akira Matsumoto¹, Keiji Maruoka^1,2 (1. Kyoto University, 2. Guangdong University of Technology)

[Lang.] Japanese

2:10 PM - 2:30 PM

[K705-3pm-04] Development of Visible Light-Gated Bifunctional Cyclooctene Catalysts

^○Tagui NAGANO¹, Keisuke ASANO², Daisuke URAGUCHI² (1. Kyoto Univ., 2. Hokkaido Univ.)

[Lang.] English

Break （2:30 PM - 2:40 PM）

2:40 PM - 3:00 PM

[K705-3pm-05] Reduction of Nitriles, Aldehydes, and Ketones with Tetrahydroxydiborn Catalyzed by an Amphiphilic Resin-Supported Nanopalladium Catalyst

^○Kaili Zhang^1,2, Aya Tazawa¹, Shintaro Okumura^1,2, Yasuhiro Uozumi^1,2 (1. Institute for Molecular Science , 2. The Graduate University for Advanced Studies)

[Lang.] English

3:00 PM - 3:20 PM

[K705-3pm-06] Electrochemical Allylation Reactions Catalyzed by Nitrogen-Doped Carbon Supported Zinc Electrodes

^○Ryusuke Masuda¹, Tomohiro Yasukawa¹, Yasuhiro Yamashita¹, Shu Kobayashi¹ (1. The Univ. of Tokyo)

[Lang.] English

3:20 PM - 3:40 PM

[K705-3pm-07] Continuous-flow enantioselective hydroacylations with chiral heterogeneous Rh catalysts and sequential-flow transformations

^○Yuki Saito¹, Shū Kobayashi¹ (1. The University of Tokyo)

[Lang.] English

Academic Program [Oral B]

[K705-4am] 15. Organic Chemistry -Aliphatic and Alicyclic Compounds, and New Synthetic Technology-

Sat. Mar 25, 2023 9:00 AM - 10:20 AM K705 (K705, Lecture Hall Bldg. [7F])

Chair: Masaki Nishijima, Shinichiro Fuse

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9:00 AM - 9:20 AM

[K705-4am-01] Multistep-flow Syntheses of APIs Utilizing Continuous-flow C–N Bonds Forming Reactions with Heterogeneous Catalysts

^○Ken Nishizawa¹, Yuki Saito¹, Shu Kobayashi¹ (1. The university of Tokyo)

[Lang.] Japanese

9:20 AM - 9:40 AM

[K705-4am-02] Development of Flow Microwave Reactor Using CSTR and Rapid Synthesis of Organic Compounds

^○Takeko Matsumura¹, Akiyoshi Ono¹, Isao Kotani², Kentaro Kotani², Nobuyuki Nakayama², Mitsuyoshi Kishihara³, Yoshihito Mori⁴ (1. MINERVA LIGHT LAB., 2. Mac engineering Co. Ltd.,, 3. Okayama Prefectural University, 4. Ochanomizu University)

[Lang.] Japanese

9:40 AM - 10:00 AM

[K705-4am-03] Oil/water-biphasic dynamic kinetic resolution in a Pickering emulsion

^○Kyohei Kanomata¹, Jihoon Moon¹, Takusho Kin¹, Karin Mizuno¹, Shuji Akai¹ (1. Osaka University)

[Lang.] Japanese

10:00 AM - 10:20 AM

[K705-4am-04] Photosensitized Singlet Oxygen-supported Alcohol Oxidation Mediated by Nitroxyl Radical Catalyst

^○Masaki Nishijima¹, Shota Nagasawa¹, Yusuke Sasano¹, Yasuyuki Araki¹, Yoshiharu Iwabuchi¹, Takehiko Wada¹ (1. Tohoku University)

[Lang.] Japanese

Sessions

15. Organic Chemistry -Aliphatic and Alicyclic Compounds, and New Synthetic Technology- » Oral B

[K705-1pm] 15. Organic Chemistry -Aliphatic and Alicyclic Compounds, and New Synthetic Technology-

[K705-1pm-01] Highly Stereoselective Synthesis of γ,δ-Unsaturated Quaternary α-Amino Esters via the Tandem N-Alkylation/Claisen Rearrangement of α-Imino Allylesters

[K705-1pm-02] Selective Defluoroaminoxylation of perfluoroalkylarenes by organic photoredox catalysis

[K705-1pm-03] 1,4-Addition Reaction of 2H-Heptafluoropropane to Unsaturated C-C bond

[K705-1pm-04] α-Amino acid and peptide synthesis using catalytic cross-dehydrogenative coupling

[K705-1pm-05] Oxidative Dearomative Coupling Reaction of Arenols Using Hypohalite Catalysis

[K705-2pm] 15. Organic Chemistry -Aliphatic and Alicyclic Compounds, and New Synthetic Technology-

[K705-2pm-01] Stereoselective Addition of Sulfenate Species to Electrophiles as a Versatile Synthetic Method of Chiral Sulfoxides

[K705-2pm-02] The Effect of Water in the Esterification Mediated by MNBA, Highly Efficient Dehydration Condensation Reagent

[K705-2pm-03] Z-Enamide Synthesis by Stereoselective Radical Fluoroalkylation Reaction

[K705-2pm-04] Carboxylic Acid-Cooperative-Ru(bpga)-Catalyzed Highly Site-Selective C–H Oxygenation

[K705-2pm-05] Visible-Light-Induced Carboamination of Styrenes with Carboxylic Acids and (Diarylmethylene)aminobenziodoxolones

[K705-2pm-06] Tandem Enantioselective [2+2], [3+2] and [4+2] Cycloaddition Reactions of In Situ-generated N-Allenoylpyrazoles Induced by Chiral π–Cu(II) Catalysts

[K705-2pm-07] Enantioselective Radical Cation [2+2] and [4+2] Cycloadditions Using Chiral Iron(III) Catalyst with Photoirradiation

[K705-2vn] 15. Organic Chemistry -Aliphatic and Alicyclic Compounds, and New Synthetic Technology-

[K705-2vn-01] Magnesium(II) and Sodium(I) Bisphenoxide Catalysts for Transesterification of Methyl (Meth)acrylate and Their Reaction Mechanisms

[K705-2vn-02] Development of DACN based Multi-Molecular Connector and Its Application for Hybridization of Peptides

[K705-2vn-03] Synthesis of polyhalogenated molecules by a general Cu-catalyzed halo-halofluoroalkylation of alkenes/alkynes with fluorinated carboxylic anhydrides

[K705-2vn-04] E-Selective Elongation Reaction of Aldehydes by Weinreb Amide-type Horner–Wadsworth–Emmons Reagent

[K705-2vn-05] Et₂Zn-Mediated Cross-coupling Reactions between Dibromoketones and Monobromo Carbonyl Compounds

[K705-2vn-06] Design and synthesis of novel bifunctional organocatalysts for an enantioselective rearrangement of α-acyloxy-β-keto sulfides to α-acyloxy thioesters

[K705-2vn-07] Development of Efficient Synthetic Method of Latanoprost Using an Organocatalyst

[K705-3pm] 15. Organic Chemistry -Aliphatic and Alicyclic Compounds, and New Synthetic Technology-

[K705-3pm-01] Photocatalytic transfer hydrogenation from water to carbon–carbon multiple bonds of unsaturated carboxylic acids

[K705-3pm-02] Development of Photoinduced α-Alkylation Reactions of Carbonyl Compounds with Alkenes

[K705-3pm-03] Modular Synthesis of 1,4-Dicarbonyl Compounds via Sequential Photocatalysis Using Ambiphilic Radical Linchpin

[K705-3pm-04] Development of Visible Light-Gated Bifunctional Cyclooctene Catalysts

[K705-3pm-05] Reduction of Nitriles, Aldehydes, and Ketones with Tetrahydroxydiborn Catalyzed by an Amphiphilic Resin-Supported Nanopalladium Catalyst

[K705-3pm-06] Electrochemical Allylation Reactions Catalyzed by Nitrogen-Doped Carbon Supported Zinc Electrodes

[K705-3pm-07] Continuous-flow enantioselective hydroacylations with chiral heterogeneous Rh catalysts and sequential-flow transformations

[K705-4am] 15. Organic Chemistry -Aliphatic and Alicyclic Compounds, and New Synthetic Technology-

[K705-4am-01] Multistep-flow Syntheses of APIs Utilizing Continuous-flow C–N Bonds Forming Reactions with Heterogeneous Catalysts

[K705-4am-02] Development of Flow Microwave Reactor Using CSTR and Rapid Synthesis of Organic Compounds

[K705-4am-03] Oil/water-biphasic dynamic kinetic resolution in a Pickering emulsion

[K705-4am-04] Photosensitized Singlet Oxygen-supported Alcohol Oxidation Mediated by Nitroxyl Radical Catalyst

Authentication