Academic Program [Oral A]

13. Organic Chemistry -Reaction Mechanism, Photochemistry, Electrochemistry- » Oral A

[K701-1pm] 13. Organic Chemistry -Reaction Mechanism, Photochemistry, Electrochemistry-

Wed. Mar 22, 2023 1:00 PM - 3:40 PM K701 (K701, Lecture Hall Bldg. [7F])

Chair: Gaku Fukuhara, Tsuyoshi Mita

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1:00 PM - 1:10 PM

[K701-1pm-01] Elucidation of deiodination mechanism of type-1 iodothyronine deiodinase by peptide-based aliphatic compounds as an active site model

^○Haruka Toba¹, Ruka Mikami¹, Kenta Arai¹ (1. Tokai University)

[Lang.] Japanese

1:10 PM - 1:20 PM

[K701-1pm-02] Development of C-H alkylation of benzyl alcohols and benzylamine with α-ketoester using thiobenzoic acid.

^○Kaichi Sato¹, Fumihisa Kobayashi¹, Masashi Fujita¹, Hiromichi Egami¹, Yoshitaka Hamashima¹ (1. University of Shizuoka)

[Lang.] Japanese

1:20 PM - 1:30 PM

[K701-1pm-03] Muonium addition to isonitrile: Observation of imidoyl radical by µSR

^○Shigekazu Ito¹, Kakeru Konagaya¹, Reuben Parchment-Morisson², Kenji M. Kojima², Iain McKenzie² (1. Tokyo Institute of Technology, 2. TRIUMF)

[Lang.] Japanese

1:30 PM - 1:40 PM

[K701-1pm-04] Utilization of HBr Generated by Photolysis of CBr₄: Development of Isomerization Reaction from 1,4-Cyclohexadienes to 1,3-Cyclohexadiens

^○Seiji Akiyama¹, Miho Shimada², Satoshi Maeda^1,3,4, Yuuya Nagata¹ (1. ICReDD, Hokkaido Univ., 2. Graduate School of Chemical Science and Engineering, Hokkaido Univ., 3. Graduate School of Science, Hokkaido Univ., 4. NIMS)

[Lang.] English

1:40 PM - 1:50 PM

[K701-1pm-05] Electrochemical α-Aminoalkylation of Sulfonylalkenes with Amines and Aldehydes

^○Naoto Nakahara¹, Kotaro Sekinishi¹, Kyohei Yonekura¹, Eiji Shirakawa^1,2 (1. School of Biological and Environmental Sciences, Kwansei Gakuin University, 2. CREST, JST)

[Lang.] Japanese

1:50 PM - 2:00 PM

[K701-1pm-06] Photosolvolysis of α-(3-methoxy-2-naphthoxy)-p-methyl-propiophenone in Methanol

^○Satoshi Usui¹, Momoko Moroi, Keita Fukamachi (1. Niigata University)

[Lang.] Japanese

2:00 PM - 2:10 PM

[K701-1pm-07] Photorelease reaction of alcohols from novel photolabile molecules based on 1,4-naphthoquinone core

Tsumoru Morimoto¹, ^○Motonori Washisaka¹, HaiYing Liu¹, Kiyomi Kakiuchi¹, Tsuyoshi Kawai¹ (1. Nara Institute of Science and Technology)

[Lang.] Japanese

Break (2:10 PM - 2:20 PM)

2:20 PM - 2:30 PM

[K701-1pm-08] Synthesis, Isolation, and Reactivities of N-Sulfonyl Aza-Breslow Intermediates Using Fluorinated NHCs

^○Zhuoqin Yang¹, Kenichi Michigami¹, Mitsuhiro Ueda¹, Masato Ohashi¹ (1. Osaka Metropolitan Univ.)

[Lang.] Japanese

2:30 PM - 2:40 PM

[K701-1pm-09] Substituent Effect on Positive Charge Delocalization and Antiaromaticity of Cations Generated by Protonation of Benzo[a]fluoranthenes

^○Takao Okazaki¹, Haruki Yamashita¹, Toshikazu Kitagawa¹ (1. Mie University)

[Lang.] Japanese

2:40 PM - 2:50 PM

[K701-1pm-10] CO₂ capture and release using light and photocatalytic carbon resource utilization

^○Shuhei Uno¹, Tatsushi Imahori¹ (1. Tokyo University of Science)

[Lang.] Japanese

2:50 PM - 3:00 PM

[K701-1pm-11] Photochemical Methane Oxygenation with Chlorine Dioxide in Aqueous Solution at Normal Temperature and Pressure

^○Kei Ohkubo¹, Kumiko Hiramatsu¹, Yusaku Yamazaki², Takashi Ando² (1. Osaka Univ. , 2. Okoppe Town, Hokkaido)

[Lang.] Japanese

3:00 PM - 3:10 PM

[K701-1pm-12] Synthesis of 33- and 48-membered ring lactones by photoinduced decarboxylation

^○Shoki Kuresawa¹, Yasuharu Yoshimi¹ (1. University of Fukui)

[Lang.] Japanese

3:10 PM - 3:20 PM

[K701-1pm-13] Development of Photoreduction of Aryl Iodide via Aryl Radicals through Halogen-Bonding Interaction

^○Kentaro Kimura¹, Eiji Yamaguchi¹, Akichika Itoh¹ (1. Gifu Pharmaceautical University)

[Lang.] Japanese

3:20 PM - 3:30 PM

[K701-1pm-14] Unique effects of iodine substitution on the luminescence properties of halogenated thienyl diketone derivatives

^○Daiki Shikichi¹, Mao Komura¹, Yosuke Tani^1,2 (1. Osaka Univ., 2. ICS-OTRI.Osaka Univ.)

[Lang.] Japanese

3:30 PM - 3:40 PM

[K701-1pm-15] Generation of photo-induced polarized electron spins at solid-liquid interfaces

^○Reiya Yabuki¹, Koki Nishimura¹, Kenichiro Tateishi², Tomohiro Uesaka², Nobuhiro Yanai^1,3 (1. Grad. Sch. Eng., Kyushu Univ., 2. RIKEN Nishina Center for Accelerator-Based Science,, 3. FOREST, JST)

[Lang.] Japanese

Session information

[K701-1pm] 13. Organic Chemistry -Reaction Mechanism, Photochemistry, Electrochemistry-

[K701-1pm-01] Elucidation of deiodination mechanism of type-1 iodothyronine deiodinase by peptide-based aliphatic compounds as an active site model

[K701-1pm-02] Development of C-H alkylation of benzyl alcohols and benzylamine with α-ketoester using thiobenzoic acid.

[K701-1pm-03] Muonium addition to isonitrile: Observation of imidoyl radical by µSR

[K701-1pm-04] Utilization of HBr Generated by Photolysis of CBr₄: Development of Isomerization Reaction from 1,4-Cyclohexadienes to 1,3-Cyclohexadiens

[K701-1pm-05] Electrochemical α-Aminoalkylation of Sulfonylalkenes with Amines and Aldehydes

[K701-1pm-06] Photosolvolysis of α-(3-methoxy-2-naphthoxy)-p-methyl-propiophenone in Methanol

[K701-1pm-07] Photorelease reaction of alcohols from novel photolabile molecules based on 1,4-naphthoquinone core

[K701-1pm-08] Synthesis, Isolation, and Reactivities of N-Sulfonyl Aza-Breslow Intermediates Using Fluorinated NHCs

[K701-1pm-09] Substituent Effect on Positive Charge Delocalization and Antiaromaticity of Cations Generated by Protonation of Benzo[a]fluoranthenes

[K701-1pm-10] CO₂ capture and release using light and photocatalytic carbon resource utilization

[K701-1pm-11] Photochemical Methane Oxygenation with Chlorine Dioxide in Aqueous Solution at Normal Temperature and Pressure

[K701-1pm-12] Synthesis of 33- and 48-membered ring lactones by photoinduced decarboxylation

[K701-1pm-13] Development of Photoreduction of Aryl Iodide via Aryl Radicals through Halogen-Bonding Interaction

[K701-1pm-14] Unique effects of iodine substitution on the luminescence properties of halogenated thienyl diketone derivatives

[K701-1pm-15] Generation of photo-induced polarized electron spins at solid-liquid interfaces

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