Academic Program [Oral B]

[K505-1pm] 09. Coordination Chemistry, Organometallic Chemistry

Wed. Mar 22, 2023 1:10 PM - 3:40 PM K505 (K505, Lecture Hall Bldg. [5F])

Chair: Naoki Ishida, Yoshiaki Tanabe

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1:10 PM - 1:30 PM

[K505-1pm-01] Construction of Molecular Gears Based on Lanthanoid Double-decker Complexes with Phthalocyanine and Naphthalocyanine Functionalized with Four Planar Peripheral Substituents

^○Jeevithra Dewi Subramaniam¹, Toshio Nishino¹, Gwénaël Rapenne^1,2 (1. Nara Institute of Science and Technology, 2. University of Toulouse, France)

[Lang.] English

1:30 PM - 1:50 PM

[K505-1pm-02] Photoluminescence Properties of Mononuclear Europium(III) and Gadolinium(III) Complexes with Tetradentate Schiff Base Ligands in the Solid State

^○Masanobu Tsuchimoto¹, Toshiki Sakata¹, Naoki Takeda¹, Shuhei Itoh¹, Tomoaki Sugaya¹, Hyuma Masu², Masayuki Watabnabe³ (1. Chiba Institute of Technology, 2. Chiba University, 3. Japan Atomic Energy Agency )

[Lang.] Japanese

1:50 PM - 2:10 PM

[K505-1pm-03] Synthesis of Dinuclear Titanium Oxalate Complexes Supported by a Tris(phenolato)amine Ligand

^○Akira Okumura¹, Florentine Mohr¹, Thomas Paul Spaniol¹, Jun Okuda¹ (1. RWTH Aachen Univ.)

[Lang.] English

2:10 PM - 2:30 PM

[K505-1pm-04] Transformation of dinitrogen and alkenes to alkyl amines at a trititanium polyhydride framework

^○Takanori Shima¹, Ping Wu², Ryota Owada¹, Gen Luo², Zhaomin Hou¹ (1. RIKEN, 2. Anhui University)

[Lang.] Japanese

Break （2:30 PM - 2:40 PM）

2:40 PM - 3:00 PM

[K505-1pm-05] Transformation of Pyridines to Cyclopentadienyl Units by Denitrogenation in a PNP-Ligated Dititanium Hydride Framework

^○Xiaoxi ZHOU¹, Qingde ZHUO ¹, Takanori SHIMA¹, Xiaohui KANG², Zhaomin HOU¹ (1. RIKEN, 2. Dalian Medical University)

[Lang.] English

3:00 PM - 3:20 PM

[K505-1pm-06] Reaction of a Titanium Dinitrogen Complex Bearing an (ONO)-Ligand with CO₂ and CS₂

^○Yutaka Ishida¹, Sui Hasegawa¹, Hiroyuki Kawaguchi¹ (1. Tokyo Institute of Technology)

[Lang.] Japanese

3:20 PM - 3:40 PM

[K505-1pm-07] Precise control of metal-centered chirality of pentacoordinate chiral-at-vanadium(V) complexes using chiral auxiliaries

^○Ayako Hino¹, Koichi Nagata¹, Hitoshi Ube¹, Mitsuhiko Shionoya¹ (1. The Univ. of Tokyo)

[Lang.] English

Academic Program [Oral B]

[K505-1vn] 09. Coordination Chemistry, Organometallic Chemistry

Wed. Mar 22, 2023 4:10 PM - 6:40 PM K505 (K505, Lecture Hall Bldg. [5F])

Chair: Daisuke Tanaka, Satoshi Horike

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4:10 PM - 4:30 PM

[K505-1vn-01] Liquid–liquid transition in coordination polymer melt studied by dynamic mechanical analysis

^○Taichi Nishiguchi¹, Yuki Ohara², Kentaro Kadota³, Satoshi Horike^2,3 (1. Faculty of Engineering, Kyoto University, 2. Graduate School of Engineering, Kyoto University, 3. iCeMS, KUIAS, Kyoto University)

[Lang.] English

4:30 PM - 4:50 PM

[K505-1vn-02] Glass formation of coordination polymers driven by dehydration treatment

^○Zeyu FAN¹, Yong-Sheng Wei², Satoshi Horike^2,1 (1. Graduate School of Engineering, Kyoto University, 2. Institute for Advanced Study, Kyoto University)

[Lang.] English

4:50 PM - 5:10 PM

[K505-1vn-03] Photo-generated extremely long-lived spin-polarized radicals in
metal-organic frameworks

^○Kana Orihashi¹, Akio Yamauchi¹, Saiya Fujiwara⁴, Kenichiro Tateishi⁴, Tomohiro Uesaka⁴, Asada Mizue⁵, Toshikazu Nakamura⁵, Nobuo Kimizuka^1,2, Nobuhiro Yanai^1,3 (1. Kyushu Univ., 2. CMS, Kyushu Univ., 3. FOREST, JST, 4. RIKEN, 5. Institute for Molecular Science)

[Lang.] English

5:10 PM - 5:30 PM

[K505-1vn-04] Semiconductive Nature of Lead(II) Coordination Polymers with Benzenethiol Derivatives

^○Ryohei Akiyoshi¹, Akinori Saeki², Daisuke Tanaka¹ (1. Kwansei Gakuin University, 2. Osaka University)

[Lang.] English

Break （5:30 PM - 5:40 PM）

Cancelled

5:40 PM - 6:00 PM

[K505-1vn-05] Hexabenzocoronene-Based Coordination Polymers

^○Saiya Fujiwara¹, Hiroshi Sato^1,2 (1. CEMS, RIKEN, 2. JST-PRESTO)

[Lang.] English

6:00 PM - 6:20 PM

[K505-1vn-06] Inverse Guest Adsorption and Luminescent Response in an Au(I)-based Metal−Organic Framework

^○Haruka Yoshino¹, Masaki Saigo², Kiyoshi Miyata², Ken Onda², Hitoshi Miyasaka¹ (1. Institute for Materials Research, Tohoku University, 2. Graduate School of Science, Kyushu University)

[Lang.] English

6:20 PM - 6:40 PM

[K505-1vn-07] Charge-driven Assembly of Water-soluble Ionic Metal-Organic Polyhedra with Enzymes

^○Benjamin Le Ouay¹, Ryosuke Minami¹, Purna Kanta Boruah¹, Masaaki Ohba¹ (1. Kyushu University)

[Lang.] English

Academic Program [Oral B]

[K506-1vn] 09. Coordination Chemistry, Organometallic Chemistry

Wed. Mar 22, 2023 4:10 PM - 6:40 PM K506 (K506, Lecture Hall Bldg. [5F])

Chair: Shin Takemoto, Takanori Shima

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4:10 PM - 4:30 PM

[K506-1vn-01] Synthesis of tris(dinitrogen) iron(0) complexes stabilized by organosilicon ligands

^○Reon Ishii¹, Yusuke Sunada^1,2 (1. Graduate School of Engineering, The University of Tokyo, 2. Institute of Industrial Science, The University of Tokyo)

[Lang.] Japanese

4:30 PM - 4:50 PM

[K506-1vn-02] Synthesis and Reactivity of Doubly Oxido-Bridged Diruthenium Complex with Terminal Hydroxido Ligands

^○Tomoyo Misawa-Suzuki¹, Nanako Asai¹, Hirotaka Nagao¹ (1. Fac. of Sci. and Tech., Sophia Univ.)

[Lang.] English

4:50 PM - 5:10 PM

[K506-1vn-03] Anion-Exchange-Induced Modulation of Electric Field Response in a Two-Dimensional Bis(terpyridine)metal(II) complex polymer

^○Kenji Takada¹, Hiroshi Nishihara¹ (1. Tokyo University of Science, Research Institute for Science & Technology)

[Lang.] English

5:10 PM - 5:30 PM

[K506-1vn-04] Intramolecular C-H Bond Activation and Functionalization by Low-Valent Cobalt Complexes with Diamide Ligands

^○Suiho Kobayashi¹, Tsubasa Hatanaka¹, Yasuhiro Funahashi¹ (1. Osaka Univ.)

[Lang.] English

Break （5:30 PM - 5:40 PM）

5:40 PM - 6:00 PM

[K506-1vn-05] Heterobimetallic Pt/Main Group Metal Complexes in Metal-Metal Cooperative Bond Activation

^○GOVINDARAJAN RAMADOSS¹, Shubham Deolka¹, Eugene Khaskin¹, Serhii Vasylevskyi¹, Robert R. Fayzullin², Shrinwantu Pal¹, Julia R. Khusnutdinova¹ (1. Okinawa Institute of Science and Technology Graduate University, 2. Arbuzov Institute of Organic and Physical Chemistry FRC Kazan Scientific Center, Russian Academy of Sciences 8 ArbuzovStreet,Kazan,420088 (Russian Federation))

[Lang.] English

6:00 PM - 6:20 PM

[K506-1vn-06] Fabrication of oriented conductive metal–organic framework thin film by dry process.

^○Seoungmin Chon¹, Ryo Nakayama², Shunta Iwamoto¹, Shigeru Kobayashi¹, Ryota Shimizu¹, Taro Hitosugi^2,1 (1. Tokyo Institute of Technology, 2. the University of Tokyo)

[Lang.] English

6:20 PM - 6:40 PM

[K506-1vn-07] Selective CuAAC Transformation of Cu(I) Complex Surrounded by Multiple Reactive Points

^○Takuya SHIBUE¹, Shang RONG¹, Kazuyuki KUBO¹, Shoko KUME¹, Tsutomu MIZUTA¹ (1. Hioshima Univ.)

[Lang.] Japanese

Academic Program [Oral B]

[K506-2am] 09. Coordination Chemistry, Organometallic Chemistry

Thu. Mar 23, 2023 9:00 AM - 11:40 AM K506 (K506, Lecture Hall Bldg. [5F])

Chair: Takahiro Matsumoto, Takuya Kochi

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9:00 AM - 9:20 AM

[K506-2am-01] Defluorohydrogenation of Acyl Fluorides by Secondary Phosphine Oxide as a Hydride Donor

^○Myuto Kashihara¹, Ayaka Kataoka², Yasushi Nishihara¹ (1. RIIS, Okayama Univ., 2. Grad. Sch. of Nat. Sci. and Tech., Okayama Univ.)

[Lang.] English

9:20 AM - 9:40 AM

[K506-2am-02] Effect of Carboxylate Coordination on Redox Properties and Substrate Oxidation Reactivity of Di(µ-oxido)dinickel(III) Complex

^○Yuma Morimoto¹, Ryoichiro Ogumo², Shinobu Itoh² (1. Nagoya University, 2. Osaka University)

[Lang.] English

9:40 AM - 10:00 AM

[K506-2am-03] Aerobic oxidative reactivity of nickel complexes supported in napthyridines ligand scaffolds

^○Shubham Deolka¹, Julia Khusnutdinova¹ (1. OIST ,JAPAN)

[Lang.] English

10:00 AM - 10:20 AM

[K506-2am-04] C₃ product formation by electrochemical CO₂ reduction for dinuclear Cu molecular catalyst

^○Naonari Sakamoto¹, Keita Sekizawa¹, Soichi Shirai¹, Takamasa Nonaka¹, Takeo Arai¹, Shunsuke Sato¹, Takeshi Morikawa¹ (1. Toyota Central R&D Labs., Inc.)

[Lang.] Japanese

10:20 AM - 10:40 AM

[K506-2am-05] Synthesis and Redox Reaction of Copper- and Cobalt-Containing Zeolitic Imidazolate Frameworks

^○Hiroki Nakahara¹, Masahito Kodera¹, Yutaka Hitomi¹ (1. Doshisha University)

[Lang.] English

10:40 AM - 11:00 AM

[K506-2am-06] Synthesis, structure and methane oxidation by dicopper complex with hydrophobic pocket

^○Kyosuke FUJIKAWA¹, Yutaka HITOMI¹, Masahito KODERA^1,2 (1. Doshisha Univ., 2. JST CREST)

[Lang.] Japanese

11:00 AM - 11:20 AM

[K506-2am-07] Dual Catalysis of Au₂₅ Nanocluster Functionalized by Peptide Dendron Thiolate toward Cross-Dehydrogenative Coupling between Amines and Alkynes

^○Kenta Iseri¹, Kyosuke Ueda¹, Katsuhiro Isozaki¹, Masaharu Nakamura¹ (1. Kyoto University)

[Lang.] Japanese

11:20 AM - 11:40 AM

[K506-2am-08] Electrochemical and Photochemical CO₂ Reduction by Rhenium Porphyrin Complexes

^○Jingru Liu¹, Kei Murata¹, Mengfei Wang¹, Kazuyuki Ishii¹, Yusuke Tamaki², Osamu Ishitani² (1. IIS, The Univ. of Tokyo, 2. Dept. of Chem., Tokyo Tech)

[Lang.] English

Academic Program [Oral B]

[K505-2am] 09. Coordination Chemistry, Organometallic Chemistry

Thu. Mar 23, 2023 9:00 AM - 11:30 AM K505 (K505, Lecture Hall Bldg. [5F])

Chair: Ryota Matsuoka, Tomoyuki Haraguchi

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9:00 AM - 9:20 AM

[K505-2am-01] A 3D chiral networked MX compound

^○Hao Liang¹, Kazuya Otsubo¹, Yuiga Nakamura², Shogo Kawaguchi², Hiroshi Kitagawa¹ (1. Kyoto University, 2. Japan Synchrotron Radiation Research Institute (JASRI), SPring-8)

[Lang.] English

9:20 AM - 9:40 AM

[K505-2am-02] Charge-transfer phase transition in a two-dimensional cyanido-bridged Co-W assembly with isoquinoline ligands

^○Kazuki Nakamura¹, Shota Kobayashi¹, Koji Nakabayashi¹, Kenta Imoto¹, Shin-ichi Ohkoshi¹ (1. The Univ. of Tokyo)

[Lang.] English

9:40 AM - 10:00 AM

[K505-2am-03] Gate-Open-Close Vapochromism of Rhenium(I) Molecular Crystals Supported by Non-Covalent Interactions: In-Situ Observation of the Guest-Induced Structural Transformation Dynamics

^○Yuki Matsuda¹, Ryota Nakamura¹, Yoshiki Ozawa¹, Keishiro Tahara¹, Toshikazu Ono², Nobuto Yoshinari³, Takumi Konno³, Kunihisa Sugimoto⁴, Shintaro Kobayashi⁵, Shogo Kawaguchi⁵, Masaaki Abe¹ (1. Graduate School of Science, University of Hyogo, 2. Graduate School of Engineering, Kyushu University, 3. Graduate School of Science, Osaka University, 4. Department of Chemistry, Faculty of Science and Engineering, Kindai University, 5. SPring-8/JASRI)

[Lang.] English

10:00 AM - 10:20 AM

[K505-2am-04] Complexation behavior and luminescence enhancement of a pyridyl-containing triarylmethyl radical with silver(I)

^○Takuto Mibu¹, Ryota Matsuoka¹, Tetsuro Kusamoto^1,2 (1. IMS, 2. JST-PRESTO)

[Lang.] Japanese

Break （10:20 AM - 10:30 AM）

10:30 AM - 10:50 AM

[K505-2am-05] Sequence Controll and Multi-stage Redox Composed of Single Metal containing Metallosupramolecular Polymeric Films for Electrochromic Study

^○DINES CHANDRA SANTRA¹, Masayoshi HIGUCHI¹ (1. National Institute for Materials Science (NIMS))

[Lang.] English

10:50 AM - 11:10 AM

[K505-2am-06] Development of visible-light responsive mutinuclear Zn complexes and Zn clusters based on Zn-Zn interaction

^○Yoshimasa Wada^1,2, Takahiro Maruchi², Reon Ishii², Yusuke Sunada^1,2,3 (1. Institute of Industrial Science, The University of Tokyo, 2. Graduate School of Engineering, The University of Tokyo, 3. JST-PRESTO)

[Lang.] Japanese

11:10 AM - 11:30 AM

[K505-2am-07] The spin-lattice magnetic relaxation of an S=1/2 copper(II)-substituted Keggin-type phosphotungstate

^○Toshiharu Ishizaki¹, Yoji Inoue¹, Tomoji Ozeki¹ (1. Nihon Univ.)

[Lang.] English

Academic Program [Oral B]

[K505-2pm] 09. Coordination Chemistry, Organometallic Chemistry

Thu. Mar 23, 2023 1:40 PM - 3:40 PM K505 (K505, Lecture Hall Bldg. [5F])

Chair: Norio Nakata, Shintaro Ishida

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1:40 PM - 2:00 PM

[K505-2pm-01] DNA Double Strand Breaks via Reductive O₂-Activation by Dicopper Complex: large acceleration by introducing an intercalator as DNA Binding Site

^○Machi Hata¹, Hiroyuki Matsumoto¹, Yutaka Hitomi¹, Masahito Kodera¹ (1. Doshisha University)

[Lang.] English

2:00 PM - 2:20 PM

[K505-2pm-02] Room-temperature Conversion of CO₂ into Metal-Organic Frameworks

^○Kentaro Kadota¹, Satoshi Horike^1,2 (1. Institute for Advanced Study, Kyoto University, 2. Graduate School of Engineering, Kyoto University)

[Lang.] English

2:20 PM - 2:40 PM

[K505-2pm-03] Synthesis of Lewis-base-coordinated Germabenzenylgermylenes Acting as a Ge Atom Source

^○Ryohei Nishino¹, Yoshiyuki Mizuhata¹, Norihiro Tokitoh¹ (1. Institute for Chemical Research, Kyoto Univ.)

[Lang.] Japanese

2:40 PM - 3:00 PM

[K505-2pm-04] Synthesis of Novel Silylboron Compounds Using Trialkylsilyl Anions

^○Rikuro Takahashi¹, Hajime Ito^2,3 (1. Division ofApplied Chemistry, Graduate School of Engineering, Hokkaido University, 2. Graduate School of Engineering, Hokkaido University, 3. WPI-ICReDD, Hokkaido University)

[Lang.] English

3:00 PM - 3:20 PM

[K505-2pm-05] Synthesis and Characterization of Alumanyl Complexes of Vanadium

^○Pavel Zatsepin¹, Makoto Yamashita¹ (1. Nagoya University)

[Lang.] English

3:20 PM - 3:40 PM

[K505-2pm-06] Catalytic Hydrogenation of Carbonyl Compounds Using Crude H₂ as H₂ Source

^○Mahiro Sakuraba¹, Sensuke Ogoshi¹, Yoichi Hoshimoto¹ (1. Osaka university)

[Lang.] English

Academic Program [Oral B]

[K506-3am] 09. Coordination Chemistry, Organometallic Chemistry

Fri. Mar 24, 2023 9:00 AM - 10:20 AM K506 (K506, Lecture Hall Bldg. [5F])

Chair: Manabu Nakaya, Ryo Inoue

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9:00 AM - 9:20 AM

[K506-3am-01] Synthesis of two-dimensional layer-structured coordination polymer ELM-12/3 and gate-opening adsorption properties

^○Hiroki Miura¹, Atsushi Kondo², Hirofumi Kanoh³, Hiroshi Kajiro¹ (1. Nippon Steel Corporation, 2. Oita University, 3. Chiba University)

[Lang.] Japanese

9:20 AM - 9:40 AM

[K506-3am-02] Helical Induction, Chiroptical Properties, and Quantitative Prediction of Dissymmetry Factor on the Circularly Polarized Phosphorescence of Iminopyrrolyl Platinum(II) Complexes

^○Ryo Inoue¹, Riki Kondo¹, Yasuhiro Morisaki¹ (1. Kwansei Gakuin University)

[Lang.] Japanese

9:40 AM - 10:00 AM

[K506-3am-03] pH effect on hydrothermal synthesis of the copper organodiphosphonate polymers: Investigation of luminescence and magnetic properties

^○BURAK AY^1,2, TAKAYUKI ISHIDA¹ (1. The University of Electro-Communications, 2. Çukurova University)

[Lang.] English

10:00 AM - 10:20 AM

[K506-3am-04] External-stimuli responsiveness in luminescence properties of salophene-type platinum(II) complexes with carboxy substituents

^○Shun Fujii¹, Manabu Nakaya¹ (1. Josai University)

[Lang.] Japanese

Academic Program [Oral B]

[K504-3pm] 09. Coordination Chemistry, Organometallic Chemistry

Fri. Mar 24, 2023 1:10 PM - 3:40 PM K504 (K504, Lecture Hall Bldg. [5F])

Chair: Kentaro Kadota, Shinya Takaishi

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1:10 PM - 1:30 PM

[K504-3pm-01] Investigation of thermodynamics in melting Cu²⁺-based 1D coordination polymers

^○Yuki Ohara¹, Taichi Nishiguchi¹, Shin-ichiro Noro³, Daniel Packwood², Satoshi Horike^1,2 (1. Graduate School of Engineering, Kyoto University, 2. Institute for Advanced Study, Kyoto University, 3. Faculty of Environmental Earth Science, Hokkaido University)

[Lang.] English

1:30 PM - 1:50 PM

[K504-3pm-02] Spatially Controlled Hybridization of Porous Metal-Organic Crystals

^○Kunyi Leng^1,2, Takuzo Aida^1,2, Hiroshi Sato^2,3 (1. The University of Tokyo, 2. RIKEN Center for Emergent Matter Science, 3. JST-PRESTO)

[Lang.] English

1:50 PM - 2:10 PM

[K504-3pm-03] Three-dimensional van der Waals frameworks assembled from octahedral metal-organic polyhedra

^○Shun Tokuda¹, Shuhei Furukawa¹ (1. iCeMS, Kyoto University)

[Lang.] English

2:10 PM - 2:30 PM

[K504-3pm-04] Recognition of Copolymer Sequence via Gated Inclusion in Flexible Metal-Organic Frameworks

^○Nobuhiko Hosono¹, Biplab Manna², Mizuki Asami², Takashi Uemura¹ (1. Grad. Sch. of Eng., The Univ. of Tokyo, 2. Grad. Sch. of Frontier Sci., The Univ. of Tokyo)

[Lang.] Japanese

Break （2:30 PM - 2:40 PM）

2:40 PM - 3:00 PM

[K504-3pm-05] Structural and property evaluation of cyano-bridged coordination polymers exhibiting anisotropic thermal expansion

^○Ryota Kosuge¹, Takashi KOSONE^1,2, Naoya ADACHI^1,2 (1. Graduate School of Tokyo Denki University, 2. Tokyo Denki University)

[Lang.] Japanese

3:00 PM - 3:20 PM

[K504-3pm-06] Consideration on Gated CO₂ Adsorption Behavior in One-Dimensional Porous Coordination Polymers of Phenazine-Linked Paddlewheel diruthenium complex

^○Wataru Kosaka¹, Jun Zhang², Hitoshi Miyasaka¹ (1. IMR, Tohoku Univ., 2. FRIS, Tohoku Univ.)

[Lang.] English

3:20 PM - 3:40 PM

[K504-3pm-07] Quinoid-Based Three-Dimensional Metal-Organic Framework, Fe₂(dhbq)₃ : Porosity, Electrical Conductivity and Solid-State Redox Properties

^○Shraddha Gupta¹, Haruki Tanaka¹, Shinya Takaishi¹ (1. Tohoku University)

[Lang.] English

Academic Program [Oral B]

[K505-3pm] 09. Coordination Chemistry, Organometallic Chemistry

Fri. Mar 24, 2023 1:10 PM - 3:40 PM K505 (K505, Lecture Hall Bldg. [5F])

Chair: Kazuhiro Uemura, Masaki Yoshida

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1:10 PM - 1:30 PM

[K505-3pm-01] Synthesis and Properties of Mixed-Valence Mn-oxo Clusters Ligated with Rigid Triptycene-Based Ligands

^○Mikiya Kato^1,2, Tomoya Fukui^1,2, Ryosuke Takehara^1,2, Yoshiaki Shoji^1,2, Fukushima Takanori^1,2 (1. CLS, Tokyo Tech., 2. Sch. Mater. Chem. Tech., Tokyo Tech.)

[Lang.] Japanese

1:30 PM - 1:50 PM

[K505-3pm-02] Near-infrared emission in Ag₂₉ nanoclusters induced by the modification with metal complexes

^○Wataru Ishii¹, Yoshinori Okayasu², Yoichi Kobayashi², Kawai Tsuyoshi³, Takuya Nakashima¹ (1. Osaka Metropolitan University, 2. Ritsumeikan University, 3. Nara Institute of Science and Technology)

[Lang.] English

1:50 PM - 2:10 PM

[K505-3pm-03] Magnetic properties of paramagnetic one-dimensional chains where first transition metals are infinitely aligned with metal–metal bonds

^○Atsushi Takamori¹, Kazuhiro Uemura² (1. Graduate School of Engineering, Gifu University, 2. Faculty of Engineering, Gifu University)

[Lang.] English

2:10 PM - 2:30 PM

[K505-3pm-04] Vapor, mechanical, and piezochromic multicolor switching of a carbon-centered hexagold(I) cluster with flexible N-heterocyclic carbene ligands

^○Leonardo Hayato Takeshige¹, Xiao-Li Pei¹, Hitoshi Ube¹, Zhen Lei¹, Hiroki Kobayashi², Kazuki Komatsu², Hiroyuki Kagi², Mitsuhiko Shionoya¹ (1. Department of Chemistry, Grad. Sch. Sci, The Univ. of Tokyo, 2. Geochemical Research Center, Grad. Sch. Sci, The Univ. of Tokyo)

[Lang.] English

Break （2:30 PM - 2:40 PM）

2:40 PM - 3:00 PM

[K505-3pm-05] Regioselective deprotonation of twisted trinuclear macrocycles to control the rate of helicity inversion

^○Tomoki NAKAJIMA¹, Shohei TASHIRO¹, Masahiro EHARA², Mitsuhiko SHIONOYA¹ (1. Grad. Sch. of Sci.; The Univ. of Tokyo, 2. IMS)

[Lang.] English

3:00 PM - 3:20 PM

[K505-3pm-06] Stability Control and Luminescence of Porous Crystals of Self-assembled Platinum(II) Complexes Based on the Electronic Tuning of Ligands

^○Masaki Yoshida¹, Takanari Mochizuki², Atsushi Kobayashi², Masako Kato¹ (1. Kwansei Gakuin Univ., 2. Hokkaido Univ.)

[Lang.] English

3:20 PM - 3:40 PM

[K505-3pm-07] Multi-step conversion of protonation state based on the coupling of proton, spin and molecular orientation

^○Takumi Nakanishi¹, Osamu Sato¹ (1. Kyushu University)

[Lang.] Japanese

Academic Program [Oral B]

[K505-3vn] 09. Coordination Chemistry, Organometallic Chemistry

Fri. Mar 24, 2023 4:10 PM - 6:40 PM K505 (K505, Lecture Hall Bldg. [5F])

Chair: Hironobu Ozawa, Yoshimasa Wada

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4:10 PM - 4:30 PM

[K505-3vn-01] Mechanistic Study on Chromium-catalyzed Ring-opening Arylation of 7-Oxabenzonorbornadiene Derivatives with Aryl Grignard Reagents

^○Kohei Nishi¹, Hayato Tsurugi¹, Kazushi Mashima² (1. Graduate School of Engineering Science, Osaka University, 2. Graduate School of Pharmaceutical Sciences, Osaka University)

[Lang.] English

4:30 PM - 4:50 PM

[K505-3vn-02] [2+2+1]-Cycloaddition Reaction of Azobenzenes and Diarylacetylenes Catalyzed by Early Transition Metal Imido Complexes

^○Takuya Akiyama¹, Yuya Kakiuchi¹, Ian A. Tonks², Hayato Tsurugi¹, Kazushi Mashima³ (1. Graduate School of Engineering Science, Osaka University, 2. University of Minnesota, 3. Graduate School of Pharmaceutical Science, Osaka University)

[Lang.] English

4:50 PM - 5:10 PM

[K505-3vn-03] Mechanistic study of photocatalytic CO₂ reduction by a Ru(II)-Re(I) supramolecular photocatalyst

^○Kei Kamogawa¹, Yuki Kato², Yuushi Shimoda³, Kiyoshi Miyata³, Ken Onda³, Takumi Noguchi², Yusuke Tamaki¹, Osamu Ishitani^1,4 (1. Tokyo Institute of Technology, 2. Nagoya University, 3. Kyushu University, 4. Hiroshima University)

[Lang.] English

5:10 PM - 5:30 PM

[K505-3vn-04] Improvement of formation quantum yields of one-electron reduced species of Re(I)-complex photosensitizers and its utilization

^○Naoki Hosokawa¹, Yusuke Tamaki¹, Osamu Ishitani^1,2 (1. Tokyo institute of technology, 2. Hiroshima University)

[Lang.] English

Break （5:30 PM - 5:40 PM）

5:40 PM - 6:00 PM

[K505-3vn-05] Supramolecular Framework Catalyst Constructed by Iron Porphyrin Complexes for Photochemical CO₂ Reudction

^○Kento Kosugi¹, Chiharu Akatsuka¹, Mio Kondo^1,2, Shigeyuki Masaoka¹ (1. Osaka University, 2. JST PRESTO)

[Lang.] Japanese

6:00 PM - 6:20 PM

[K505-3vn-06] Iron-catalyzed ring-opening metathesis polymerization of olefins

^○Satoshi Takebayashi¹, David Milstein² (1. Okinawa Institute of Science and Technology Graduate University, 2. Weizmann Institute of Science)

[Lang.] English

Cancelled

6:20 PM - 6:40 PM

[K505-3vn-07] Electrocatalytic Reduction of Low Concentration CO₂ using Iron Porphyrins

^○Sebastian Nybin Remello¹, Osamu Ishitani¹ (1. Tokyo Institute of Technology )

[Lang.] English

Academic Program [Oral B]

[K506-3vn] 09. Coordination Chemistry, Organometallic Chemistry

Fri. Mar 24, 2023 4:10 PM - 6:40 PM K506 (K506, Lecture Hall Bldg. [5F])

Chair: Atsushi KOBAYASHI, Yohei Ogiwara

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4:10 PM - 4:30 PM

[K506-3vn-01] Effect of a Sulfur Atom in the Benzylidene Ligand of Hoveyda-Grubbs-type Complexes on Their Catalytic Activities

^○Tsubasa Kinugawa¹, Shun Hirota¹, Takashi Matsuo¹ (1. Division of Materials Science, Nara Institute of Science and Technology)

[Lang.] Japanese

4:30 PM - 4:50 PM

[K506-3vn-02] Multi-potential-step chronocoulospectrometry for electrocatalytic proton reduction by mononuclear ruthenium complexes

^○Yuta Tsubonouchi¹, Norihisa Hoshino¹, Debraj Chandra¹, Zaki Zahran¹, Masayuki Yagi¹ (1. Grad. School of Sci. and Tech., Niigata univ.)

[Lang.] English

4:50 PM - 5:10 PM

[K506-3vn-03] A Highly Stable Molecular-based TiO₂ Photoanode for Photoelectrochemical Water Splitting Achieved by Pyridyl Anchoring Technique

^○Xin Yan¹, Ken Sakai¹, Hironobu Ozawa¹ (1. Dept. Chem. Kyushu Univ.)

[Lang.] English

Break （5:10 PM - 5:20 PM）

5:20 PM - 5:40 PM

[K506-3vn-04] Photochemical Reduction of Carbon Dioxde Catalyzed by Ru-Pd Bimetallic Complexes

^○Siteng Yang¹, Nobuharu Iwasawa¹, Jun Takaya¹ (1. Titech)

[Lang.] English

5:40 PM - 6:00 PM

[K506-3vn-05] Photo-induced pentafluoroethylation mediated by cobalt(III) complexes supported by naphthyridine-based ligands

^○Hoan Minh Dinh¹, Julia R. Khusnutdinova¹ (1. Okinawa Institute of Science and Technology)

[Lang.] English

6:00 PM - 6:20 PM

[K506-3vn-06] Molecular Catalysis of Co-NHC Complexes in Hydrogen Evolution from Water

^○Kosei Yamauchi¹, Yasunobu Wakafuji¹, Kaori Kawamura¹, Masanori Kan¹, Ken Sakai¹ (1. Kyushu University)

[Lang.] English

6:20 PM - 6:40 PM

[K506-3vn-07] Mechanistic Investigation of Electrochemical Hydrogen Evolution from Water Catalyzed by a Co-NHC Complex

^○Masanori Kan¹, Kosei Yamauchi¹, Ken Sakai¹ (1. Dept. Chem. Kyushu Univ.)

[Lang.] English

Academic Program [Oral B]

[K505-4am] 09. Coordination Chemistry, Organometallic Chemistry

Sat. Mar 25, 2023 9:00 AM - 11:30 AM K505 (K505, Lecture Hall Bldg. [5F])

Chair: Akitaka Ito, Yoshihiro Sekine

+Add all to schedule

9:00 AM - 9:20 AM

[K505-4am-01] Magnetic Properties of Organic-Inorganic Perovskites with Ferroelasticity

^○Naoto Tsuchiya¹, Ishinuki Tatsuya¹, Saya Aoki¹, Yuki Nakayama¹, Goulven Cosquer², Sadafumi Nishihara^1,2,3, Katsuya Inoue^1,2,4 (1. Graduate School of Advanced Science and Engineering, Hiroshima Univ., 2. Chirality Research Center, Hiroshima Univ., 3. JST, PRESTO, 4. International Institute for Sustainability with Knotted Chiral Meta Matter, Hiroshima Univ.)

[Lang.] English

9:20 AM - 9:40 AM

[K505-4am-02] Multifunctional Spin Crossover Compounds with Chiral Anions

^○Hikaru Zenno¹, Yoshihiro Sekine¹, Shinya Hayami¹ (1. Kumamoto University)

[Lang.] English

9:40 AM - 10:00 AM

[K505-4am-03] Luminescence from Terbium(III) Species upon Sensitization using Ionic Nanosphere

^○Nikita Madhukar¹, Taizo Misato¹, Akitaka Ito¹ (1. Kochi Univ. of Tech.)

[Lang.] English

10:00 AM - 10:20 AM

[K505-4am-04] Energy-Transfer Quenching of [Ru(bpy)₃]²⁺ in Ionic Nanosphere

^○Taizo Misato¹, Akitaka Ito¹ (1. Kochi Univ. of Tech.)

[Lang.] English

Break （10:20 AM - 10:30 AM）

10:30 AM - 10:50 AM

[K505-4am-05] Symmetry-breaking Assembly of a Supramolecular Ir Complex within a Hydrogen-bonded Host

^○Shinnosuke Horiuchi^1,2, Eri Sakuda², Yasuhiro Arikawa², Shuichi Hiraoka¹, Keisuke Umakoshi² (1. The Univ. of Tokyo, 2. Nagasaki Univ.)

[Lang.] English

10:50 AM - 11:10 AM

[K505-4am-06] Control of Molecular Arrangement and Polarity in Vapochromic Crystals

^○Fumiya Kobayashi¹, Misato Gemba¹, Makoto Tadokoro¹ (1. Tokyo Univ. of Sci.)

[Lang.] English

11:10 AM - 11:30 AM

[K505-4am-07] Latest progress on halogen-bridged metal complex chemistry

^○Masanori Wakizaka¹, Shinya Takaishi¹, Masahiro Yamashita¹ (1. Tohoku Univ.)

[Lang.] English

Sessions

09. Coordination Chemistry, Organometallic Chemistry » Oral B

[K505-1pm] 09. Coordination Chemistry, Organometallic Chemistry

[K505-1vn] 09. Coordination Chemistry, Organometallic Chemistry

[K506-1vn] 09. Coordination Chemistry, Organometallic Chemistry

[K506-2am] 09. Coordination Chemistry, Organometallic Chemistry

[K505-2am] 09. Coordination Chemistry, Organometallic Chemistry

[K505-2pm] 09. Coordination Chemistry, Organometallic Chemistry

[K506-3am] 09. Coordination Chemistry, Organometallic Chemistry

[K504-3pm] 09. Coordination Chemistry, Organometallic Chemistry

[K505-3pm] 09. Coordination Chemistry, Organometallic Chemistry

[K505-3vn] 09. Coordination Chemistry, Organometallic Chemistry

[K506-3vn] 09. Coordination Chemistry, Organometallic Chemistry

[K505-4am] 09. Coordination Chemistry, Organometallic Chemistry

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