Academic Program [Oral A]

[K705-1am] 15. Organic Chemistry -Aliphatic and Alicyclic Compounds, and New Synthetic Technology-

Wed. Mar 22, 2023 9:00 AM - 11:40 AM K705 (K705, Lecture Hall Bldg. [7F])

Chair: Shinichiro Fuse, Taku Kitanosono

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Break （9:00 AM - 9:10 AM）

9:10 AM - 9:20 AM

[K705-1am-01] Development of Continuous-flow Reductive N-Methylation of Secondary Amines with H₂ Using Supported Polysilane-Palladium Catalysts

^○Taisei Senzaki¹, Ken Nishizawa¹, Yuki Saito¹, Shu Kobayashi¹ (1. The University of Tokyo)

[Lang.] Japanese

9:20 AM - 9:30 AM

[K705-1am-02] Development of Continuous-flow Ritter Reactions for Amide Synthesis

^○Karin Sakamoto¹, Tomohiro Yasukawa¹, Kandasamy Mohanraj¹, Haruro Ishitani¹, Shu Kobayashi¹ (1. the University of Tokyo)

[Lang.] Japanese

9:30 AM - 9:40 AM

[K705-1am-03] Direct Dehydrative Amide Formation under Continuous-flow Conditions Using Mixed Metal Oxides as Solid Acid Catalysts

^○Kota Takeno¹, Haruro Ishitani¹, Masahiro Sasaya¹, Shū Kobayashi¹ (1. The University of Tokyo)

[Lang.] Japanese

9:40 AM - 9:50 AM

[K705-1am-04] Investigation into the effect of tertiary amine and Brønsted acid for rapid formation and amidation of mixed anhydride using a micro-flow reactor

^○TingHo Chen¹, Otoka Shamoto¹, Shinichiro Fuse¹ (1. Graduate School of Pharmaceutical Sciences, Nagoya University)

[Lang.] English

9:50 AM - 10:00 AM

[K705-1am-05] Development of micro-flow synthesis of asymmetrical H-phosphonate

^○Yuma Tanaka¹, Hiroshi Kitamura¹, Shinichiro Fuse¹ (1. Graduate School of Pharmaceutical Sciences, Nagoya University)

[Lang.] Japanese

10:00 AM - 10:10 AM

[K705-1am-06] Rapid synthesis of cyclic phosphotriesters via coupling-cyclization sequence in a micro-flow reactor.

^○Kohei Nakabayashi¹, Hiroshi Kitamura¹, Shinichiro Fuse¹ (1. Nagoya University)

[Lang.] Japanese

10:10 AM - 10:20 AM

[K705-1am-07] Development of the rapid nucleophilic substitution at the α-position of furan analogues using a micro-flow reactor

^○Yuma Matsuura¹, Hisashi Masui¹, Shinichiro Fuse¹ (1. Department of Basic Medicinal Sciences, Graduate School of Pharmaceutical Sciences, Nagoya University)

[Lang.] Japanese

Break （10:20 AM - 10:30 AM）

10:30 AM - 10:40 AM

[K705-1am-08] Sequential and Continuous-flow Synthesis of Tetraconazole Intermediate through Two Base-Catalyzed Reactions

^○Masahiro Sasaya¹, Haruro Ishitani¹, Shū Kobayashi¹ (1. The Univ. of Tokyo)

[Lang.] Japanese

10:40 AM - 10:50 AM

[K705-1am-09] Oximation of 2-Substituted Indoles in Water

^○Airu Hashidoko¹, Taku Kitanosono¹, Yasuhiro Yamashita¹, Shū Kobayashi¹ (1. The University of Tokyo)

[Lang.] Japanese

10:50 AM - 11:00 AM

[K705-1am-10] Development of Continuous-flow Asymmetric Hydrogenation Using Core/Shell-Type Support Immobilized Heterogeneous Catalysts

^○Tatsuya Kuremoto¹, Shu Kobayashi¹ (1. The University of Tokyo)

[Lang.] Japanese

11:00 AM - 11:10 AM

[K705-1am-11] Development of 1,4-Addition Reactions in Water Catalyzed by Rare Earth Hydroxides(1)

Taku Kitanosono¹, ^○Rina Osada¹, Tomoya Hisada¹, Yasuhiro Yamashita¹, Shū Kobayashi¹ (1. The University of Tokyo)

[Lang.] Japanese

11:10 AM - 11:20 AM

[K705-1am-12] Development of 1,4-Addition Reactions in Water Catalyzed by Rare Earth Hydroxides(2)

^○Tomoya Hisada¹, Rina Osada¹, Taku Kitanosono¹, Yasuhiro Yamashita¹, Shū Kobayashi¹ (1. The University of Tokyo)

[Lang.] Japanese

11:20 AM - 11:30 AM

[K705-1am-13] Synthesis of chiral metal-organic framework for biocompatible Lewis acid catalysis

^○Watchara Srimontree¹, Taku Kitanosono¹, Yasuhiro Yamashita¹, Shū Kobayashi¹ (1. The University of Tokyo)

[Lang.] English

11:30 AM - 11:40 AM

[K705-1am-14] Cyclic Carbonate Synthesis with Heterogeneous Catalysts under Continuous-flow Conditions

^○Zhibo Yu¹, Haruro Ishitani¹, Shu Kobayashi¹ (1. the Univ. of Tokyo)

[Lang.] English

Academic Program [Oral A]

[K704-1am] 15. Organic Chemistry -Aliphatic and Alicyclic Compounds, and New Synthetic Technology-

Wed. Mar 22, 2023 9:00 AM - 11:40 AM K704 (K704, Lecture Hall Bldg. [7F])

Chair: Kohei Fuchibe, Taiki Morita

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9:00 AM - 9:10 AM

[K704-1am-01] Development of tertiary amide-selective α-acylation

^○Kentaro Makino¹, Taiki Morita^1,2, Hiroyuki Nakamura^1,2 (1. School of Life Science and Technology, Tokyo Institute of Technology, 2. Laboratory for Chemistry and Life Science Institute of Innovative Research)

[Lang.] Japanese

9:10 AM - 9:20 AM

[K704-1am-02] Intramolecular Hydroarylation Reaction of 1,5-diaryl-1-pentynes

^○Kosho Makino^1,2, Shunsuke Sueki^1,2, Masahiro Anada^1,2 (1. Faculty of Pharmacy, Department of Pharmaceutical Sciences, Musashino University, 2. Research Institute of Pharmaceutical Sciences, Musashino University)

[Lang.] Japanese

9:20 AM - 9:30 AM

[K704-1am-03] [5 + 1] annulation of (phenylethyl)malonate toward synthesis of tetralins

^○Manami Yamaguchi¹, Mio Shimogaki¹, Yoshihiro Miyake¹, Morifumi Fujita¹ (1. Univ. of Hyogo)

[Lang.] Japanese

9:30 AM - 9:40 AM

[K704-1am-04] One-pot Synthesis of Polysubstituted Furans from Two Bromocarbonyl Compounds by Utilizing Organozinc Reagent

^○Ryo Hikima¹, Aika Takeshima², Taichi Kano¹ (1. Graduate School of Engineering, Tokyo Univ. of Agriculture and Technology, 2. Graduate School of Science, Kyoto University)

[Lang.] Japanese

9:40 AM - 9:50 AM

[K704-1am-05] A Functional Group Metathesis between Ketones and Esters via sequential Claisen/retro-Claisen Condensation

^○Hikaru Nakahara¹, Ryota Isshiki¹, Junichiro Yamaguchi¹ (1. Waseda University)

[Lang.] Japanese

9:50 AM - 10:00 AM

[K704-1am-06] Synthesis and reactivities of fluorinated p-quinone monoacetals

^○Kohei Azami¹, Keisuke Suzuki¹, Ken Ohmori¹ (1. Tokyo Institute of Technology)

[Lang.] Japanese

10:00 AM - 10:10 AM

[K704-1am-07] Development of efficient synthetic method for α,β-unsaturated thioesters from malonic acid half thioesters

^○Shun Kawasaki¹, Kengo Akagawa, Kazuaki Kudo¹ (1. IIS, The univ. of Tokyo)

[Lang.] Japanese

10:10 AM - 10:20 AM

[K704-1am-08] Click reaction of electron-rich aryl azides and product stabilization by intramolecular hydrogen bonding.

^○Teruki Ishihara¹, Hiroki Tanimoto¹, Takenori Tomohiro¹ (1. University of Toyama)

[Lang.] Japanese

Break （10:20 AM - 10:30 AM）

10:30 AM - 10:40 AM

[K704-1am-09] Synthesis of the Fluorescent-labeled Ridaifen, RID-B-BODIPY

Takatsugu Murata¹, Amane Yoneoka¹, ^○Kyoka Komukai¹, Yudai Yasukawa¹, YingJia Lu¹, Yuki Asahara¹, Motoyuki Shimonaka¹, Isamu Shiina¹ (1. Tokyo University of Science)

[Lang.] Japanese

10:40 AM - 10:50 AM

[K704-1am-10] Total Synthesisof Gentianaline B Bearing Bis-phosphocholine Moiety

Takatsugu Murata¹, Kiri Fukunishi¹, ^○Shunsei Hiraga¹, Kenta Uchida¹, Rio Seki², Misako Ohkusu², Katsuhiko Kamei², Akira Watanabe², Naruhiko Ishiwada², Takayuki Tonoi¹, Isamu Shiina¹ (1. Tokyo University of Science, 2. Chiba University)

[Lang.] Japanese

10:50 AM - 11:00 AM

[K704-1am-11] Total Synthesis of Eutyscoparol A

^○Takuto Iwayama¹, Takatsugu Murata¹, Ayana Shimauchi¹, Yukiho Kosaka¹, Isamu Shiina¹ (1. Tokyo University of Science)

[Lang.] Japanese

11:00 AM - 11:10 AM

[K704-1am-12] Improved Synthesis of Antitumor Compounds, M-COPA and Its Structure–activity Relationships

Takatsugu Murata¹, Hisazumi Tsutsui¹, Shintaro Hiraishi¹, ^○Daiki Usukura¹, Hiroki Okano ¹, Saki Kato ¹, Motoyuki Shimonaka¹, Isamu Shiina ¹ (1. Tokyo University of Science)

[Lang.] Japanese

11:10 AM - 11:20 AM

[K704-1am-13] The Synthesis of a Stereoisomer of AMF-14 at Fused Positions

Takatugu Murata¹, Hisazumi TsuTsui¹, Hiyou Natsukawa¹, Yuki Suzuki¹, ^○Fumiya Watabe¹, Ryo Hirata¹, Miyuki Natsume¹, Sho Ichikawa¹, Motoyuki Shimonaka¹, Isamu Shiina¹ (1. tokyo university of science)

[Lang.] Japanese

11:20 AM - 11:30 AM

[K704-1am-14] Efficient synthesis of ozonides under dry conditions

^○Mohamed R. El-kholany¹, Nana Kishimoto¹, Kenta Tanaka¹, Hiroyoshi Takamura¹, Isao Kadota¹ (1. The Univ. of Okayama)

[Lang.] English

11:30 AM - 11:40 AM

[K704-1am-15] Conversion of azido to diazo groups and expansion to its application to azide site-selective reactions

^○Ryo Adachi¹, Kodai Tanisawa¹, Hiroki Tanimoto¹, Takenori Tomohiro¹ (1. Univ. of Toyama)

[Lang.] Japanese

Academic Program [Oral A]

[K704-1pm] 15. Organic Chemistry -Aliphatic and Alicyclic Compounds, and New Synthetic Technology-

Wed. Mar 22, 2023 1:00 PM - 3:40 PM K704 (K704, Lecture Hall Bldg. [7F])

Chair: Naoki Mori, Takahiro Suzuki

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Break （1:00 PM - 1:50 PM）

1:50 PM - 2:00 PM

[K704-1pm-01] The synthetic studies of Phomonol(3)

^○Hajime Yokoyama¹, Kenji Tanagi¹, Masahiro Miyazawa¹ (1. University of Toyama)

[Lang.] Japanese

2:00 PM - 2:10 PM

[K704-1pm-02] Stereoselective Synthesis of Sterically Hindered 17α-Methyl Steroid Derivatives from Malononitriles via Oxidative Functionalization under O₂

^○Huazhuo Ban¹, Naoki Mori¹, Yujiro Hayashi¹ (1. Tohoku University)

[Lang.] English

2:10 PM - 2:20 PM

[K704-1pm-03] Circularly Polarized Light Induced Enantioselective Strecker Amino Acid Synthesis

^○Shun Kono¹, Chihiro Kase¹, Naoki Kubota¹, Tsuneomi Kawasaki¹ (1. Tokyo Univ. of Science)

[Lang.] Japanese

2:20 PM - 2:30 PM

[K704-1pm-04] Chirally and Chemically Reversible Strecker Reaction in Solid-state and Following Asymmetric Amplification

^○Yuya Masuda¹, Yutaro Machida¹, Yudai Tanaka¹, Tsuneomi Kawasaki¹ (1. Tokyo Univ. of Science)

[Lang.] Japanese

2:30 PM - 2:40 PM

[K704-1pm-05] Chiral recognition using chiral crystal of racemic cyanohydrin (2)

^○Yong Du Kim¹, Ayane Mitsuo¹, Takamori Segawa¹, Tsuneomi Kawasaki¹ (1. Tokyo Univ. of Science)

[Lang.] Japanese

Break （2:40 PM - 2:50 PM）

2:50 PM - 3:00 PM

[K704-1pm-06] Synthetic study of mycenolide A for elucidation of stereochemistry

^○Kyouhei Konishi¹, Ken-ichi Fuhshuku¹ (1. Meisei University)

[Lang.] Japanese

3:00 PM - 3:10 PM

[K704-1pm-07] Synthetic Studies on Acylated Cellulose using Ionic Liquids

^○Shuhei Miyahana¹, Yumiko Takagi¹ (1. Kagawa University)

[Lang.] Japanese

3:10 PM - 3:20 PM

[K704-1pm-08] Ring-opening reaction of cyclobutanones for synthesis of γ-aminobutyric acid esters

^○Ishin Tomiya¹, Yuhao Wu¹, Kengo Hyodo¹ (1. Kindai University)

[Lang.] Japanese

3:20 PM - 3:30 PM

[K704-1pm-09] Synthesis of Tricyclo[4.2.1.0^3,7]nonane Derivatives Using Skeletal Rearrangement of Tricyclic Compounds Containing a Norbornene Substructure

^○Akihiro Yoshitani¹, Tomonari Sasage², Ranmaru Kato², Kazutada Ikeuchi³, Keiji Tanino⁴ (1. Faculty of Science, Hokkaido Univ., 2. Graduate School of Chemical Science and Engineering, Hokkaido Univ., 3. Graduate School of Pharmaceutical Science, Nagoya city Univ., 4. Graduate School of Science, Hokkaido Univ.)

[Lang.] Japanese

3:30 PM - 3:40 PM

[K704-1pm-10] Catalytic phosphonylation with bis(2,2,2-trifluoroethyl) phosphite for the synthesis of dinucleoside phosphite diesters

^○Dario Mrdovic¹, Akira Matsunaga¹, Yuki Saito¹, Shu Kobayashi¹ (1. Graduate School of Science, The University of Tokyo)

[Lang.] English

Academic Program [Oral A]

[K704-1vn] 15. Organic Chemistry -Aliphatic and Alicyclic Compounds, and New Synthetic Technology-

Wed. Mar 22, 2023 4:10 PM - 6:40 PM K704 (K704, Lecture Hall Bldg. [7F])

Chair: Azusa Kondoh, Takuji Kawamoto

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4:10 PM - 4:20 PM

[K704-1vn-01] Synthesis of 1-(3-arylnaphthalen-1-yl)pyridin-2(1H)-one

^○Ryosuke Nishikuma¹, Syunya IKEDA¹, Karin HIROTA¹, Takuji KAWAMOTO¹, Akio KAMIMURA¹ (1. Yamaguchi University)

[Lang.] Japanese

4:20 PM - 4:30 PM

[K704-1vn-02] Synthesis of plasmalogen analogues

^○Yuri Higuma¹, Yudai Shishida¹, Hirokazu Shimooka¹, Tatsuo Okauchi¹, Mitsuru Kitamura¹ (1. Kyushu Institute University)

[Lang.] Japanese

4:30 PM - 4:40 PM

[K704-1vn-03] Facile construction of tropolone skeleton from dioxinone derivative

^○Sangeun Yeom¹, Keisuke Suzuki, Ken Ohmori (1. Tokyo Institute of Technology)

[Lang.] Japanese

4:40 PM - 4:50 PM

[K704-1vn-04] Intermolecular asymmetric iodazolation of alkenyl ethers using chiral dinuclear Zn bis(aminoimino)binaphthoxide complex

^○Emi Amma¹, Takayoshi Arai¹ (1. Graduate School of Science, Chiba University)

[Lang.] Japanese

4:50 PM - 5:00 PM

[K704-1vn-05] Development of enantioselective oxidative dimerization of 2-oxindoles using chiral bis-guanidium / hypoiodite catalyst

^○Yuta Shimizu¹, Io Mori¹, Kota Sugimoto¹, Xu Ban³, Choon-Hong Tan², Minami Odagi¹, Kazuo Nagasawa¹ (1. Tokyo University of Agriculture and Technology, 2. Nanyang Technological University, 3. Henan Normal University)

[Lang.] Japanese

5:00 PM - 5:10 PM

[K704-1vn-06] Development of Chiral Halonium Salt Catalysts with N-Nitrosamine Moiety and Their Applications

^○Tatsuya Ao¹, Yasushi Yoshida¹, Takashi Mino¹, Masami Sakamoto¹ (1. Chiba University)

[Lang.] Japanese

Break （5:10 PM - 5:20 PM）

5:20 PM - 5:30 PM

[K704-1vn-07] Synthesis of Vinylidenecyclopropanes via Gold(I)-Catalyzed Cyclopropanation of Stannylated Propargyl Esters

^○Hiroto Mori¹, Shota Nakagawa¹, Toshinobu Korenaga², Yoshikazu Horino¹ (1. Chitose Inst. Sci. Tech., 2. Iwate Univ.)

[Lang.] Japanese

5:30 PM - 5:40 PM

[K704-1vn-08] Synthesis and reactivity of 1,5-anthracenophane derivative with simple hydrocarbon ansa-chain

^○Hiroki Kashiwagura¹, Yixuan Zhu¹, Suzuki Keisuke¹, Ohmori Ken¹ (1. Tokyo Institute of technology)

[Lang.] Japanese

5:40 PM - 5:50 PM

[K704-1vn-09] Brønsted Base-Catalyzed Umpolung Addition Reaction of Aryl Ketones Utilizing [1,2]-Phospha-Brook Rearrangement

^○Hirochika Suzuki¹, Takayuki Hirozane¹, Azusa Kondoh¹, Masahiro Terada¹ (1. Tohoku University)

[Lang.] Japanese

5:50 PM - 6:00 PM

[K704-1vn-10] Brønsted Base-Catalyzed Reductive Deimination of
α-iminoketones

^○Seitaro Inoue¹, Rihaku Ojima¹, Azusa Kondoh¹, Masahiro Terada¹ (1. Tohoku University)

[Lang.] Japanese

6:00 PM - 6:10 PM

[K704-1vn-11] Synthesis and Stereochemical Analysis of Planar Chiral 3-Aza[7]orthopyridinophene

^○Ryo Yamaguchi¹, Chisato Iso², Yusuke Hatayama¹, Kazunobu Igawa³, Yuuya Kawasaki², Katsuhiko Tomooka^1,2 (1. IGSES, Kyushu Univ., 2. IMCE, Kyushu Univ., 3. FAST, Kumamoto Univ.)

[Lang.] Japanese

6:10 PM - 6:20 PM

[K704-1vn-12] Efficient Synthesis and Stereochemical Analysis of Planar Chiral 3-Oxa[7]orthocyclophene

^○Yukiho Hashimoto¹, Chisato Iso², Yuuya Kawasaki², Kazunobu Igawa³, Katsuhiko Tomooka^1,2 (1. IGSES, Kyushu Univ., 2. IMCE, Kyushu Univ., 3. FAST, Kumamoto Univ.)

[Lang.] Japanese

6:20 PM - 6:30 PM

[K704-1vn-13] Design, Synthesis, and Stereochemical Analysis of 2-Naphthylbenzoic Acid Esters having Dynamic Axial Chirality

^○Kotaro Uchiyama¹, Yuuya Kawasaki², Kazunobu Igawa³, Katsuhiko Tomooka^1,2 (1. IGSES, Kyushu Univ., 2. IMCE, Kyushu Univ., 3. FAST, Kumamoto Univ.)

[Lang.] Japanese

6:30 PM - 6:40 PM

[K704-1vn-14] Solid-phase synthesis of N-methylated oligopeptides

^○Kazuki Sato¹, Keiko Sekiguchi¹, Suzuki Ayaka¹, Takeshi Wada¹ (1. Tokyo Univ. Sci.)

[Lang.] Japanese

Academic Program [Oral A]

[K705-1vn] 15. Organic Chemistry -Aliphatic and Alicyclic Compounds, and New Synthetic Technology-

Wed. Mar 22, 2023 4:10 PM - 6:50 PM K705 (K705, Lecture Hall Bldg. [7F])

Chair: Ryota Isshiki, Yosuke ASHIKARI

+Add all to schedule

4:10 PM - 4:20 PM

[K705-1vn-01] Continuous-flow Carbon–Carbon Bond Forming Reactions Using Anion-exchange Resin Catalysts Prepared with Organic Porogens

^○Yuichi Furiya¹, Haruro Ishitani¹, Shū Kobayashi¹ (1. University of Tokyo)

[Lang.] Japanese

4:20 PM - 4:30 PM

[K705-1vn-02] Continuous Flow Enantioselective Cyclization of 1,6-Enynes Using Heterogeneous Chiral Rhodium Catalysts

^○Yuki Sato¹, Yuki Saito¹, Shu Kobayashi¹ (1. The University of Tokyo)

[Lang.] Japanese

4:30 PM - 4:40 PM

[K705-1vn-03] Hydrogenative Conversion of Biomass-derived Carboxylic Acids into Lactones on Platinum-loaded MOF Catalysts

Haruro Ishitani¹, ^○Takashi Uemura¹, Tomoya Kawase¹, Shū Kobayashi¹ (1. The Univ. of Tokyo Science)

[Lang.] Japanese

4:40 PM - 4:50 PM

[K705-1vn-04] Electrochemical Allylation Reactions of Carbonyl Compounds Catalyzed by MOF-derived single atom catalyst

^○Hanako Nakajima¹, Masuda Ryusuke¹, Yasukawa Tomohiro¹, Kitanosono Taku¹, Yamashita Yasuhiro¹, Kobayashi Shu¹ (1. The university of Tokyo)

[Lang.] Japanese

4:50 PM - 5:00 PM

[K705-1vn-05] Synthesis of polycyclic aromatics by mechanochemical cyclodehydrogenation reaction

^○Kanna Fujishiro¹, Lawrence Scott², Hideto Ito¹, Kenichiro Itami¹ (1. Nagoya Univ., 2. Boston College)

[Lang.] Japanese

5:00 PM - 5:10 PM

[K705-1vn-06] Microwave-specific Enhancement of Catalytic Asymmetric Nazarov Cyclization

^○Junichiro Fukuzumi¹, Tohru Yamada¹, Kodai Saito² (1. Keio University, 2. Hokkaido University of Education)

[Lang.] Japanese

5:10 PM - 5:20 PM

[K705-1vn-07] Attempts to Use Mechanochemical Reactions for All Synthetic Steps in Preparation of Bioactive Compounds

^○Emiru Baba¹, Koji Kubota^1,2, Hajime Ito^1,2 (1. Graduate School of Engineering, Hokkaido University, 2. WPI-ICReDD, Hokkaido University)

[Lang.] Japanese

Break （5:20 PM - 5:30 PM）

5:30 PM - 5:40 PM

[K705-1vn-08] Coupling Reactions Using Single-Walled Carbon Nanotube (SWNT)-Supported Catalysts in Water

^○Shunsuke Shiramizu¹, Taku Kitanosono¹, Yasuhiro Yamashita¹, Shū Kobayashi¹ (1. The University of Tokyo)

[Lang.] Japanese

5:40 PM - 5:50 PM

[K705-1vn-09] Development of Heterogeneous Rh catalysts for C–H amidation under Continuous-flow Conditions

Yuki Saito¹, ^○Taro Konno², Shū Kobayashi¹ (1. Synthetic Organic Chemistry Lab., Department of Chemistry, Grad. School of Science, The University of Tokyo., 2. Department of Chemistry, School of Science, The University of Tokyo)

[Lang.] Japanese

5:50 PM - 6:00 PM

[K705-1vn-10] Development of Depolymerization Reactions of PET using Bead Mill Technology

^○Tomoya Kawase¹, Haruro Ishitani¹, Shū Kobayashi¹ (1. The University of Tokyo)

[Lang.] Japanese

6:00 PM - 6:10 PM

[K705-1vn-11] Generation of Schlosser Bases by Using Flow Microreactors and Their Reaction

^○Hiroki Nakayama¹, Shintaro Kamio¹, Kazuhiro Okamoto¹, Keita Hukumoto¹, Takashi Tamaki¹, Yosuke Ashikari¹, Aiichiro Nagaki¹ (1. Hokkaido University)

[Lang.] Japanese

6:10 PM - 6:20 PM

[K705-1vn-12] Kinetic study of rapid reactions enabled by flow microreactors, and its application for coexistence-type reactions

^○Dong-eun YOO¹, Yosuke ASHIKARI¹, Kazuhiro OKAMOTO¹, Masatomo IWATA¹, kensuke MUTA¹, Hiroki SOUTOME¹, Tomoko KAWAGUCHI¹, Shuto OSHIDA¹, Hiroki NAKAYAMA¹, Kotaro MIZUGUCHI¹, Ryohei NAKASATO¹, Aiichiro NAGAKI¹ (1. Hokkaido University)

[Lang.] Japanese

6:20 PM - 6:30 PM

[K705-1vn-13] Generation and reactions of 4-pyridyl lithium using flow microreactors

^○Yusuke Kimuro^1,2, Yosuke Ashikari¹, Aiichiro Nagaki¹ (1. The Univ. of Hokkaido, 2. JUZEN CHEMICAL CORPORATION)

[Lang.] Japanese

6:30 PM - 6:40 PM

[K705-1vn-14] Mono-selective deuteration of lithium halocarbenoids using flow microreactors

^○Kensuke Muta^1,2, Kazuhiro Okamoto², Ryousuke Higuma², Yosuke Ashikari², Aiichiro Nagaki² (1. Central Glass Co., Ltd., 2. The Univ. of Hokkaido)

[Lang.] Japanese

6:40 PM - 6:50 PM

[K705-1vn-15] Kinetic syudy of Living Anion Copolymerization by Quench Flow Method

^○Shuto Oshida¹, Tomoko Kawaguchi¹, Hodaka Sakaue¹, Masahiro Takumi¹, Aiichiro Nagaki¹ (1. Hokkaido University)

[Lang.] Japanese

Academic Program [Oral A]

[K704-2pm] 15. Organic Chemistry -Aliphatic and Alicyclic Compounds, and New Synthetic Technology-

Thu. Mar 23, 2023 1:00 PM - 3:40 PM K704 (K704, Lecture Hall Bldg. [7F])

Chair: Kei Murakami, Keisuke Asano

+Add all to schedule

1:00 PM - 1:10 PM

[K704-2pm-01] Defluoroheteroarylation of Trifluoromethylarenes using Photoredox Catalyst and Tin Iodide

Naoki Sugihara¹, ^○Masayuki Abe¹, Yoshihiro Nishimoto¹, Makoto Yasuda¹ (1. Graduate School of Engineering, Osaka University)

[Lang.] Japanese

1:10 PM - 1:20 PM

[K704-2pm-02] Light-Gated Brominating Reagents for Tyrosine Modification

^○Rakuto YOSHIDA¹, Keisuke ASANO², Daisuke URAGUCHI² (1. Kyoto Univ., 2. Hokkaido Univ.)

[Lang.] Japanese

1:20 PM - 1:30 PM

[K704-2pm-03] Hydrogen Bond-Accelerated Decatungstate-Catalyzed C(sp³)-H Alkylation of 2-Methylphenylboronic Acid Derivatives

^○Hui Jiang¹, Takeru Torigoe², Yoichiro Kuninobu¹ (1. Kyushu Univ., 2. Kyoto Inst. of Tech.)

[Lang.] English

1:30 PM - 1:40 PM

[K704-2pm-04] Development of Photocatalytic Alkylation Reactions of Active Methylene Compounds with Non-activated Alkenes

^○Yoshihiro Ogasawara¹, Trisha Banik¹, Yasuhiro Yamashita¹, Shu Kobayashi¹ (1. The University of Tokyo)

[Lang.] Japanese

1:40 PM - 1:50 PM

[K704-2pm-05] Development of Photocatalytic Alkylation Reaction of Non-activated Alkenes in Flow System

^○Trisha Banik¹, Yoshihiro Ogasawara¹, Yasuhiro Yamashita¹, Shu Kobayashi¹ (1. The University of Tokyo)

[Lang.] English

1:50 PM - 2:00 PM

[K704-2pm-06] Synthesis of Alkylphosphonate Oligonucleotides through Light-Driven Radical-Polar Crossover

^○Kenji Ota¹, Kazunori Nagao¹, Dai Hata², Naoya Miyamoto², Ryosuke Tokunoh², Yusuke Sasaki², Hirohisa Ohmiya^1,3 (1. ICR, Kyoto Univ., 2. Takeda Pharmaceutical Company Limited, 3. JST PRESTO)

[Lang.] Japanese

2:00 PM - 2:10 PM

[K704-2pm-07] Development of new synthesis of α-halogenoammonium salts via the generation of α-ammonio radicals

^○Kazuki Hirate¹, Takumi Kinoshita¹, Youta Sakakibara¹, Kei Murakami¹ (1. Kwansei Gakuin University)

[Lang.] Japanese

2:10 PM - 2:20 PM

[K704-2pm-08] Construction of ring structures adjacent to ammonio groups promoted by photoredox catalyst

^○Aoi Yoshita¹, Yota Sakakibara¹, Kei Murakami¹ (1. Kwansei Gakuin University)

[Lang.] Japanese

Break （2:20 PM - 2:30 PM）

2:30 PM - 2:40 PM

[K704-2pm-09] Direct functionalization of monosubstituted pyrrolidines

^○Shoma Chiba¹, Kokoro Nowaki¹, Bumpei Maeda¹, Kei Murakami¹ (1. Kwansei Gakuin University)

[Lang.] Japanese

2:40 PM - 2:50 PM

[K704-2pm-10] Synthesis of 1,3-propanediamine scaffold via α-ammonio radical

^○Kosuke Hamawaki¹, Yuta Makihara¹, Bunpei Maeda¹, Yota Sakakibara¹, Kei Murakami¹ (1. Kwansei Gakuin University)

[Lang.] Japanese

2:50 PM - 3:00 PM

[K704-2pm-11] A Photoredox/Cobalt/N-Heterocyclic Carbene/Brønsted Base Cooperative Catalysis for Markovnikov Selective Hydroacylation of Alkenes

^○Yunosuke Takekawa¹, Masanari Nakagawa¹, Kazunori Nagao², Hirohisa Ohmiya^2,3 (1. Grad. Sch. Med. Sci., Kanazawa Univ., 2. ICR, Kyoto Univ., 3. JST PRESTO)

[Lang.] Japanese

3:00 PM - 3:10 PM

[K704-2pm-12] Facile Synthesis of 1,2-Amino Alcohols from Alcohols and Imines via a Photoinduced Hydrogen-Atom Transfer Catalysis

^○Joaquim Caner¹, Akira Matsumoto¹, Keiji Maruoka^1,2 (1. Kyoto University, 2. Guangdong University of Technology)

[Lang.] English

3:10 PM - 3:20 PM

[K704-2pm-13] γ-selective functionalization of amines enabled by intramolecular hydrogen atom transfer of α-ammonio radical

^○Kosuke Terada¹, Yota Sakakibara¹, Kei Murakami¹ (1. kwansei gakuin university)

[Lang.] Japanese

3:20 PM - 3:30 PM

[K704-2pm-14] Dehydrative Etherification of Alcohols Using Environmentally Benign Nanoporous Gold Photocatalysts

^○Takehiro Hiraoka¹, Masato Miyauchi¹, Vivek Raut², Naoki Asao¹ (1. Graduate School of Science and Technology, Shinshu University, 2. Research Initiatives for Supra-Materials, Shinshu University)

[Lang.] Japanese

3:30 PM - 3:40 PM

[K704-2pm-15] Photoredox-Catalyzed Acceptorless Dehydrogenative Cycloaddition

^○Haruka Fujimori^1,2, Kohsuke Ohmatsu^1,2, Takashi Ooi^1,2 (1. Grad. Sch. of Eng., Nagoya Univ., 2. ITbM, Nagoya Univ.)

[Lang.] Japanese

Academic Program [Oral A]

[K704-2vn] 15. Organic Chemistry -Aliphatic and Alicyclic Compounds, and New Synthetic Technology-

Thu. Mar 23, 2023 4:10 PM - 6:40 PM K704 (K704, Lecture Hall Bldg. [7F])

Chair: Kenichi Michigami, Minami Odagi

+Add all to schedule

4:10 PM - 4:20 PM

[K704-2vn-01] Iodocyanation of enamides catalyzed by trispentafluorophenylborane (BCF)

^○Ikumi Furusawa¹, Takumi Suzuki, Takayoshi Arai¹ (1. Graduate School of Science, Chiba University)

[Lang.] Japanese

4:20 PM - 4:30 PM

[K704-2vn-02] Machine-Learning Prediction of Catalytic Activity in Dehydrative
Amidation

^○Taiki Nagano¹, Naoki Noto², Susumu Saito^2,3 (1. Nagoya University, 2. Integrated Research Consortium on Chemical Sciences, Nagoya University (IRCCS, Nagoya Univ.), 3. Graduate School of Science, Nagoya University (Grad. Sch. Sci., Nagoya Univ.))

[Lang.] Japanese

4:30 PM - 4:40 PM

[K704-2vn-03] Development of chiral Lewis acid catalysis self-repairable in water

^○Taku Kitanosono¹, Fangqiu Lu¹, Yasuhiro Yamashita¹, Shu Kobayashi¹ (1. The University of Tokyo)

[Lang.] Japanese

4:40 PM - 4:50 PM

[K704-2vn-04] Scalling-up study for flow manufacturing of drug precursors

^○Yosuke ASHIKARI¹, Kei MAEKAWA¹, Aiichiro NAGAKI¹ (1. Hokkaido University)

[Lang.] Japanese

4:50 PM - 5:00 PM

[K704-2vn-05] Development of modular synthesis of polyamines

^○Tokihiro Furuhashi¹, Shintaro Matsumoto¹, Satoshi Matsubara², Kei Murakami¹ (1. Kwansei Gakuin University, 2. Nagoya University)

[Lang.] Japanese

5:00 PM - 5:10 PM

[K704-2vn-06] Access to ortho-Hydroxyphenyl Ketimines via Imine Anion-Mediated Smiles Rearrangement

^○Shunki Jinno¹, Takahiro Senoo¹, Keiji Mori¹ (1. Tokyo University of Agriculture and Technology)

[Lang.] Japanese

5:10 PM - 5:20 PM

[K704-2vn-07] Boronic Acid-Catalyzed Peptide Bond Formation Using Amino Esters

^○Naoya Takahashi¹, Airi Takahashi², Naoyuki Shimada² (1. Kitasato University, 2. Nihon University)

[Lang.] Japanese

Break （5:20 PM - 5:30 PM）

5:30 PM - 5:40 PM

[K704-2vn-08] Development of a new synthetic method for boryldienes by 1,3-boron shift reaction of homoallenylboronates

^○RYOTA SAKAMOTO¹, Minami Odagi¹, Kazuo Nagasawa¹ (1. Tokyo University of Agriculture and Technology)

[Lang.] Japanese

5:40 PM - 5:50 PM

[K704-2vn-09] Electrophilic cyclization via boronate complex enables the synthesis of fluoromethyl-substituted cyclopropanes

^○Natsuki Oyama¹, Hajime Ito^1,2 (1. Graduate School of Engineering, Hokkaido University , 2. WPI-ICReDD, Hokkaido University)

[Lang.] Japanese

5:50 PM - 6:00 PM

[K704-2vn-10] Deoxygenative Geminal Silylboration of Amides

^○Koh Watanabe¹, Kazunori Nagao², Hirohisa Ohmiya² (1. Grad. Sch. Med. Sci., Kanazawa Univ., 2. ICR, Kyoto Univ.)

[Lang.] Japanese

6:00 PM - 6:10 PM

[K704-2vn-11] Highly Effective 1,3,2-Dioxaborolan-4-one Catalyst for Dehydrative Condensation of Carboxylic Acids with Amines

^○Qianchun HUANG¹, Shuhei Ohmura¹, Kazuaki Ishihara¹ (1. Nagoya University)

[Lang.] English

6:10 PM - 6:20 PM

[K704-2vn-12] Development of new fluorinated electron-withdrawing boronic esters facilitating mild deprotonation adjacent to the boron atoms

^○Taiki Maeda¹, Taisei Kamiyanagi², Kenichi Michigami¹, Mitsuhiro Ueda¹, Masato Ohashi¹ (1. Osaka Metropolitan University, 2. Osaka Prefecture University)

[Lang.] Japanese

6:20 PM - 6:30 PM

[K704-2vn-13] Transformation of Boracycles to Carbocycles Utilizing Photochemically-Generated Siloxycarbenes

^○Yu Matsuoka¹, Eriko Saito¹, Yamaguchi Kohei¹, Kento Ishida¹, Ryosuke Masuda¹, Hiroyuki Kusama¹ (1. Gakushuin Univ.)

[Lang.] Japanese

6:30 PM - 6:40 PM

[K704-2vn-14] Wittig Reactions Using Ambiphilic Phosphine-Borane Compounds

^○Seiya Endo¹, Kazuishi Hukuda¹, Nobuharu Iwasawa¹, Jun Takaya¹ (1. Tokyo Institute of Technology)

[Lang.] Japanese

Academic Program [Oral A]

[K705-3am] 15. Organic Chemistry -Aliphatic and Alicyclic Compounds, and New Synthetic Technology-

Fri. Mar 24, 2023 9:00 AM - 11:40 AM K705 (K705, Lecture Hall Bldg. [7F])

Chair: Haruki Mizoguchi, Shuhei Kusumoto

+Add all to schedule

9:00 AM - 9:10 AM

[K705-3am-01] Chiral Iron(III)-catalyzed Enantioselective Oxidative [3+2] Cycloaddition of Phenols with Anethole

^○Kohsuke Nomura¹, Shuhei Ohmura¹, Kazuaki Ishihara¹ (1. The Univ. of Nagoya)

[Lang.] Japanese

9:10 AM - 9:20 AM

[K705-3am-02] Site-, Regio-, and Enantioselective [4+2] Cycloaddition of Oxidatively Generated ortho-Quinone Methides

^○Takaharu Morino¹, Takehiro Kato¹, Muhammet Uyanik¹, Kazuaki Ishihara¹ (1. Nagoya University)

[Lang.] Japanese

9:20 AM - 9:30 AM

[K705-3am-03] Cu/I Hybrid Catalysis for Enantioselective Aerobic Oxidative γ-Lactonization of δ-Oxocarboxylic Acids

^○Shunki Matsuyama¹, Soki Ihara¹, Takehiro Kato¹, Muhammet Uyanik¹, Kazuaki Ishihara¹ (1. Nagoya University)

[Lang.] Japanese

9:30 AM - 9:40 AM

[K705-3am-04] Enantioselective Aromatic Claisen Rearrangemnt of Allyl 2-Naphthyl Ethers Catalyzed by π–Cu(II) complexes

^○Kazuaki Ishihara¹, Lu Yao¹, Kazuki Takeda¹, Kaori Ando², Natsuhisa Oka² (1. Nagoya University, 2. Gifu University)

[Lang.] English

9:40 AM - 9:50 AM

[K705-3am-05] Carbon–carbon bond cleavage in alcoholysis of acetophenone mediated by europium complexes

^○Haruki Takarai¹, Soichiro Kohara¹, Shuhei Kusumoto¹, Kyoko Nozaki¹ (1. The University of Tokyo)

[Lang.] Japanese

9:50 AM - 10:00 AM

[K705-3am-06] Asymmetric iodoetherification using chiral multinuclear Zn bis(aminoimino)binaphthoxide complex with phenol substrates as nucleophiles

^○Yuki Namba¹, Takayoshi Arai¹ (1. Chiba university)

[Lang.] Japanese

10:00 AM - 10:10 AM

[K705-3am-07] Asymmetric Direct Mannich Reaction of α-Ketoesters Catalyzed by Sulfonamide-substituted Chiral Lewis Acid Catalyst

^○Takeru Abe¹, Haruki Mizoguchi¹, Akira Sakakura¹ (1. The Univ. of Okayama)

[Lang.] Japanese

10:10 AM - 10:20 AM

[K705-3am-08] One-pot catalytic reactions of phosphite diesters toward the synthesis of oligonucleotides

^○Akira Matsunaga¹, Dario Mrdović¹, Yuki Saito¹, Shū Kobayashi¹ (1. the University of Tokyo)

[Lang.] Japanese

Break （10:20 AM - 10:30 AM）

10:30 AM - 10:40 AM

[K705-3am-09] Design of Chiral Iron(III) Catalyst for Enantioselective Radical Cation [4+2] Cycloaddition of α,β-Unsaturated Carboxylic Acid Derivatives

^○Hayato Akao¹, Kei Katagiri¹, Shuhei Ohmura¹ (1. Nagoya University)

[Lang.] Japanese

10:40 AM - 10:50 AM

[K705-3am-10] Silver-catalyzed CO₂ Incorporation into Propargylic Amides

^○Seiya Uema¹, Tohru Yamada¹ (1. Keio University)

[Lang.] Japanese

10:50 AM - 11:00 AM

[K705-3am-11] Silver Catalyzed Formylation of Amines using Carbon Dioxide

^○Kenshiro Sekine¹, Ryotaro Aoshima¹, Seiya Uema¹, Kodai Saito², Tohru Yamada¹ (1. Keio University, 2. Hokkaido University of Education)

[Lang.] Japanese

11:00 AM - 11:10 AM

[K705-3am-12] Palladium-Catalyzed Intramolecular Allylation of Aldehydes through in Situ Generation of Allylsilanes

^○Haruya Hirano¹, Ayumu Natsubori¹, Yoshikazu Horino¹ (1. Chitose Inst. Sci. Tech.)

[Lang.] Japanese

11:10 AM - 11:20 AM

[K705-3am-13] Development and Catalytic Application of Novel Chiral Halonium Salts with Hydroxy Group

^○Shunki Tanaka¹, Yasushi Yoshida¹, Takashi Mino¹ (1. Faculty of Engineering, Chiba University)

[Lang.] Japanese

11:20 AM - 11:30 AM

[K705-3am-14] Decarboxylative Cyclization of Cyclic Carbonates for Stereoselective Preparation of Bicyclo[3.3.0]octane Skeleton

Risa Yamaguchi¹, ^○Tsukasa Amemiya¹, Yoichi Dokai¹, Tohru Yamada¹, Kodai Saito² (1. Keio University, 2. Hokkaido University of Education)

[Lang.] Japanese

11:30 AM - 11:40 AM

[K705-3am-15] Decarboxylative Coupling Reaction of Cyclic Carbonates and Ketene Silyl Acetals

^○Yoichi Dokai¹, Aoi Fujioka¹, Kodai Saito², Tohru Yamada¹ (1. Keio Univ., 2. Hokkaido Univ. of Education)

[Lang.] Japanese

Academic Program [Oral A]

[K704-3am] 15. Organic Chemistry -Aliphatic and Alicyclic Compounds, and New Synthetic Technology-

Fri. Mar 24, 2023 9:00 AM - 11:30 AM K704 (K704, Lecture Hall Bldg. [7F])

Chair: Ryosuke Masuda, Yuto Sumida

+Add all to schedule

9:00 AM - 9:10 AM

[K704-3am-01] Photoredox-catalyzed generation of α-ammoniovinyl radicals

^○Rina Tonedachi¹, Aoi Yoshita¹, Yota Sakakibara¹, Kei Murakami¹ (1. Kwansei gakuin university)

[Lang.] Japanese

9:10 AM - 9:20 AM

[K704-3am-02] meta-Selective Acylation of Electron-rich Arenes through N-Heterocyclic Carbene/Photoredox Catalysis

^○Yamato Goto¹, Masaki Sano¹, Yuto Sumida¹, Hirohisa Ohmiya^2,3 (1. Grad. Sch. Med. Sci., Kanazawa Univ., 2. ICR, Kyoto Univ., 3. JST PREST)

[Lang.] Japanese

9:20 AM - 9:30 AM

[K704-3am-03] A Photoredox/Cobalt Dual Catalysis for Markovnikov Selective Hydrohalogenation of Alkenes

^○Shotaro Shibutani¹, Kazunori Nagao¹, Hirohisa Ohmiya^1,2 (1. ICR, Kyoto Univ., 2. JST PRESTO)

[Lang.] Japanese

9:30 AM - 9:40 AM

[K704-3am-04] Development of Photocatalytic α-Alkylation Reactions of Silicon Enolates with Non-activated Alkenes

^○Damir Medunjanin¹, Yoshihiro Ogasawara¹, Yasuhiro Yamashita¹, Shu Kobayashi¹ (1. The University of Tokyo)

[Lang.] English

9:40 AM - 9:50 AM

[K704-3am-05] Efficient arylation of heteroatom nucleophiles through an interplay between a nickel complex and a titanium dioxide photocatalyst

^○Riku Hashimoto¹, Hiroya Tada¹, Jieun Jung¹, Shogo Mori², Susumu Saito^2,1 (1. Grad. Sch. Sci., Nagoya Univ., 2. IRCCS, Nagoya Univ.)

[Lang.] Japanese

9:50 AM - 10:00 AM

[K704-3am-06] Water-controlled C(sp³)–H bond functionalization of ethers under Ag/TiO₂ photocatalysis

^○Buddhini Ranasinghe¹, Shogo Mori², Susumu Saito^1,2 (1. Graduate School of Science, Nagoya University, 2. IRCCS, Nagoya University)

[Lang.] English

10:00 AM - 10:10 AM

[K704-3am-07] Synthesis of a-Hydroxyamino Carbonyl Compounds by Acyl Radical Addition to Nitrones Using Photoredox Catalyst

^○Tadachika Matsudaira¹, Ken Yamanomoto¹, Takahiko Akiyama¹ (1. Gakushuin University)

[Lang.] Japanese

Break （10:10 AM - 10:20 AM）

10:20 AM - 10:30 AM

[K704-3am-08] Catalytic Three-Component Cycloaddition Reaction Triggered by Single-Electron Oxidation of Phosphorus Ylide

^○Ryuhei Suzuki^1,2, Kohsuke Ohmatsu^1,2, Takashi Ooi^1,2 (1. Graduate School of Engneering, Nagoya Univ., 2. ITbM, Nagoya Univ.)

[Lang.] Japanese

10:30 AM - 10:40 AM

[K704-3am-09] Novel Methodology for Synthesis of 2-Fluoropyrrole Derivatives Utilizing Photoinduced Electron Transfer and S_NV Reactions

^○Minori Chaya¹, Ryosuke Masuda¹, Hiroyuki Kusama¹ (1. Gakushuin University)

[Lang.] Japanese

10:40 AM - 10:50 AM

[K704-3am-10] Visible light–promoted regioselective functionalization of allylamines by dual–role catalysis of thiobenzoic acid

^○Masashi Fujita¹ (1. University of Shizuoka)

[Lang.] Japanese

10:50 AM - 11:00 AM

[K704-3am-11] N-Methylation of amino acids and peptides using a metal-loaded titanium dioxide photocatalyst and methanol

^○Yuki Hashiba¹, Ivven Huang¹, Hiroshi Naka³, Shogo Mori², Susumu Saito^1,2 (1. Grad. Sch. Sci., Nagoya Univ., 2. IRCCS, Nagoya Univ., 3. Grad. Sch. Pharm., Kyoto Univ.)

[Lang.] Japanese

11:00 AM - 11:10 AM

[K704-3am-12] Dimerization of Benzyl Chlorides using Zirconocene and Photoredox Catalysis

^○Keisuke Tanaka¹, Kazuhiro AIDA¹, Eisuke OTA¹, Junichiro YAMAGUCHI¹ (1. Waseda University)

[Lang.] Japanese

11:10 AM - 11:20 AM

[K704-3am-13] Development of 4-borylthiophenols as multifunctional photocatalysts: application to the synthesis of 1,2-diol or 1,2-amino alcohol derivatives

^○Kikura Takeru¹, Yuya Taura¹, Yoshitaka Aramaki¹, Takashi Ooi¹ (1. Graduate School of Engineering, Nagoya University : ITbM, Nagoya University)

[Lang.] Japanese

11:20 AM - 11:30 AM

[K704-3am-14] Substrate-Specific Oxidation in a Coordination Cage by Capping the Portal with a Tripodal Copper Catalyst

^○Wei He¹, Hiroki Takezawa¹, Makoto Fujita^1,2 (1. The Univ. of Tokyo, 2. Institute for Molecular Science)

[Lang.] English

Academic Program [Oral A]

[K704-3pm] 15. Organic Chemistry -Aliphatic and Alicyclic Compounds, and New Synthetic Technology-

Fri. Mar 24, 2023 1:00 PM - 3:40 PM K704 (K704, Lecture Hall Bldg. [7F])

Chair: Kohei Sato, Mitsuru Shoji

+Add all to schedule

1:00 PM - 1:10 PM

[K704-3pm-01] Microwave flow chemistry: Machine learning to predict outlet temperatures of single and mixed solvents

^○Kaishi ISOBE¹, Kohei SATO¹, Tetsuo NARUMI¹, Kazuhiro TAKEDA¹, Nobuyuki MASE¹ (1. Shizuoka University)

[Lang.] Japanese

1:10 PM - 1:20 PM

[K704-3pm-02] Fine bubble organic chemistry: Gas tunnel effect of ultrafine bubbles to promote gas-liquid-solid phase reactions

^○Tomoki KOZUKA¹, Kohei SATO¹, Tetsuo NARUMI¹, Nobuyuki MASE¹ (1. Shizuoka University)

[Lang.] Japanese

1:20 PM - 1:30 PM

[K704-3pm-03] Microwave flow chemistry: Rapid yield and productivity optimization of organic reactions for social implementation

^○Jun UEDA¹, Kohei SATO¹, Tetsuo NARUMI¹, Kazuhiro TAKEDA¹, Nobuyuki MASE¹ (1. Shizuoka University)

[Lang.] Japanese

1:30 PM - 1:40 PM

[K704-3pm-04] Green manufacturing: Multi-variable optimization of reaction conditions by unsteady flow method

^○Naoki MIYASHITA¹, Kohei SATO¹, Tetsuo NARUMI¹, Kazuhiro Takeda¹, Nobuyuki MASE¹ (1. Shizuoka University)

[Lang.] Japanese

1:40 PM - 1:50 PM

[K704-3pm-05] Fine bubble organic chemistry: Reducing agent-free ozonolysis

^○Hiroto SAKURAI¹, Yuta SUMII², Shogo HANADA², Kohei SATO¹, Tetsuo NARUMI¹, Nobuyuki MASE¹ (1. Shizuoka University, 2. Astellas Pharma Inc.)

[Lang.] Japanese

1:50 PM - 2:00 PM

[K704-3pm-06] Green manufacturing: Short-step synthesis of fairy chemicals toward industrial production

^○Arun Kumar Manna¹, Kohei SATO¹, Tetsuo NARUMI¹, Kazuhiro TAKEDA¹, Nobuyuki MASE¹ (1. Shizuoka University)

[Lang.] English

2:00 PM - 2:10 PM

[K704-3pm-07] Reductive Borylmetallation of Alkenes Using Flow Microreactors

^○Kazuki Nishihara¹, Yiyuan Jiang¹, Hideki Yorimitsu¹ (1. Kyoto University)

[Lang.] Japanese

2:10 PM - 2:20 PM

[K704-3pm-08] Atom-Economical Synthesis of N-Aryl Amides Utilizing Catalytic Amidation of Vinyl Esters

^○Tomohiro Ichitsuka¹, Takashi Makino¹, Takayuki Ishizaka¹ (1. National Institute of Advanced Industrial Science and Technology)

[Lang.] Japanese

Break （2:20 PM - 2:30 PM）

2:30 PM - 2:40 PM

[K704-3pm-09] Construction of Heterogeneous Chiral Potassium Catalyst Systems and Application to Continuous-flow Reactions

^○Tomoya Kimura¹, Yasuhiro Yamashita¹, Shū Kobayashi¹ (1. The University of Tokyo)

[Lang.] Japanese

2:40 PM - 2:50 PM

[K704-3pm-10] Development of Heterogeneous Lewis Acid Catalysts Supported on Single-Walled Carbon Nanotubes for Reactions in Water and Evaluation of their Reusability

^○Satoshi Tanaka¹, Taku Kitanosono¹, Yasuhiro Yamashita¹, Shū Kobayashi¹ (1. The University of Tokyo)

[Lang.] Japanese

2:50 PM - 3:00 PM

[K704-3pm-11] Real-Time Analysis of Living Anionic Polymerization by Flow Inline IR

Rikako Yoshioka¹, Yosuke Ashikari², ^○aiichiro nagaki² (1. Kyoto University, 2. Hokkaido University)

[Lang.] Japanese

3:00 PM - 3:10 PM

[K704-3pm-12] Rapid amidation reaction in aqueous media enebled by flow microreactor

^○Kotaro Mizuguchi¹ (1. Hokkaido University)

[Lang.] Japanese

3:10 PM - 3:20 PM

[K704-3pm-13] Generation of carbocations triggered by protic acid and their integrated reaction with carbanions by flow microreactors

^○Hiroki Soutome^1,2, Hiroki Yamashita¹, Yusuke Kimuro¹, Yousuke Ashikari¹, Masahiro Takumi¹, Aiichiro Nagaki¹ (1. Hokkaido University, 2. AGC Inc.)

[Lang.] Japanese

3:20 PM - 3:30 PM

[K704-3pm-14] Rapid flow epoxidation of cyclohexene via air oxidation

^○Kyoko Mandai^1,2, Tetsuya Yamamoto¹, Hiroki Mandai², Aiichiro Nagaki¹ (1. Hokkaido Univ., 2. Gifu Univ. of Medical Science)

[Lang.] Japanese

3:30 PM - 3:40 PM

[K704-3pm-15] Switchable Chemoselectivity of Reactive Intermediates Formation Using Flow Microreactors

^○Tomoko Kawaguchi¹, Yosuke Ashikari¹, Takashi Tamaki¹, Mai Furusawa¹, Yuya Yonekura¹, Yoko Aizawa¹, Yusuke Takahashi¹, Aiichiro Nagaki¹ (1. Hokkaido University)

[Lang.] Japanese

Academic Program [Oral A]

[K705-3vn] 15. Organic Chemistry -Aliphatic and Alicyclic Compounds, and New Synthetic Technology-

Fri. Mar 24, 2023 4:10 PM - 6:30 PM K705 (K705, Lecture Hall Bldg. [7F])

Chair: Shuhei Omura, Tatsuhiro Uchikura

+Add all to schedule

4:10 PM - 4:20 PM

[K705-3vn-01] Brønsted Base-Catalyzed Addition Reaction of Diarylmethyl Anions Utilizing [1,2]-Phospha-Brook Rearrangement

^○Azusa Kondoh¹, Masahiro Terada¹ (1. Tohoku University)

[Lang.] Japanese

4:20 PM - 4:30 PM

[K705-3vn-02] Phosphine Oxide–Silyl Lewis Acid Cooperative Catalyst for Iodochlorination of Alkenes

^○Keigo Nagami¹, Shuhei Ohmura¹, Kazuaki Ishihara¹ (1. Nagoya University)

[Lang.] Japanese

4:30 PM - 4:40 PM

[K705-3vn-03] Chiral Organoiodine(III)-catalyzed Enantioselective Oxidative Biaryl Coupling of 2-Alkoxynaphthalenes

^○Shunsuke Minabe¹, Hiroki Tanaka, Muhammet Uyanik¹, Kazuaki Ishihara¹ (1. Nagoya University)

[Lang.] Japanese

4:40 PM - 4:50 PM

[K705-3vn-04] Phase-transfer-catalyzed Oxidative Chlorocyclization Reactions Using Chloride and Oxone

^○Yuto Fujii¹, Takehiro Kato¹, Muhammet Uyanik¹, Kazuaki Ishihara¹ (1. Nagoya University)

[Lang.] Japanese

4:50 PM - 5:00 PM

[K705-3vn-05] Construction of three contiguous stereocenters through amino acid-catalyzed asymmetric aldol reactions

^○Ryoga Hikawa¹, Mio Shimogaki², Taichi Kano¹ (1. Graduate School of Engineering, Tokyo University of Agriculture and Technology, 2. Graduate School of Science, University of Hyogo)

[Lang.] Japanese

5:00 PM - 5:10 PM

[K705-3vn-06] Enantioselective Friedel-Crafts alkylation reaction of heterocyclic compounds and trifluoromethyl ketimines using chiral phosphoric acid

^○Chihiro Narita¹, Yusuke Suda¹, Tatsuhiro Uchikura¹, Takahiko Akiyama¹ (1. Gakushuin University)

[Lang.] Japanese

5:10 PM - 5:20 PM

[K705-3vn-07] Enantioselective Chiral Metal Phosphate Catalyzed Reduction of β-Trifluoromethyl Nitroalkenes

^○Yuki Kaneko¹, Takanobu Setogawa¹, Tatsuhiro Uchikura¹, Takahiko Akiyama¹ (1. GakushuinUniversity)

[Lang.] Japanese

Break （5:20 PM - 5:30 PM）

5:30 PM - 5:40 PM

[K705-3vn-08] Enantioselective Organocatalyzed [4+2] Cycloaddition of 3-Hydroxy-2-Pyrone

^○Xianghao Li¹, Masahisa Nakada¹ (1. Waseda University)

[Lang.] Japanese

5:40 PM - 5:50 PM

[K705-3vn-09] One-pot synthesis of chiral multi-substituted trans-hydrindanes via organocatalyst-mediated three-component reaction

^○Naoki Mori¹, Toshiki Tachibana¹, Nariyoshi Umekubo¹, Yujiro Hayashi¹ (1. Tohoku Univ.)

[Lang.] English

5:50 PM - 6:00 PM

[K705-3vn-10] Six-membered Ring Bromoetherification of Alkenyl Alcohols Using N-oxide Catalyst

^○Hoshino Yuki¹, Moriyama Katsuhiko¹ (1. Chiba University)

[Lang.] Japanese

6:00 PM - 6:10 PM

[K705-3vn-11] Formal Ring Contraction of Cyclic N-Sulfonamides via C–N Bond Cleavage and α-Amination by Oxidation of Halides

^○Katsuhiko Moriyama¹, Yuna Nishiguchi¹, Akihiko Tomizuka¹ (1. Chiba University)

[Lang.] Japanese

6:10 PM - 6:20 PM

[K705-3vn-12] Development of a method for the construction of a 7-norbornanone skeleton using 1,4-bis(silyloxy)-1,3-cyclopentadienes

^○Yoshito Hirokawa¹, Tomonari Sasage¹, Kazutada Ikeuchi², Keiji Tanino³ (1. Graduate School of Chemical Science and Engineering, Hokkaido University, 2. Graduate School of Pharmaceutical Science, Nagoya city Univ, 3. Graduate School of Science, Hokkaido University)

[Lang.] Japanese

6:20 PM - 6:30 PM

[K705-3vn-13] Nucleophilic Substitution of Chiral Siladihydroisobenzofuran: Analysis of Stereochemical Course and Synthetic Application

^○Teppei Yamane¹, Kazunobu Igawa², Katsuhiko Tomooka^1,3 (1. IGSES, Kyushu Univ., 2. FAST, Kumamoto Univ., 3. IMCE, Kyushu Univ.)

[Lang.] Japanese

Academic Program [Oral A]

[K704-3vn] 15. Organic Chemistry -Aliphatic and Alicyclic Compounds, and New Synthetic Technology-

Fri. Mar 24, 2023 4:10 PM - 6:20 PM K704 (K704, Lecture Hall Bldg. [7F])

Chair: Kensuke Kiyokawa, Yasunori Toda

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4:10 PM - 4:20 PM

[K704-3vn-01] Chiral copper catalyzed-enantioselective radical carbo-oxygenation of alkenes

^○Yujin Shimizu¹, Yasunori Toda¹, Hiroyuki Suga¹ (1. Shinshu University)

[Lang.] Japanese

4:20 PM - 4:30 PM

[K704-3vn-02] p-Methoxybenzyl-Radical-Promoted Chemoselective Protection of sec-Alkylamides

^○JINGWEN JIA¹, Terumasa Kato², Keiji Maruoka^1,2 (1. Kyoto University, 2. Guangdong University of Technology)

[Lang.] English

4:30 PM - 4:40 PM

[K704-3vn-03] Intermolecular C(sp³)–H amination Enabled by Visible-Light-Excited (Diarylmethylene)aminobenziodoxolones

^○Mari Sugimura¹, Kensuke Kiyokawa¹, Satoshi Minakata¹ (1. Osaka University)

[Lang.] Japanese

4:40 PM - 4:50 PM

[K704-3vn-04] Stereoselective Diamination of α, β-Unsaturated Carbonyl Compounds Catalyzed by N, N-Dihalosulfonamides.

^○Takeshi Sugiyama¹, Satoshi Minakata¹ (1. Osaka University)

[Lang.] Japanese

4:50 PM - 5:00 PM

[K704-3vn-05] Ring-opening radical reactions using vinyl cyclic perfluoroalkane sulfonamides

^○Moeri Terauchi¹, Takahiro Kawabata¹, Tetsushi Yamasaki¹, Takuji Kawamoto¹, Akio Kamimura¹ (1. Yamaguchi University)

[Lang.] Japanese

5:00 PM - 5:10 PM

[K704-3vn-06] Design of Amidate HAT Catalyst for Direct Functionalization of Unbiased C(sp³)–H Bonds

^○Soichiro Mori^1,4, Lukas Entgelmeier², Ryuhei Suzuki ^3,4, Olga Garcia Mancheño², Kohsuke Ohmatsu^3,4, Takashi Ooi^3,4 (1. Nagoya Univ., 2. University of Münster, 3. Grad. Sch. of Eng., Nagoya Univ., 4. ITbM, Nagoya Univ.)

[Lang.] Japanese

Break （5:10 PM - 5:20 PM）

5:20 PM - 5:30 PM

[K704-3vn-07] Development of radical silylation reaction using silylated vitamin C derivatives

^○Tamaki Agematsu¹ (1. Kanagawa University)

[Lang.] Japanese

5:30 PM - 5:40 PM

[K704-3vn-08] Synthesis of multi-substituted naphthalenes by hydride-shift mediated C-H bond functionalization/Krapcho decarboxylation sequence

^○Kotaro Amano¹, Keiji Mori¹ (1. Tokyo University of Agriculture and Technology)

[Lang.] Japanese

5:40 PM - 5:50 PM

[K704-3vn-09] Double C(sp³)-H bond functionalization based on traceless activating group strategy: effective approach to fused-carbocyclic skeleton.

^○Takayuki Matsuno¹, Keiji Mori¹ (1. Tokyo University of Agriculture and Technology)

[Lang.] Japanese

5:50 PM - 6:00 PM

[K704-3vn-10] Construction of fused-carbocycles via hydride shift-mediated C(sp³)-H bond functionalization at a position of aliphatic methylene group.

^○Hiroto Okawa¹, Keiji Mori¹, Dan Sakai¹ (1. Tokyo University of Agriculture and Technology)

[Lang.] Japanese

6:00 PM - 6:10 PM

[K704-3vn-11] Double C(sp³)-H bond functionalization at α,β-positions of nitrogen atom based on double redox processes

^○Ryosuke Yamagishi¹, Keiji Mori¹ (1. Tokyo University of Agriculture and Technology)

[Lang.] Japanese

6:10 PM - 6:20 PM

[K704-3vn-12] Selective Generation of Carbon-centered Radicals via Semiconductor-photocatalyzed Oxidation of α-Hydroxyesters for Organic Synthesis

^○Shu Sakurai¹, Shogo Mori², Susumu Saito^1,2 (1. Grad. Sch. Sci., Nagoya Univ., 2. IRCCS, Nagoya Univ.)

[Lang.] Japanese

Academic Program [Oral A]

[K704-4am] 15. Organic Chemistry -Aliphatic and Alicyclic Compounds, and New Synthetic Technology-

Sat. Mar 25, 2023 9:00 AM - 11:20 AM K704 (K704, Lecture Hall Bldg. [7F])

Chair: Takeru Torigoe, Tsuyuka Sugiishi

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9:00 AM - 9:10 AM

[K704-4am-01] Metal-Free Visible-Light-Induced Bromo-Perfluoroalkylation of Olefins

^○Koto Tagami¹, Yajima Tomoko¹ (1. Ochanomizu University)

[Lang.] Japanese

9:10 AM - 9:20 AM

[K704-4am-02] The studies of the addition of a trifluoromethyl radical to vinyl triflates

^○Mai Hisayuki¹, Takuji KAWAMOTO¹, Akio KAMIMURA¹ (1. Yamaguchi University)

[Lang.] Japanese

9:20 AM - 9:30 AM

[K704-4am-03] Benzylic Difluorination of 2-Methylbenzenesulfonate Salts using Selectfluor under UV Irradiation

^○Jialin Zeng¹, Takeru Torigoe², Yoichiro Kuninobu¹ (1. Kyushu Univ., 2. Kyoto Inst. of Tech.)

[Lang.] Japanese

9:30 AM - 9:40 AM

[K704-4am-04] Chiral Organoiodine(III)-catalyzed Enantioselective Oxidative Dearomative Fluorination of Arenols

^○Shogo Yamamoto¹, Hiroki Tanaka¹, Muhammet Uyanik¹, Kazuaki Ishihara¹ (1. Nagoya University)

[Lang.] Japanese

9:40 AM - 9:50 AM

[K704-4am-05] Reductive transformation of perfluorocarboxylic acids

^○Shota Suzuki¹, Asuka Chiba¹, Tsuyuka Sugiishi¹, Soshi Shiraishi¹, Hideki Amii¹ (1. Gunma University)

[Lang.] Japanese

9:50 AM - 10:00 AM

[K704-4am-06] Synthetic Applications of Aryl Difluoromethylsilanes with various substituents.

^○Kanami Matsui¹, Toshiki Yamaguchi¹, Tsuyuka Sugiishi¹, Hideki Amii¹ (1. Gunma University)

[Lang.] Japanese

10:00 AM - 10:10 AM

[K704-4am-07] Proline derivatives-mediated asymmetric aldol and Mannich reactions of ethyl trifluoropyruvate

^○Hinata Odaira¹, Naoki Mori¹, Yujiro Hayashi¹ (1. Tohoku Univ.)

[Lang.] English

Break （10:10 AM - 10:20 AM）

10:20 AM - 10:30 AM

[K704-4am-08] Development of recoverable and reusable reagents for aromatic trifluoromethylation (1)

Mizuki Kita¹, Akari Matsuoka¹, Takuto Mimura¹, Sichen Yue¹, Kazuki Komoda¹, Tsuyuka Sugiishi¹, ^○Hideki Amii¹ (1. Gunma University)

[Lang.] Japanese

10:30 AM - 10:40 AM

[K704-4am-09] Development of recoverable and reusable reagents for aromatic trifluoromethylation (2)

^○Akari Matsuoka¹, Mizuki Kita¹, Tuyuka Sugiishi¹, Hideki Amii¹ (1. Gunma University)

[Lang.] Japanese

10:40 AM - 10:50 AM

[K704-4am-10] Lithium Assisted visible light driven Photoreduction of Trifluoromethylarene to Synthesize Difluoroalkane

^○Fua Akutsu¹, Haruna Tani¹, Tatsuhiro Uchikura¹, Takahiko Akiyama¹ (1. Gakushuin University)

[Lang.] Japanese

10:50 AM - 11:00 AM

[K704-4am-11] Multiselective Diels–Alder Reaction of α-Arylacroleins Catalyzed by Boron Tribromide-Assisted Chiral Phosphoric Acids

^○Kai Matsui¹, Manabu Hatano², Kazuaki Ishihara¹ (1. Nagoya University, 2. Kobe Pharmaceutical University)

[Lang.] English

11:00 AM - 11:10 AM

[K704-4am-12] Asymmetric conjugate addition of trialkenylboroxines to enone diesters using a hybrid Cu-catalyst system

^○Noritaka Kunitomo¹, Kento Yasumoto², Taichi Kano¹ (1. Graduate School of Engineering, Tokyo University of Agriculture and Technology, 2. Graduate school of Science, Kyoto University)

[Lang.] Japanese

11:10 AM - 11:20 AM

[K704-4am-13] Lewis Acid-catalyzed Decarboxylative Cyanation of Cyclic Enol Carbonates

^○Haruki Yokoyama¹, Yoichi Dokai¹, Natsuki Kimaru¹, Kodai Saito², Tohru Yamada¹ (1. Keio University, 2. Hokkaido University of Education)

[Lang.] Japanese

Sessions

15. Organic Chemistry -Aliphatic and Alicyclic Compounds, and New Synthetic Technology- » Oral A

[K705-1am] 15. Organic Chemistry -Aliphatic and Alicyclic Compounds, and New Synthetic Technology-

[K704-1am] 15. Organic Chemistry -Aliphatic and Alicyclic Compounds, and New Synthetic Technology-

[K704-1pm] 15. Organic Chemistry -Aliphatic and Alicyclic Compounds, and New Synthetic Technology-

[K704-1vn] 15. Organic Chemistry -Aliphatic and Alicyclic Compounds, and New Synthetic Technology-

[K705-1vn] 15. Organic Chemistry -Aliphatic and Alicyclic Compounds, and New Synthetic Technology-

[K704-2pm] 15. Organic Chemistry -Aliphatic and Alicyclic Compounds, and New Synthetic Technology-

[K704-2vn] 15. Organic Chemistry -Aliphatic and Alicyclic Compounds, and New Synthetic Technology-

[K705-3am] 15. Organic Chemistry -Aliphatic and Alicyclic Compounds, and New Synthetic Technology-

[K704-3am] 15. Organic Chemistry -Aliphatic and Alicyclic Compounds, and New Synthetic Technology-

[K704-3pm] 15. Organic Chemistry -Aliphatic and Alicyclic Compounds, and New Synthetic Technology-