Academic Program [Oral A]

[K504-1pm] 09. Coordination Chemistry, Organometallic Chemistry

Wed. Mar 22, 2023 1:00 PM - 3:40 PM K504 (K504, Lecture Hall Bldg. [5F])

Chair: Ryo Ohtani, Wataru Kosaka

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1:00 PM - 1:10 PM

[K504-1pm-01] Fabrication of highly oriented crystalline pillared-layer-type metal-organic framework thin film by casting method

^○QIYUAN ZHANG¹, TOMOYUKI HARAGUCHI¹, TAKASHIRO AKITSU¹ (1. Tokyo University of Science)

[Lang.] English

1:10 PM - 1:20 PM

[K504-1pm-02] Synthesis of Sulfur-Containing One-Dimensional Semiconducting Coordination Polymers and Correlation between Metal Ion Species and Physical Properties

^○Saori Ogura¹, Yuka Nakatani¹, Hinaka Hashimoto¹, Ainori Saeki², Ryohei Akiyoshi¹, Daisuke Tanaka¹ (1. Kwansei Gakuin University, 2. Osaka University)

[Lang.] Japanese

1:20 PM - 1:30 PM

[K504-1pm-03] Synthesis and Characterization of Lead(II) Coordination Polymer Composed of Sulfur-Containing Ligands

^○Tomoki Uotani¹, Ryohei Akiyoshi¹, Daisuke Tanaka¹ (1. Kwansei Gakuin University)

[Lang.] Japanese

1:30 PM - 1:40 PM

[K504-1pm-04] Synthesis and Characterization of Manganese(II) Coordination Polymer Composed of Trithiocyanuric Acid

^○Keiichi Matsuda¹, Ryohei Akiyoshi¹, Daisuke Tanaka¹ (1. Kwansei Gakuin University)

[Lang.] Japanese

1:40 PM - 1:50 PM

[K504-1pm-05] Synthesis and Characterization of Sn(II) Coordination Polymer with Benzenethiol Derivatives

^○Kosuke Sakai¹, Ryohei Akiyoshi¹, Daisuke Tanaka¹ (1. Kwansei Gakuin University)

[Lang.] Japanese

1:50 PM - 2:00 PM

[K504-1pm-06] Flexible Metal-Organic Frameworks with Dipyridinoarsoles

^○Kazuma Kikuchi¹, Hiroi Sei², Kouki Oka², Norimitsu Tohnai², Hiroaki Imoto¹, Kensuke Naka¹ (1. Kyoto Institute of Technology, 2. Osaka University)

[Lang.] Japanese

2:00 PM - 2:10 PM

[K504-1pm-07] Development of a Hydrogen-Bonded Framework Catalyst Based on Rh Paddle-Wheel Complexes

^○Yuka Kiyokawa¹, Hikaru Iwami¹, Kento Kosugi¹, Yutaka Saga¹, Mio Kondo^1,2, Shigeyuki Masaoka¹ (1. Osaka Univ., 2. JST PRESTO)

[Lang.] Japanese

2:10 PM - 2:20 PM

[K504-1pm-08] External stimuli responsive organic-inorganic hybrids Tin(IV) chloride with naphthalene diimide analogues

^○Shunya Masuda¹, Sotaro Kusumoto¹, Yoshihiro Koide¹ (1. The Univ. of Kanagawa)

[Lang.] Japanese

Break （2:20 PM - 2:30 PM）

2:30 PM - 2:40 PM

[K504-1pm-09] Fluorescence turn on volatile amines detection in an antimony based organic–inorganic hybrid

^○Sotaro Kusumoto¹, Ryoto Tada¹, Yoshihiro Koide¹ (1. Kanagawa Univ.)

[Lang.] Japanese

2:40 PM - 2:50 PM

[K504-1pm-10] Photoluminescence Properties of a Three-Dimensional Coordination Polymer from Rare Earth Ion and Small Ligands

^○Rina Takano¹, Burak Ay^1,2, Takayuki Ishida¹ (1. The University of Electro-Communications, 2. Çukurova University)

[Lang.] English

2:50 PM - 3:00 PM

[K504-1pm-11] Synthesis, Structures and Gas Adsorption Properties of Hydroxamate Metal-Organic Frameworks

^○Yanhua ZHANG¹, Koh SUGAMATA¹, Akihiro SHIRAI², Mao MINOURA¹ (1. Rikkyo University , 2. Nippon Soda Co., Ltd.)

[Lang.] Japanese

3:00 PM - 3:10 PM

[K504-1pm-12] Observation of metamagnetism in nickel-octacyanotungstate 1D magnet.

^○Shintaro Akagi¹, Junhao Wang¹, Kenta Imoto², Shin-ichi Ohkoshi², Hiroko Tokoro¹ (1. University of Tsukuba, 2. The University of Tokyo)

[Lang.] Japanese

3:10 PM - 3:20 PM

[K504-1pm-13] Temperature and light-dependent low-frequency absorbance in spin-crossover systems

^○Guanping Li¹, Olaf Stefanczyk¹, Kunal Kumar¹, Koji Nakabayashi¹, Shin-ichi Ohkoshi¹ (1. Department of Chemistry, School of Science, University of Tokyo)

[Lang.] English

3:20 PM - 3:30 PM

[K504-1pm-14] The effect of the co-substitution with heavy alkali cations for THz wave absorption properties with charge-transfer induced phase transition of cyanido-bridged metal assemblies

^○Yuuki Mineo¹, Koji Nakabayashi¹, Kenta Imoto¹, Kosuke Nakagawa¹, Marie Yoshikiyo¹, Shin-ichi Ohkoshi¹ (1. The Univ. of Tokyo)

[Lang.] English

3:30 PM - 3:40 PM

[K504-1pm-15] Ln-[Fe(CN)₅NO] crystals showing photo-switchable polarization of second harmonic light

^○Taiki Sakaguchi¹, Kenta Imoto¹, Koji Nakabayashi¹, Shin-ichi Ohkoshi¹ (1. The Univ. of Tokyo)

[Lang.] English

Academic Program [Oral A]

[K506-1pm] 09. Coordination Chemistry, Organometallic Chemistry

Wed. Mar 22, 2023 1:00 PM - 3:40 PM K506 (K506, Lecture Hall Bldg. [5F])

Chair: Tomohiro Iwai, Yusuke Tamaki

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1:00 PM - 1:10 PM

[K506-1pm-01] Development of novel methanol fuel cell anode catalyst using Fe(III) complex

^○Takahiro Kawaguchi¹, Daisuke Nakane¹, Takashiro Akitsu¹ (1. Tokyo University of Science)

[Lang.] Japanese

1:10 PM - 1:20 PM

[K506-1pm-02] Development of Function-Integrated System for Water Oxidation by Electrochemical Polymerization of Pentanuclear Iron Complexes

^○Takumi Matsuzaki¹, Hikaru IWAMI¹, Yutaka SAGA¹, Mio KONDO^1,2, Sigeyuki MASAOKA¹ (1. Osaka Univ., 2. JST PRESTO)

[Lang.] Japanese

1:20 PM - 1:30 PM

[K506-1pm-03] Photochemical CO₂ Reduction by Iron Porphyrin Complexes with Multi-Proton/Electron Transfer Moieties

^○Maho Imai¹, Kento Kosugi¹, Yutaka Saga¹, Mio Kondo^1,2, Shigeyuki Masaoka¹ (1. Osaka Univ., 2. JST PRESTO)

[Lang.] Japanese

1:30 PM - 1:40 PM

[K506-1pm-04] Substrate oxidation by an iron(IV)-oxo complex bearing a porphyrin ligand with a substrate-trapping site

^○Lianyu Wei¹, shogo tanaka¹, tamoya ishizuka¹, takahiko kojima¹ (1. The Univ. of Tsukuba)

[Lang.] English

1:40 PM - 1:50 PM

[K506-1pm-05] Photocatalytic Reactions Using Water as an Electron Source Driven by Phase-Migrating Electron Mediators

^○Ren Itagaki¹, Akinobu Nakada², Ryu Abe², Ho-Chol Chang¹ (1. Chuo Univ., 2. Kyoto Univ.)

[Lang.] Japanese

1:50 PM - 2:00 PM

[K506-1pm-06] Reactivity of Iron Sandwich Complexes with Oxocyclohexadienyl Ligands toward Proton-Coupled Electron Transfer Reactions

^○Yuye ZHANG¹, Shogo KURIYAMA¹, Yoshiaki NISHIBAYASHI¹ (1. School of Engineering, The University of Tokyo)

[Lang.] English

2:00 PM - 2:10 PM

[K506-1pm-07] Effects of π-Donation from the Axial Ligands on the Reactivity of Iron(IV)-oxide Porphyrin-π-cation Radical Complex toward Alkane Hydroxylation Reactions

^○Toshiya Higashi¹, Yuma Morimoto², Hiroshi Fujii³, Shinobu Itoh¹ (1. Osaka University, 2. Nagoya University, 3. Nara Women's University)

[Lang.] Japanese

2:10 PM - 2:20 PM

[K506-1pm-08] CO₂Reduction Reaction Catalyzed by a Doubly N-confused Hexaphyrin Dinuclear-Iron Complex

^○Daichi Sugawara¹, Takashi Ito¹, Takashi Nakazono², Tohru Wada¹ (1. College of Science, Department of Chemistry, Rikkyo University, 2. Research Center for Artificial Photosynthesis (ReCAP), Osaka Metropolitan University)

[Lang.] Japanese

Break （2:20 PM - 2:30 PM）

2:30 PM - 2:40 PM

[K506-1pm-09] Efficient electrocatalytic CO₂ reduction by base metal complexes with in-plane N₄ ligands.

^○Chiho Narita¹, Yuta Tsubonouchi¹, Norihisa Hoshino¹, Debraj Chandra¹, Zaki Zahran¹, Masayuki Yagi¹ (1. Grad. School of Sci. and Tech., Niigata univ.)

[Lang.] Japanese

2:40 PM - 2:50 PM

[K506-1pm-10] Photocatalytic CO₂ reduction by an iron porphyrin-based framework catalyst constructed by hydrogen bonding

^○XIANJUN LI¹, Maho IMAI¹, Kento KOSUGI¹, Yutaka SAGA¹, Mio KONDO^1,2, Shigeyuki MASAOKA¹ (1. Osaka University, 2. JST PRESTO)

[Lang.] English

2:50 PM - 3:00 PM

[K506-1pm-11] Reaction mechanism of non-heme mononuclear iron-thiolato complex with oxygen

^○Masaki Kubo¹, Daisuke Nakane³, Tomohiro Ozawa¹, Tomohiko Inomata¹, Hideki Masuda^2,1 (1. Graduate School of Engineering, Nagoya Institute of Technology, 2. Aichi Institute of Technology, 3. Tokyo University of Science)

[Lang.] Japanese

3:00 PM - 3:10 PM

[K506-1pm-12] Iron-catalyzed Suzuki-Miyaura Coupling of Propargyl Electrophiles with Organoboron Compounds Derived from Alkenyl Bromides

^○Beiling WU¹, Siming LU¹, Ryosuke AGATA², Hiroshi MATSUDA³, Satoshi AOKI¹, Francesca PINCELLA¹, Katsuhiro ISOZAKI¹, Masaharu NAKAMURA¹ (1. Kyoto Univ., 2. MCG Corp., 3. TSK Corp.)

[Lang.] English

3:10 PM - 3:20 PM

[K506-1pm-13] Earth-Abundant Systems for Photocatalytic CO₂ Reduction using Chromium Complexes Supported by Ferrocenyl Groups for Improving the Performance

^○Taku Wakabayashi¹, Jieun Jung¹, Youhei Kametani², Yoshihito Shiota², Kazunari Yoshizawa², Susumu Saito^1,3 (1. Grad. Sch. Sci., Nagoya Univ., 2. IMCE, Kyushu Univ., 3. IRCCS, Nagoya Univ.)

[Lang.] English

3:20 PM - 3:30 PM

[K506-1pm-14] Theoretical study on proton-coupled electron transfer reaction using metallocene toward nitrogen fixation

^○Yusuke Tsuruta¹, Akihito Egi¹, Hiromasa Tanaka², Yoshiaki Nishibayashi³, Kazunari Yoshizawa¹ (1. Institute for Materials Chemistry and Engineering, Kyushu Univ., 2. School of Liberal Arts and Science, Daido Univ., 3. School of Engineering, The Univ. of Tokyo)

[Lang.] Japanese

3:30 PM - 3:40 PM

[K506-1pm-15] Synthesis of Multi-substituted Cyclopentadiene Derivatives from Tungsten Vinylcarbene Complexes and Internal Alkynes

^○Akira Yamamoto¹, Takuya Akiyama¹, Hayato Tsurugi¹, Kazushi Mashima² (1. Graduate School of Engineering Science, Osaka University, 2. Graduate School of Pharmaceutical Sciences, Osaka University)

[Lang.] Japanese

Academic Program [Oral A]

[K503-1pm] 09. Coordination Chemistry, Organometallic Chemistry

Wed. Mar 22, 2023 1:00 PM - 3:40 PM K503 (K503, Lecture Hall Bldg. [5F])

Chair: Ken-Ichiro Kanno, Shin Takemoto

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1:00 PM - 1:10 PM

[K503-1pm-01] Molybdenum-Germylyne Complex as a Catalyst for Hydroboration of Carbonyl Compounds

^○Christof Israel Marbella Fontanilla¹, Koichi Nagata¹, Yuto Shimizu², Seiji Mori², Hisako Hashimoto¹ (1. Tohoku University, 2. Ibaraki University)

[Lang.] English

1:10 PM - 1:20 PM

[K503-1pm-02] Theoretical investigations of hydroboration of carbonyl compounds catalyzed by Molybdenum-Germylyne complex

^○Yuto Shimizu¹, Christof Israel Marbella Fontanilla², Koichi Nagata², Hisako Hashimoto², Seiji Mori¹ (1. Graduate School of Science and Engineering, Ibaraki University, 2. Graduate School of Science, Tohoku University)

[Lang.] Japanese

1:20 PM - 1:30 PM

[K503-1pm-03] Synthesis and Reactivity of Germylenes Bearing a Phenalenyl-Based Ligand

^○Kenta Uchida¹, Takuya Kodama^1,2, Chihiro Nakasuji³, Ryohei Kishi^3,4,5, Yasutaka Kitagawa^3,4,5,6, Mamoru Tobisu^1,2 (1. Graduate School of Engineering, Osaka University, 2. ICS-OTRI, 3. Graduate School of Engineering Science, Osaka University, 4. QIQB, Osaka University, 5. RCSEC, Osaka University, 6. CSRN, Osaka University)

[Lang.] Japanese

1:30 PM - 1:40 PM

[K503-1pm-04] Synthesis and structure of a linear germanium-centered heteroallene

^○Teppei Asakawa¹, Koh Sugamata¹, Mao Minoura¹ (1. Rikkyo University)

[Lang.] Japanese

1:40 PM - 1:50 PM

[K503-1pm-05] Cooperative binding of lanthanum ions in a nanospace of a tetrahedral organic cage molecule with four coordination sites

^○Daiki Ito¹, Nozomi Mihara¹, Takuya Shiga¹, Masayuki Nihei¹ (1. Univ. of Tsukuba)

[Lang.] Japanese

1:50 PM - 2:00 PM

[K503-1pm-06] Effect of Substituents of Tripodal Schiff Base Ligands on Selective Crystallization of Dy³⁺ Complexes from Solution Containing Nd³⁺ and Dy³⁺

^○Hinako Masaki¹, Atsuko Masuya Suzuki², Ryo Tsunashima² (1. Faculty of Science, Yamaguchi University, 2. Graduate School of Sciences and Technology for Innovation, Yamaguchi University)

[Lang.] Japanese

2:00 PM - 2:10 PM

[K503-1pm-07] Synthesis and Luminescence Properties of Samarium Complexes with a 1,4,7,10-Tetraazacyclododecane Skeleton

^○Satono Nakai¹, Hidetaka Nakai¹ (1. Grad. Sch. Sci. Eng. Kindai Univ.)

[Lang.] Japanese

2:10 PM - 2:20 PM

[K503-1pm-08] Introduction of a Metal Ion to a Coordination Cage by a Lewis-Basic Anion Cap

^○Akira Taniguchi¹, Hiroki Takezawa¹, Makoto Fujita^1,2 (1. The Univ. of Tokyo, 2. Institute for Molecular Science)

[Lang.] Japanese

Break （2:20 PM - 2:30 PM）

2:30 PM - 2:40 PM

[K503-1pm-09] Synthesis and Luminescence Properties of Dysprosium Complexes with a 1,4,7,10-Tetraazacyclododecane Skeleton

^○Shungo Katsuki¹, Kaai Yamamoto², Hidetaka Nakai¹ (1. Grad. Sch. Sci. Eng. Kindai Univ., 2. Dept. Appl. Chem. Kindai Univ.)

[Lang.] Japanese

2:40 PM - 2:50 PM

[K503-1pm-10] Preparation of Yb Complexes Directed toward the Capture of Key Reaction Intermediates in Pinacol Coupling

^○Daisuke Yoshikawa¹, Kenichi Michigami¹, Mitsuhiro Ueda¹, Naoki Ishida², Masahiro Murakami², Masato Ohashi¹ (1. Osaka Metropolitan Univ., 2. Kyoto Univ.)

[Lang.] Japanese

2:50 PM - 3:00 PM

[K503-1pm-11] Synthesis of discrete Zr organometallic cages bearing photocatalytic moieties

^○Masaki Kitada¹, Yutaka Saga¹, Mio Kondo^1,2, Sigeyuki Masaoka¹ (1. Graduate School of Engineering Osaka University., 2. JST CREST)

[Lang.] Japanese

3:00 PM - 3:10 PM

[K503-1pm-12] Synthesis and structure of Zr complexes supported by biphenolate ligands

^○Masataka Oishi¹ (1. Tokyo Institute of Technology)

[Lang.] Japanese

3:10 PM - 3:20 PM

[K503-1pm-13] Syntheses and crystal structures of one-dimensional assembles consisting of Keggin-typed polyoxometalates with different internal ions and platinum-palladium trinuclear complex

^○Momoka Ohshika¹, Atsushi Takamori², Kazuhiro Uemura³ (1. Graduate School of Natural Science and Technology, Gifu Univ., 2. Graduate School of Engineering, Gifu Univ., 3. Faculty of Engineering, Gifu Univ.)

[Lang.] Japanese

3:20 PM - 3:30 PM

[K503-1pm-14] Syntheses and Crystal Structures of Two-dimensional Assembles Consisting of Keggin-typed Polyoxometalate and Tetranuclear Platinum Complex

^○Yuma Ito¹, Atsushi Takamori², Kazuhiro Uemura¹ (1. Faculty of Engineering, Gifu University, 2. Graduate School of Engineering, Gifu University)

[Lang.] Japanese

3:30 PM - 3:40 PM

[K503-1pm-15] Ligand Exchange Reaction on Manganese(II) Disilyl Complexes Involving Skeletal Rearrangement of Organosilyl Ligands

^○Yosuke Kawabuchi¹, Takuma Suzuki¹, Yoshimasa Wada^1,2, Yusuke Sunada^1,2 (1. Department of Applied Chemistry, School of Enginnering, The University of Tokyo, 2. Institute of Industrial Science, The University of Tokyo)

[Lang.] Japanese

Academic Program [Oral A]

[K503-1vn] 09. Coordination Chemistry, Organometallic Chemistry

Wed. Mar 22, 2023 4:10 PM - 6:40 PM K503 (K503, Lecture Hall Bldg. [5F])

Chair: Atsuko Masuya-Suzuki, Sota Sato

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4:10 PM - 4:20 PM

[K503-1vn-01] Synthesis of Iron Complexes Bearing Biaryl-Supported Silicon-Containing Ligands

^○Yuto Suga¹, Yusuke Sunada^1,2 (1. School of Engineering, The University of Tokyo, 2. Institute of Industrial Science, The University of Tokyo)

[Lang.] Japanese

4:20 PM - 4:30 PM

[K503-1vn-02] Solid-phase synthesis of metallopeptide as template for metal subnanoparticles

^○Yusuke Narita¹, Nanami Antoku, Shogo Saito², Masayoshi Tanaka², Takane Imaoka¹, Mina Okouchi², Kimihisa Yamamoto¹ (1. Lab Chem. Life Sci, Tokyo Institute of Technology, 2. School of Materials and Chemical Technology)

[Lang.] Japanese

4:30 PM - 4:40 PM

[K503-1vn-03] Mimicking Structure and Function of Non-heme Diiron Enzymes with a Macrocyclic Ligand

^○Keita Yamanaka¹, Tsubasa Hatanaka¹, Yasuhiro Funahashi¹ (1. Osaka Univ.)

[Lang.] Japanese

4:40 PM - 4:50 PM

[K503-1vn-04] Synthesis and Characterization of a [Fe₅₅] Nanocluster Protected by Bulky P^tBu₃

^○Kanata Tanaka¹, Koki Kawamoto², Shunya Oishi², Mizuki Tada², Tatsuya Higaki¹, Yasuhiro Ohki¹ (1. Institute for Chemical Research, Kyoto Univ., 2. Graduate School of Science and RCMS, Nagoya University)

[Lang.] Japanese

4:50 PM - 5:00 PM

[K503-1vn-05] Synthetic study of magnetic ionic liquid gels with iron(III) chloride

^○Shin Kiyokawa¹, Yumiko Takagi¹ (1. Kagawa University)

[Lang.] Japanese

5:00 PM - 5:10 PM

[K503-1vn-06] Synthesis and characterization of an iron(II) complex with 4-coordinate type alkylamine ligand directed toward the formation of higher oxidation bis-μ-oxo species

^○Ayami Yamamoto¹, Itsuki Igarashi², Tomohiko Inomata², Tomohiro Ozawa², Hideki Masuda³ (1. Nagoya Institute of Technology, 2. Graduate School of Engineering, Nagoya Institute of Technology, 3. Aichi Institute of Technology)

[Lang.] Japanese

5:10 PM - 5:20 PM

[K503-1vn-07] Preparation and characterization of Iron (III) complexes of sugar-conjugated fluorochlorin derivatives

^○Shino Nakashima¹, Haruo Akashi¹ (1. Okayama University of Science)

[Lang.] Japanese

Break （5:20 PM - 5:30 PM）

5:30 PM - 5:40 PM

[K503-1vn-08] Synthesis and Reduction of Heterobimetallic Complexes Containing a Vanadocene Skeleton

^○Asahi Suzuki¹, Hinano Kusunose¹, Tsubasa Hatanaka¹, Yasuhiro Funahashi¹ (1. Osaka Univ.)

[Lang.] Japanese

5:40 PM - 5:50 PM

[K503-1vn-09] Development of a water oxidation catalyst by the integration of pentanuclear iron complexes and graphene oxide

^○Zhi Yang¹, Takumi Matsuzaki¹, Yutaka Saga¹, Mio Kondo^1,2, Shigeyuki Masaoka¹ (1. Osaka University, 2. JST PRESTO)

[Lang.] English

5:50 PM - 6:00 PM

[K503-1vn-10] Synthesis and Properties of a Dinuclear Ruthenium(III,III) Complex Bridged by an Oxido and the Two Acetato Ligands

^○Masahiro Hayashi¹, Tomoyo Misawa¹, Hirotaka Nagao¹ (1. Fac. of Sci. and Tech., Sophia Univ.)

[Lang.] Japanese

6:00 PM - 6:10 PM

[K503-1vn-11] Synthesis of Hetero-Multinuclear Complexes Using Ruthenodithioethers and Ruthenodithiols

^○Ryoma Ohashi¹, Mina Tsujiwaki¹, Shin Takemoto¹, Hiroyuki Matsuzaka¹ (1. Osaka Metropolitan University)

[Lang.] Japanese

6:10 PM - 6:20 PM

[K503-1vn-12] Synthesis of Diruthenium Paddlewheel Complexes with Pyrenecarboxylate Ligands

^○Ren Takaki¹, Shinpei Kusaka², Hiroaki Iguchi², Ryotaro Matsuda² (1. Nagoya Univ., 2. Nagoya Univ. )

[Lang.] Japanese

6:20 PM - 6:30 PM

[K503-1vn-13] Stepwise reduction reactions from sulfite to disulfide on a dinuclear ruthenium complex

^○Motoki Yamada¹, Yasuhiro Arikawa¹, Shinnosuke Horiuchi¹, Eri Sakuda¹, Keisuke Umakoshi¹ (1. Nagasaki University)

[Lang.] Japanese

6:30 PM - 6:40 PM

[K503-1vn-14] Control of spatiotemporal structure of polymer aggregates by utilizing artificial photosynthetic reactions

^○Takafumi Enomoto¹, Aya Mizutani Akimoto¹, Ryo Yoshida¹ (1. Department of Materials Engineering, School of Engineering, The University of Tokyo)

[Lang.] Japanese

Academic Program [Oral A]

[K504-1vn] 09. Coordination Chemistry, Organometallic Chemistry

Wed. Mar 22, 2023 4:10 PM - 6:50 PM K504 (K504, Lecture Hall Bldg. [5F])

Chair: Souichirou Kawamorita, Yuya Tanaka

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4:10 PM - 4:20 PM

[K504-1vn-01] Theoretical study on electronic states of dinuclear ruthenium complexes that involve pi-electron groups in bridging ligands: Discussion based on orbital symmetry and orbital energy of pi-electron groups

^○Keisuke Sasaki¹, Naoka Amamizu¹, Yusuke Kataoka², Hsiu-Hui Chen³, I-Jui Hsu³, Ryohei Kishi^1,4,5,6, Yasutaka Kitagawa^1,4,5,6,7 (1. Graduate School of Engineering Science, Osaka University, 2. Graduate School of Natural Science and Technology, Shimane University, 3. National Taipei University of Technology, 4. QIQB, Osaka Univ., 5. RCSEC, Osaka Univ., 6. ICS-OTRI, Osaka Univ., 7. SRN-OTRI, Osaka Univ.)

[Lang.] Japanese

4:20 PM - 4:30 PM

[K504-1vn-02] Structure and Electrochemical Properties of Mononuclear Copper Complexes with Ethylenediamine-Based Pentadentate Ligands Bearing Quinoline Analogs

^○Miyu Akedo¹, Erina Hamamoto¹, Shoko Yoshida¹, Yuji Mikata¹ (1. Nara Women's University)

[Lang.] Japanese

4:30 PM - 4:40 PM

[K504-1vn-03] Structure and Electrochemical Properties of Mononuclear Copper Complexes with Oxygen-Containing Pentadentate Ligands Bearing Quinoline Analogs

^○Hinata Koike¹, Mizuho Uchida¹, Yuji Mikata¹ (1. Nara Women's University)

[Lang.] Japanese

4:40 PM - 4:50 PM

[K504-1vn-04] Theoretical study on control of frontier orbital energy of Ir-M (M = Mn, Fe, Co, Ni, Cu, Zn) hetero-binuclear complexes bridged by pyrazoles

^○Yuta Hayashi¹, Naoka Amamizu¹, Keisuke Sasaki¹, Masahiro Tsuda¹, Ryouhei Kishi^1,2,3,4, Yasutaka Kitagawa^1,2,3,4,5 (1. Graduate School of Engineering Science, Osaka Univ., 2. QIQB, Osaka Univ., 3. RCSEC, Osaka Univ., 4. ICS, Osaka Univ., 5. SRN, Osaka Univ.)

[Lang.] Japanese

4:50 PM - 5:00 PM

[K504-1vn-05] One-Pot Construction of ABCD Porphyrins through Platinum Templated Cyclization

^○Momoka Yokoyama¹, Ryo Inoue¹, Itsuki Maruyama¹, Yasuhiro Morisaki¹ (1. Kwansei Gakuin University)

[Lang.] Japanese

5:00 PM - 5:10 PM

[K504-1vn-06] Enhanced Emission in a Specific Aggregation State of trans-Bis(iminomethylpyrrolato)platinum(II) Complex bearing Vaulted Structure

^○Shufang Huang¹, Soichiro Kawamorita¹, Takeshi Naota¹ (1. Osaka University)

[Lang.] English

5:10 PM - 5:20 PM

[K504-1vn-07] On-Off Control of Emission of trans-Bis(iminomethylpyrazolato)platinum(II) Complex by External Stimuli

^○Junki MAEGAWA¹, Soichiro KAWAMORITA¹, Takeshi NAOTA¹ (1. Osaka University)

[Lang.] Japanese

5:20 PM - 5:30 PM

[K504-1vn-08] Long-range chirality recognition through 1D Eu(III) helicates

^○Kotaro Yakuwa¹, Junpei Yuasa¹ (1. Tokyo University of Science)

[Lang.] Japanese

Break （5:30 PM - 5:40 PM）

5:40 PM - 5:50 PM

[K504-1vn-09] Theoretical study on structure and magnetic anisotropy of
double-decker phthalocyanine terbium(III) complexes using
density functional theory method.

^○Koki Masuda¹, Masahiro Tsuda², Yuta Hayashi², Keisuke Sasaki², Mitsuhiro Nishida¹, Kazuki Honjo¹, Naoka Amamizu², Ryohei Kishi^2,3,4,5, Yasutaka Kitagawa^2,3,4,5,6 (1. Faculty of Engineering Sceience,Osaka University, 2. Graduate School of Engineering Sceince, Osaka University, 3. QIQB, Osaka University, 4. RCSEC, Osaka University, 5. ICS, Osaka University, 6. SRN, Osaka University)

[Lang.] Japanese

5:50 PM - 6:00 PM

[K504-1vn-10] Synthesis of NHC metal complexes for supramolecular tessellations

^○Hayato Takahashi¹, Shohei Saito¹ (1. Grad. Sch. of Sci. Kyoto Univ.)

[Lang.] Japanese

6:00 PM - 6:10 PM

[K504-1vn-11] Synthesis of metallocycle using NHC Cu(I) complex and its solid-state emission property

^○Rempei Ando¹, Mingoo Jin², Hajime Ito^1,2 (1. Graduate School of Engineering, Hokkaido University, 2. WPI-ICReDD, Hokkaido University)

[Lang.] Japanese

6:10 PM - 6:20 PM

[K504-1vn-12] Visible-Light-Induced Reactions Catalyzed by a Hollow Cage with Cyclometalated Pt(II) Corners

^○Rikuya Tanaka¹, Hiroki Takezawa¹, Makoto Fujita^1,2 (1. University of Tokyo, 2. Institute for Molecular Science)

[Lang.] Japanese

6:20 PM - 6:30 PM

[K504-1vn-13] An Acetylene-embedded Micelle that Binds Organic Dyes and Metal Salts

^○Shinnosuke Hirata¹, Yuri Katagiri¹, Yuya Tanaka¹, Michito Yoshizawa¹ (1. Tokyo Institute of Technology)

[Lang.] Japanese

6:30 PM - 6:40 PM

[K504-1vn-14] Water-solubilization of Mechanochromic Luminescent Solids by Aromatic Micelles

^○Yoshihisa Hashimoto¹, Yuri Katagiri¹, Yuya Tanaka¹, Michito Yoshizawa¹ (1. Tokyo institute of technology)

[Lang.] Japanese

6:40 PM - 6:50 PM

[K504-1vn-15] Naphthalene Diimide-Based Semiconducting Porous Coordination Polymers for Efficient Chemiresistive Gases Sensing

^○Ziqian Xue¹, Ken-ichi Otake¹, Yusuke Nishiyama², Susumu Kitagawa¹ (1. Kyoto univ., 2. RIKEN-JEOL Collaboration Center)

[Lang.] English

Academic Program [Oral A]

[K504-2am] 09. Coordination Chemistry, Organometallic Chemistry

Thu. Mar 23, 2023 9:00 AM - 11:40 AM K504 (K504, Lecture Hall Bldg. [5F])

Chair: Kiyonori Takahashi, Ryohei Akiyoshi

+Add all to schedule

9:00 AM - 9:10 AM

[K504-2am-01] Proton Conduction Behavior in Flexible Free-Standing Membranes of Coordination Polymers

^○Jiangfeng Lu¹, Yukihiro Yoshida¹, Hiroshi Kitagawa¹ (1. Kyoto University)

[Lang.] English

9:10 AM - 9:20 AM

[K504-2am-02] Synthesis of hydrophobic metal-organic frameworks for proton conduction

^○Tuo Di¹, Yukihiro Yoshida¹, Hiroshi Kitagawa¹ (1. Kyoto University)

[Lang.] English

9:20 AM - 9:30 AM

[K504-2am-03] Charge control and construction of multi-dimensional structure of paddlewheel-type diruthenium (II, II) complexes by post-synthetic molecular modifications

^○Chisa Itoh¹, Haruka Yoshino^1,2, Wataru Kosaka^1,2, Yusuke Ootani², Momoji Kubo², Toyohiko Konno², Hitoshi Miyasaka^1,2 (1. Tohoku Univ., 2. IMR, Tohoku Univ.)

[Lang.] Japanese

9:30 AM - 9:40 AM

[K504-2am-04] Synthesis of porous gels assembled from ruthenium-based metal-organic polyhedra

^○Fuerkaiti TAYIER¹, Javier Troyano², Shuhei Furukawa^1,2 (1. Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University, 2. Institute for Integrated Cell-Material Sciences (WPI-iCeMS), Kyoto University)

[Lang.] English

9:40 AM - 9:50 AM

[K504-2am-05] Carbon dioxide gate sorption properties of one-dimensional Cu complexes with paddlewheel dimer units

^○Sihao Xing¹, Xin Zheng², Kiyonori Takahashi³, Takayoshi Nakamura³, Shin-ichiro Noro^1,2 (1. Hokkaido University, Graduate School of Env.Science, 2. Hokkaido University, Faculty of Env.Earth Science, 3. Hokkaido University, RIES)

[Lang.] English

9:50 AM - 10:00 AM

[K504-2am-06] Formation of a two-dimensional Cd complex polymer using [2 + 2] photodimerization reaction

^○Shishi Du¹, Xin ZHENG², Kiyonori TAKAHASHI^1,3, Takayoshi NAKAMURA^1,3, Shin-ichiro NORO^1,2 (1. Hokkaido University Graduate School of Environmental Science, 2. Hokkaido University Faculty of Environmental Earth Science, 3. Hokkaido University, RIES)

[Lang.] English

10:00 AM - 10:10 AM

[K504-2am-07] Synthesis of Sulfur-Coordinated Semiconductive 1D Coordination Polymers Exhibiting Elasticity

^○Serina Nojima¹, Ryohei Akiyoshi¹, Akinori Saeki, Daisuke Tanaka¹ (1. Kwansei Gakuin University)

[Lang.] Japanese

10:10 AM - 10:20 AM

[K504-2am-08] Synthesis and Characterization of Two-Dimensional Semiconductive Coordination Polymer Exhibiting Liquid Crystalline Property

^○Chie Sawada¹, Ryohei Akiyoshi¹, Akinori Saeki², Shinya Hayami³, Daisuke Tanaka¹ (1. Kwansei Gakuin University, 2. Osaka University, 3. Kumamoto University)

[Lang.] Japanese

Break （10:20 AM - 10:30 AM）

10:30 AM - 10:40 AM

[K504-2am-09] Synthesis and Physical Property of NiPd(CN)₄ with Structural Complexities

^○yudai iwai¹, Ryo Ohtani¹, Masaaki Ohba¹ (1. kyushu university)

[Lang.] Japanese

10:40 AM - 10:50 AM

[K504-2am-10] Verification of Mechanism of Magnesium Ion Conduction in Metal–Organic Frameworks Having Large-Sized Pores

^○Takahiro Erikawa¹, Masaaki Sadakiyo¹ (1. Tokyo Univ. of Sci.)

[Lang.] Japanese

10:50 AM - 11:00 AM

[K504-2am-11] Acid Separation by an Acid-Tolerant Metal–Organic Framework Having Small-Sized Pores

^○Kyoko Shiraishi¹, Masaaki Sadakiyo¹ (1. Tokyo Univ. of Sci.)

[Lang.] Japanese

11:00 AM - 11:10 AM

[K504-2am-12] Superionic Conduction in a Magnesium-Ion-Containing Metal–Organic Framework under Water Vapor

^○Kaori Taniguchi¹, Masaaki Sadakiyo¹ (1. Tokyo Univ. of Sci.)

[Lang.] Japanese

11:10 AM - 11:20 AM

[K504-2am-13] Transparent Coordination Polymer Monolith for Intermediate Temperature Proton Conductivity

^○Ellan Berdichevsky¹, Nattapol Ma¹, Satoshi Horike^2,1 (1. Graduate School of Engineering, Kyoto University, 2. Institute for Advanced Study, Kyoto University)

[Lang.] English

11:20 AM - 11:30 AM

[K504-2am-14] CO₂ Electrolysis by Iron-Porphyrin Complexes Incorporated in Coordination Polymer Glasses

^○SARA SAIF ALI KHALID ALSHUKAILI^1,2, Hiroyasu Tabe^1,2, Satoshi Horike ^2,1 (1. Graduate School of Engineering, Kyoto University, 2. Institute for Advanced Study, Kyoto University)

[Lang.] English

11:30 AM - 11:40 AM

[K504-2am-15] Effects of amount and state of the accommodated guest molecules on the luminescent property of naphthalenediimide-based MOF

^○Shoto Yamashita¹, Yohei Takashima¹, Takaaki Tsuruoka¹, Kensuke Akamatsu¹ (1. Konan University)

[Lang.] Japanese

Academic Program [Oral A]

[K503-2am] 09. Coordination Chemistry, Organometallic Chemistry

Thu. Mar 23, 2023 9:00 AM - 11:40 AM K503 (K503, Lecture Hall Bldg. [5F])

Chair: Akihiro Tsurusaki, Yoshiyuki Mizuhata

+Add all to schedule

9:00 AM - 9:10 AM

[K503-2am-01] Synthesis and Properties of an Iron Complex Ligated by Aluminum(I) Hydride

^○Keita Sato¹, Takashi Komuro¹, Hisako Hashimoto¹ (1. Tohoku Univ.)

[Lang.] Japanese

9:10 AM - 9:20 AM

[K503-2am-02] Synthesis, Propaties and Reactivity of Gallylenes Bearing a Phenalenyl-Based Ligand

^○Nijito Mukai¹, Takuya Kodama^1,2, Mamoru Tobisu^1,2 (1. Graduate Shcool of Engineering, Osaka University, 2. Osaka University ICS-OTRI)

[Lang.] Japanese

9:20 AM - 9:30 AM

[K503-2am-03] Synthesis and Photophysical Property of Sila-Functionalized Silyldiarylboranes

^○Mutsuki Tanaka¹, Atsushi Kawachi² (1. Graduate School of Science and Engineering, Hosei University, 2. Faculty of Bioscience and Applied Chemistry, Hosei University)

[Lang.] Japanese

9:30 AM - 9:40 AM

[K503-2am-04] Functionalized Disilanylboronic Esters: Synthesis and Transition-Metal-Catalyzed Reaction

^○Jiaying Li¹, Toshimichi Ohmura², Michinori Suginome¹ (1. Kyoto University, 2. Kyoto Institute of Technology)

[Lang.] Japanese

9:40 AM - 9:50 AM

[K503-2am-05] Silicon-Containing Ring Formation through Carbon Skeletal Reorganization of 1,3-Dienes Using an (Aminosilyl)boronic Ester

^○Miki Inagaki¹, Takeru Torigoe¹, Toshimichi Ohmura¹ (1. Kyoto Institute of Technology)

[Lang.] Japanese

9:50 AM - 10:00 AM

[K503-2am-06] Synthesis of (Boryl)oligosilanes Using Boron-substituted Silyllithium

^○Yuta Kowada¹, Atsushi Kawachi² (1. Graduate School of Science and Engineering, Hosei University, 2. Faculty of Bioscience and Applied Chemistry, Hosei University)

[Lang.] Japanese

10:00 AM - 10:10 AM

[K503-2am-07] Synthesis of Oxygen-Free Polycarbosilane

^○Fuki MIYAJIMA¹, Soichiro KYUSHIN¹, Mitsuhiko SATO², Masaki SUGIMOTO³, Akira IDESAKI³ (1. Graduate School of Science and Technology, Gunma Univ., 2. The Center for Ceramic Matrix Composites, Tokyo University of Technology, 3. Takasaki Advanced Radiation Research Institute)

[Lang.] Japanese

10:10 AM - 10:20 AM

[K503-2am-08] Synthesis of Perisopropyl-Substituted Ladder Oligogermanes

^○Koki UEHARA¹, Ryoji TANAKA², Soichiro KYUSHIN¹, Hideyuki MATSUMOTO¹ (1. Graduate School of Science and Technology, Gunma Univ., 2. Sagami Chemical Research Institute)

[Lang.] Japanese

Break （10:20 AM - 10:30 AM）

10:30 AM - 10:40 AM

[K503-2am-09] Structures and Properties of Dianions of Tetraphenylporphyrin-Silicon Complexes

^○Yuzuha Aoki¹, Tomohiro Tsumuraya¹, Soichiro Kyushin¹ (1. Graduate School of Science and Technology, Gunma Univ.)

[Lang.] Japanese

10:40 AM - 10:50 AM

[K503-2am-10] Synthesis and Reactivities of Cationic Silicon(II) Species Stabilized by an Iminophosphonamide Ligand

^○Kazuki Nakaya¹, Akihiko Ishii¹, Norio Nakata¹ (1. Saitama University)

[Lang.] Japanese

10:50 AM - 11:00 AM

[K503-2am-11] Syntheses and reactivities of hydrogermylene with an intramolecular NHC-amino ligand

^○Ryo Akama¹ (1. The Univ. of Saitama)

[Lang.] Japanese

11:00 AM - 11:10 AM

[K503-2am-12] Robust C-F bond Activaton Mediated by Iminophosphonamido-Chlorosilylene

^○Takuya Awaji¹, Shintaro Takahishi¹, Akihiko Ishii¹, Norio Nakata¹ (1. Saitama University)

[Lang.] Japanese

11:10 AM - 11:20 AM

[K503-2am-13] Synthesis and reactivities of gold(Ⅰ) complexes bearing an iminophosphonamido-aminosilylene ligand

^○Shota Kamiyama¹, Akihiko Ishii¹, Norio Nakata¹ (1. Saitama university)

[Lang.] Japanese

11:20 AM - 11:30 AM

[K503-2am-14] Synthesis and Structure of Plumbylene with Bulky Thiolate Ligands

^○Ryo Matsukura¹, Kohei Sugano¹, Futo Koizumi¹, Kei Ota¹, Daisuke Hashizume², Tsukasa Matsuo¹ (1. Kindai Univ., 2. RIKEN)

[Lang.] Japanese

11:30 AM - 11:40 AM

[K503-2am-15] Synthesis of Compounds of Group 15 Elements Bearing Bulky Rind Groups

^○Yuria Kawase¹, Kei Ota¹, Tsukasa Matsuo¹ (1. Kindai Univ.)

[Lang.] Japanese

Academic Program [Oral A]

[K504-2pm] 09. Coordination Chemistry, Organometallic Chemistry

Thu. Mar 23, 2023 1:00 PM - 3:40 PM K504 (K504, Lecture Hall Bldg. [5F])

Chair: Keishiro Tahara, Masahiro Yamashina

+Add all to schedule

1:00 PM - 1:10 PM

[K504-2pm-01] Theoretical study on relationship between electronic structure and magnetic anisotropy in bathocuproine cobalt(II) complexes.

^○Masahiro Tsuda¹, Yasutaka Kitagawa^1,3,5,4,6, Ryohei Kishi^1,3,4,5, Koki Masuda², Naoka Amamizu¹, Keisuke Sasaki¹, Yuta Hayashi¹, Mitsuhiro Nishida², Kazuki Honjo² (1. Graduate School of Engineering Science, Osaka Univ., 2. Faculty of Engineering Science, Osaka Univ., 3. QIQB, Osaka Univ., 4. RCSEC, Osaka Univ., 5. ICS-OTRI, Osaka Univ., 6. SRN-OTRI, Osaka Univ.)

[Lang.] Japanese

1:10 PM - 1:20 PM

[K504-2pm-02] Multi-Dynamic Crystalline Molecular Rotors by N-Heterocyclic Carbene Binuclear Au(I) Complex with Solvated THF

^○Mingoo Jin¹, Satsuki Matsuura, Hikaru Yamamoto², Motohiro Mizuno³, Hajime Ito^1,2 (1. WPI-ICReDD, Hokkaido University, 2. Department of Engineering, Faculty of Applied Chemistry, 3. NanoMaterials Research Institute, Kanazawa University)

[Lang.] English

1:20 PM - 1:30 PM

[K504-2pm-03] Two-dimensionally geared intermolecular structure in crystal formed by Au(Ⅰ) complexes bearing triptycene and triadamantylphosphine

^○Hikaru Yamamoto¹, Rempei Jin¹, MIngoo Jin², Hajime Ito^1,2 (1. Graduate School of Engineering, Hokkaido University, 2. WPI-ICReDD, Hokkaido University)

[Lang.] Japanese

1:30 PM - 1:40 PM

[K504-2pm-04] Reactivity of benzo- and benzofurane-fused iridaoxabenzenes

^○Hinako Abeta¹, Youichi Ishii¹, Takahiro Iwamoto¹, Mika Suzuki (1. Chuo University)

[Lang.] Japanese

1:40 PM - 1:50 PM

[K504-2pm-05] Synthesis and Structure of Nickel(0) Complex Coordinated with Antiaromatic Hydrocarbon

^○Takefumi Imanishi¹, Junichi Usuba¹, Kosuke Yasui¹, Yuta Uetake², Aiko Fukazawa¹ (1. The Univ. of Kyoto, 2. The Univ. of Osaka)

[Lang.] Japanese

1:50 PM - 2:00 PM

[K504-2pm-06] Synthesis, Structure, and Luminescence Properties of Terbium Complexes with a Chiral 1,4,7,10-Tetraazacyclododecane Skeleton

^○Hisaki Matsui¹, Shunsuke Suga¹, Hidetaka Nakai¹ (1. Grad. Sch. Sci. Eng. Kindai Univ.)

[Lang.] Japanese

2:00 PM - 2:10 PM

[K504-2pm-07] Closed Cavity-directed Recognition and Detection of Unprotected Dipeptides by a Polyaromatic Capsule

^○Mayu Shuto¹, Ryuki Sumida¹, Tomohisa Sawada^1,2, Michito Yoshizawa¹ (1. Lab. for Chem. & Life Sci., Tokyo Inst. of Tech., 2. JST-PRESTO)

[Lang.] Japanese

2:10 PM - 2:20 PM

[K504-2pm-08] Efficient Binding and Cyclization of Linear Monoterpenes by a Polyaromatic Capsule

^○Ryuki Sumida¹, Michito Yoshizawa¹ (1. Lab. for Chem. & Life Sci., Tokyo Tech)

[Lang.] Japanese

Break （2:20 PM - 2:30 PM）

2:30 PM - 2:40 PM

[K504-2pm-09] Coordination cross-linked assemblies of polyaromatic capsules and their host ability

^○Yohei Kobayashi¹, Ryuki Sumida¹, Michito Yoshizawa¹ (1. Lab. for Chem. & Life Sci., Tokyo Tech)

[Lang.] Japanese

2:40 PM - 2:50 PM

[K504-2pm-10] External Saccharide-modification of a Polyaromatic Capsule

^○Mayuko Ueda¹, Lorenzo Catti¹, Michito Yoshizawa¹ (1. Lab. for Chem. & Life Sci., Tokyo Tech)

[Lang.] Japanese

2:50 PM - 3:00 PM

[K504-2pm-11] Coordination Cages with Bianthryl Ligand: Control of Assembly Structure Based on the Side-Chain Steric Effect and Evaluation of Encapsulation Ability

^○Sota Watanabe¹, Masahiro Yamashina¹, Shinji Toyota¹ (1. Tokyo Inst. of Tech.)

[Lang.] Japanese

3:00 PM - 3:10 PM

[K504-2pm-12] Vapor-induced emission enhancement of hexanuclear copper(I) and silver(I) complexes in the crystalline states

^○Yuki Takenaka¹, Haruki Inoue¹, Yuga Yamashita¹, Yoshiki Ozawa¹, Keishiro Tahara¹, Masaaki Abe¹ (1. University of Hyogo)

[Lang.] Japanese

3:10 PM - 3:20 PM

[K504-2pm-13] Guest-dependence of Luminescence Piezochromism of Cubane-type Silver(I) Iodide Complex in Crystalline States

^○Mayuka Fujiwara¹, Takuya Sakagami¹, Yoshiki Ozawa¹, Masaaki Abe¹, Keishiro Tahara¹ (1. Univ. of Hyogo)

[Lang.] Japanese

3:20 PM - 3:30 PM

[K504-2pm-14] Core Isomerism of Diphosphine-Bridged Diruthenium Complexes Bearing Proton-Responsive Ligand

^○Kazuki Shinozaki¹, Satoshi Suzuki¹, Yoshihito Kayaki¹, Shinji Ando¹, Shigeki Kuwata² (1. Tokyo Institutte of Technology, 2. Ritsumeikan University)

[Lang.] Japanese

3:30 PM - 3:40 PM

[K504-2pm-15] Band Structures and Electrical Conductivities of Heterometallic One-dimensional Chains

^○Kazuhiro Uemura¹, Masahiro Sato² (1. Faculty of Engineering, Gifu University, 2. School of Engineering, The University of Tokyo)

[Lang.] Japanese

Academic Program [Oral A]

[K503-2pm] 09. Coordination Chemistry, Organometallic Chemistry

Thu. Mar 23, 2023 1:00 PM - 3:40 PM K503 (K503, Lecture Hall Bldg. [5F])

Chair: Masaaki Sadakiyo, Shouhei Tashiro

+Add all to schedule

1:00 PM - 1:10 PM

[K503-2pm-01] Crystal Growth and Thin Film Formation of Sulfur-Coordinated Semiconductive Coordination Polymers on Pb Substrates

^○Misaki Ueno¹, Sawa Hongo¹, Ryohei Akiyoshi¹, Daisuke Tanaka¹ (1. Kwanseigakuin University)

[Lang.] Japanese

1:10 PM - 1:20 PM

[K503-2pm-02] Synthesis and Crystal Size Control of Sulfur-Containing One-Dimensional Metal-Organic Frameworks Using Microfluidic Systems

^○Yuya Azuma¹, Ryohei Akiyoshi¹, Daisuke Tanaka¹ (1. Kwansei Gakuin University)

[Lang.] Japanese

1:20 PM - 1:30 PM

[K503-2pm-03] Synthesis, structural transformation, and ionic conductivity of lithium-based coordination polymers

^○Kotoha Kageyama¹, Satoshi Horike^2,1 (1. Graduate School of Engineering, Kyoto University, 2. Institute for Advanced Study, Kyoto University)

[Lang.] Japanese

1:30 PM - 1:40 PM

[K503-2pm-04] Synthesis and Metal Recognition of Novel Schiff Base-Type [2+2] Macrocycles

^○Yuki Yamaguchi¹, Makoto Miyasaka¹ (1. Graduate school of Engineering, Tokyo Denki University)

[Lang.] Japanese

1:40 PM - 1:50 PM

[K503-2pm-05] Synthesis and evaluation of aqueous MOF dispersion using structural transformation reaction

^○Saaya Yamanouchi¹, Yohei Takashima¹, Takaaki Tsuruoka¹, Kensuke Akamatsu¹ (1. Konan Univ FIRST)

[Lang.] Japanese

1:50 PM - 2:00 PM

[K503-2pm-06] Creation of exposed surface on chemically modified gold superatom: selective removal of the ligand

^○Yuto Fukumoto¹, Tsubasa Omoda², Haru Hirai³, Shinjiro Takano¹, Tatsuya Tsukuda¹ (1. Fac. of Sci., The Univ. of Tokyo, 2. Sch. of Mater. and Chem. Tech., Tokyo Tech, 3. Grad. Sch. of Sci., The Univ. of Tokyo)

[Lang.] English

Break （2:00 PM - 2:10 PM）

2:10 PM - 2:20 PM

[K503-2pm-07] MOF-Supported Molybdenum Complexes as Reusable Nitrogen Fixation Catalyst

^○Yoshikatsu Kameda¹, Shun Suginome¹, Yoshiaki NIshibayashi¹ (1. School of Engineering, The University of Tokyo)

[Lang.] Japanese

2:20 PM - 2:30 PM

[K503-2pm-08] Direct synthesis of cyanate anion from dinitrogen catalyzed by molybdenum-nitride complexes

^○Keita Sugiyama¹, Shun Suginome¹, Yoshiaki Nishibayashi¹ (1. School of Engineering, The University of Tokyo)

[Lang.] Japanese

2:30 PM - 2:40 PM

[K503-2pm-09] Development of Solid-State Catalytic Nitrogen Fixation Reaction Using Molybdenum Complex

^○Kurumi MUROTA¹, Shun SUGINOME¹, Yoshiaki NISHIBAYASHI¹ (1. School of Engineering, The University of Tokyo)

[Lang.] Japanese

2:40 PM - 2:50 PM

[K503-2pm-10] Development of Ammonia Formation Catalyzed by Molybdenum and Samarium Complexes

^○Taichi Mitsumoto¹, Yasuomi Yamazaki¹, Shogo Kuriyama¹, Yoshiaki Nishibayashi¹ (1. School of Engineering, The University of Tokyo)

[Lang.] Japanese

2:50 PM - 3:00 PM

[K503-2pm-11] Photoreduction of CO₂using molybdenum complexes as self-photosensitized catalysts

^○Hiroaki Shibayama¹, Hiroko Okuwa¹, Kenji Kamada¹, Jieun Jung¹, Susumu Saito^1,2 (1. Grad. Sch. Sci., Nagoya Univ., 2. IRCCS, Nagoya Univ.)

[Lang.] Japanese

3:00 PM - 3:10 PM

[K503-2pm-12] Activation and catalytic reduction of dinitrogen with novel molybdenum complexes bearing tripodal ligands

^○Shoki Yabutani¹, Tomohiro Ozawa¹, Tomohiko Inomata¹, Hideki Masuda^1,2 (1. Graduate School of Engineering, Nagoya Institute of Technology, 2. Aichi Institute of Technology)

[Lang.] Japanese

3:10 PM - 3:20 PM

[K503-2pm-13] Synthesis of molybdenum complex with novel PCP-type pincer ligand for improving ammonia production activity.

^○Yuma Ishitobi¹, Yoshiaki NISHIBAYASHI² (1. Idemitsu Kosan Co.,Ltd., 2. School of Engineering, The University of Tokyo)

[Lang.] Japanese

3:20 PM - 3:30 PM

[K503-2pm-14] Visible-Light-Driven Photocatalytic Nitrogen Fixation with High Efficiency

^○Takahiro Kubo^1,2, Yasuomi YAMAZAKI^1,2, Yoshiaki Nishibayasi^1,2 (1. The University of Tokyo, 2. School of Engineering)

[Lang.] Japanese

3:30 PM - 3:40 PM

[K503-2pm-15] Catalytic Ammonia Production Using Molybdenum Pincer-Type Complexes Bearing Pyridine Derivative Moieties for Promoting Proton-Coupled Electron Transfer

^○Kaito Nakaya^1,2, Yasuomi Yamazaki^1,2, Yoshiaki Nishibayashi^1,2 (1. The university of Tokyo, 2. Faculty of Engineering)

[Lang.] Japanese

Academic Program [Oral A]

[K503-2vn] 09. Coordination Chemistry, Organometallic Chemistry

Thu. Mar 23, 2023 4:10 PM - 6:50 PM K503 (K503, Lecture Hall Bldg. [5F])

Chair: Ken Tanaka, Yoshimasa Wada

+Add all to schedule

4:10 PM - 4:20 PM

[K503-2vn-01] Synthesis of Amide Complexes of Low-Valent Cobalt by Utilizing Stabilization with Aromatic Rings

^○Shinnosuke Otsuka¹, Tsubasa Hatanaka¹, Yasuhiro Funahashi¹ (1. Osaka Univ.)

[Lang.] Japanese

4:20 PM - 4:30 PM

[K503-2vn-02] Syntheses and properties of fac- and mer-type cobalt complexes bearing bis(2-pyridylmethyl)ether

^○Ryo Toriba¹, Tomoyo Misawa¹, Hirotaka Nagao¹ (1. Fac. of Sci. and Tech., Sophia Univ.)

[Lang.] Japanese

4:30 PM - 4:40 PM

[K503-2vn-03] Construction of Co-oxo Clusters Using Rigid Triptycene-based Multi-dentate Ligands

^○Keisuke Ito^1,2, Tomoya Fukui^1,2, Takuya Shiga³, Masayuki Nihei³, Takanori Fukushima ^1,2 (1. CLS, Tokyo Tech., 2. Sch. Mater. and Chem. Tech., Tokyo Tech., 3. Univ. of Tsukuba)

[Lang.] Japanese

4:40 PM - 4:50 PM

[K503-2vn-04] Study on Synthesis and Adsorption Heat of a Cobalt(II) Nanoporous Metal Complex

^○Kako Ohno¹, Shinpei Kusaka², Hiroaki Iguchi², Ryotaro Matsuda² (1. Nagoya Univ., 2. Nagoya Univ. )

[Lang.] Japanese

4:50 PM - 5:00 PM

[K503-2vn-05] Synthesis and reactivity of multinulear rhodium complexes bearing tetra-tert-butoxy disilicate ligand

^○Yusuke Ishizaka¹, Kazuhiro Matsumoto¹, Jun-Chul Choi¹ (1. National Institute of Advanced Industrial Science and Technology)

[Lang.] Japanese

5:00 PM - 5:10 PM

[K503-2vn-06] Synthesis of dinuclear Rh complexes containing macrocyclic pincer ligand

^○Junichi Ito¹, Ayaka Komori², Makoto Yamashita² (1. Japan Coast Guard Academy, 2. Graduate School of Engineering, Nagoya University)

[Lang.] Japanese

5:10 PM - 5:20 PM

[K503-2vn-07] Fabrication of metal–organic polyhedra with expandable skeletons

^○Yuto Osugi¹, Ami Nishijima², Takashi Uemura² (1. School of Engineering, The Univ. of Tokyo, 2. Graduate School of Engineering, The Univ. of Tokyo)

[Lang.] Japanese

5:20 PM - 5:30 PM

[K503-2vn-08] Synthesis of Oxo-bridged Rhodium-gold Multi-metallic complexes and Selective Metal Exchange Reactions on the Bridging Oxo Ligand

^○Hiroki Mori¹, Hayato Tsurugi¹, Kazushi Mashima² (1. Graduate School of Engineering Science, Osaka University, 2. Graduate School of Pharmaceutical Sciences, Osaka University)

[Lang.] Japanese

5:30 PM - 5:40 PM

[K503-2vn-09] Synthesis, Structure, and Reactivity of Rhodium and Iridium Dinuclear Complexes with Oxysulfur Ligands

^○Shinji Suzuki¹, Hidetaka Nakai¹ (1. Grad. Sch. Sci. Eng. Kindai Univ.)

[Lang.] Japanese

Break （5:40 PM - 5:50 PM）

5:50 PM - 6:00 PM

[K503-2vn-10] Synthesis and Properties of Cp*Ir Complexes Coordinated with N-alkyl/O-alkyl-3-hydoxypyrazole.

^○Genta Horiguchi¹, Yoshihito Kayaki¹, Shigeki Kuwata² (1. Tokyo Institute of Technology, 2. Ritsumeikan University )

[Lang.] Japanese

6:00 PM - 6:10 PM

[K503-2vn-11] π-Conjugated Nickel Complexes featuring α-Cyanocarbanion Ligands

^○Koji Matsuda¹, Hiroki Yamamoto, Hajime Kameo¹, Hiroyuki Matsuzaka¹ (1. Osaka Metropolitan University )

[Lang.] Japanese

6:10 PM - 6:20 PM

[K503-2vn-12] Synthesis of Bimetallic Complexes Bearing a PNiP Pincer Ligand

^○Kouki Fujita¹, Kazuhiko Semba¹, Yoshiaki Nakao¹ (1. Graduate School of Engineering, Kyoto Univesity)

[Lang.] Japanese

6:20 PM - 6:30 PM

[K503-2vn-13] Synthesis and Characterization of Group 10 Transition Metal Complexes Bearing a NHC/Pyridyl Hybrid Ligand.

^○Masaya Okamura¹, Kobana Saki¹, Kitahara Misa¹, Suzuki Rena¹, Shiro Hikichi¹ (1. Kanagawa University)

[Lang.] English

6:30 PM - 6:40 PM

[K503-2vn-14] Synthetic Studies on Nickel(I) Complexes Bearing a Phenalenyl-Based Tridentate Ligand

^○Hikaru NOGUCHI¹, Takuya KODAMA^1,2, Mamoru TOBISU^1,2 (1. Faculty of Engineering, Osaka University, 2. ICS-OTRI, Osaka University)

[Lang.] English

6:40 PM - 6:50 PM

[K503-2vn-15] Synthesis and Reactivity of Nickel Complexes Having Isoindoline-Based Polyprotic Pyrazole Ligand

^○WEI SYUAN LIN¹, Shigeki KUWATA² (1. Tokyo Institute of Technology, 2. Ritsumeikan University)

[Lang.] English

Academic Program [Oral A]

[K502-2vn] 09. Coordination Chemistry, Organometallic Chemistry

Thu. Mar 23, 2023 4:10 PM - 6:50 PM K502 (K502, Lecture Hall Bldg. [5F])

Chair: Takashi Komuro, Takuya Kodama

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4:10 PM - 4:20 PM

[K502-2vn-01] Synthesis and Singlet Oxygen Trapping of Cage-shaped Nanoporous Metal Complexes Bearing Anthracene Moieties

^○Satoko Ito¹, Shinpei Kusaka², Hiroaki Iguchi², Ryotaro Matsuda² (1. Nagoya Univ., 2. Nagoya Univ. )

[Lang.] Japanese

4:20 PM - 4:30 PM

[K502-2vn-02] Evolution of MOF crystals from newly generated amorphous MOFs

^○Takumi Kakuchi¹, Youhei Takashima², Takaaki Tsuruoka², Kensuke Akamatsu² (1. Konan graduate school, 2. Konan University)

[Lang.] Japanese

4:30 PM - 4:40 PM

[K502-2vn-03] Separation of nitrate anion from water using a shaped MOF-polymer composite

^○Aditya Irfan Witono¹, Xin Zheng², Shin-ichiro Noro^1,2 (1. Hokkaido Univ. Grad. school of Environmental Sciences, 2. Hokkaido Univ. Fac. of Environmental Earth Sciences)

[Lang.] English

4:40 PM - 4:50 PM

[K502-2vn-04] Solar Hydrogen Production using TiO₂ Photoanode Modified with Various Zn Porphyrins

^○Naoto Nakashima¹, Ken Sakai¹, Hironobu Ozawa¹ (1. Dept. Chem. Kyushu Univ.)

[Lang.] Japanese

4:50 PM - 5:00 PM

[K502-2vn-05] Visible-Light-Mediated Reductive Transformation of Aryl Chlorides Catalyzed by Organic Aluminum Complexes

Yoshihiro Nishimoto¹, ^○Ryota Takahashi¹, Takuma Miyamura⁴, Yasuko Osakada³, Mamoru Fujitsuka², Manabu Abe⁴, Makoto Yasuda¹ (1. Graduate School of Engineering, Osaka University, 2. SANKEN (The Institute of Scientific and Industrial Research) Osaka University, 3. Institute for Advanced Co-Creation Studies, SANKEN (The Institute of Scientific and Industrial Research) Osaka University, 4. Graduate School of Advanced Science and Engineering Hiroshima University)

[Lang.] Japanese

5:00 PM - 5:10 PM

[K502-2vn-06] Development of Al Complexes with Phosphino Group-Substituted Carbon Ligand for Lewis Acid/Lewis Base Catalyst

Yoshihiro Nishimoto¹, ^○Hirotaka Okamoto¹, Makoto Yasuda¹ (1. Graduate School of Engineering, Osaka University)

[Lang.] English

5:10 PM - 5:20 PM

[K502-2vn-07] Synthesis of Alkoxyoligosilanes via Ruthenium-Catalyzed Hydrosilylation of Aldehydes

^○Yasuhiro SUNAGA¹, Ken-ichiro KANNO¹, Soichiro KYUSHIN¹ (1. Graduate School of Science and Technology, Gunma Univ.)

[Lang.] Japanese

Break （5:20 PM - 5:30 PM）

5:30 PM - 5:40 PM

[K502-2vn-08] Reactivity of Diarylstannylenes Bearing Bulky Rind Groups

^○Yuto Ueno¹, Shigeaki Konaka¹, Kei Ota¹, Tsukasa Matsuo¹ (1. Kindai Univ.)

[Lang.] Japanese

5:40 PM - 5:50 PM

[K502-2vn-09] Transformation of carbon dioxide using three-coordinated tin(II) complexes supported by an intramolecular NHC-amino ligand

^○Soichiro Miyake¹, Akihiko Ishii¹, Norio Nakata¹ (1. Graduate School of Science and Engineering, Saitama University)

[Lang.] Japanese

5:50 PM - 6:00 PM

[K502-2vn-10] Synthesis of Tertiary Silanes by Ruthenium-Catalyzed Redistribution Reactions of Secondary Silanes

^○Honami YOKOYA¹, Ken-ichiro KANNO¹, Soichiro KYUSHIN¹ (1. Graduate School of Science and Technology, Gunma Univ.)

[Lang.] Japanese

6:00 PM - 6:10 PM

[K502-2vn-11] Photocatalytic CO₂ reduction catalyzed by S₂N₂-type 3d-metal complexes bearing pyridine pendants as Lewis-acid binding sites

^○Asuka Hamaguchi¹, Tomoya Ishizuka¹, Takuya Kawanishi¹, Takahiko Kojima¹ (1. University og Tsukuba)

[Lang.] Japanese

6:10 PM - 6:20 PM

[K502-2vn-12] Electrochemical Hydrogen Evolution Reaction Catalyzed by a Dinuclear Cobalt Complex bearing Doubly N-confused Hexaphyrin

^○Risa TAKADA¹, Takashi Nakazono², Daichi Sugawara¹, Tohru Wada¹ (1. College of Science, Department of Chemistry, Rikkyo University, 2. Research Center for Artificial Photosynthesis (ReCAP), Osaka Metropolitan University)

[Lang.] Japanese

6:20 PM - 6:30 PM

[K502-2vn-13] Development of a new photocatalytic system using two-layer solutions for water splitting

^○Masaru OGASAWARA¹, Yasuomi YAMAZAKI¹, Yoshiaki NISHIBAYASHI¹ (1. School of Engineering, The University of Tokyo)

[Lang.] Japanese

6:30 PM - 6:40 PM

[K502-2vn-14] Elucidation of Ligand Effects on Iridium-catalyzed Hydrogenolysis of Urea Derivatives into Formamides and Amines

^○Naoki Naito¹, Kazuki Tsuge², Takanori Iwasaki², Kyoko Nozaki² (1. Sch. of Eng., The Univ. of Tokyo, 2. Grad. Sch. of Eng., The Univ. of Tokyo)

[Lang.] Japanese

6:40 PM - 6:50 PM

[K502-2vn-15] Pd-Catalyzed Arylation of Ge-Me Bond

^○Kanta Ooishi¹, Akihiro Mushiake, Hajime Kameo¹, Hiroyuki Matsuzaka¹ (1. Osaka Metropolitan University)

[Lang.] Japanese

Academic Program [Oral A]

[K504-2vn] 09. Coordination Chemistry, Organometallic Chemistry

Thu. Mar 23, 2023 4:10 PM - 6:50 PM K504 (K504, Lecture Hall Bldg. [5F])

Chair: Masanori Takimoto, Takahiro Iwamoto

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4:10 PM - 4:20 PM

[K504-2vn-01] Imidoyl C-H Alkylation of Aldimines with Alkenes by Rare-Earth Catalysts

^○Zhou Sun¹, Masayoshi Nishiura¹, Xuefeng Cong¹, Zhaomin Hou¹ (1. RIKEN)

[Lang.] English

4:20 PM - 4:30 PM

[K504-2vn-02] Synthesis of Chiral BINOL-Based MOF by Photo-Deprotection

Takahiro Sawano¹, ^○Sora Kataguchi¹, Yuta Goto¹, Hiroyuki Arafune², Ryo Takeuchi¹ (1. Aoyama Gakuin University, 2. National Institute of Technology, Tsuruoka College)

[Lang.] Japanese

4:30 PM - 4:40 PM

[K504-2vn-03] Synthesis of 1,3,5-triazine using Nb/Fe catalyzed cross-cycloaddition with nitrile and trifluorotoluene

^○Tomohisa Murakami¹, Yuki Hori¹, Yuta Shiraishi¹, Maito Fuji¹, Wataru Hato², Yuto Isomura², Akito Uchida², Yasushi Obora¹ (1. Fac. Chem. Matl. & Bioeng., Kansai Univ, 2. TOHO KASEI CO.,LTD)

[Lang.] English

4:40 PM - 4:50 PM

[K504-2vn-04] Development of Tungsten Complexes Bearing PNNP-type Tetradentate Ligands for Visible-Light-Driven CO₂ Reduction

^○Chihiro Yamada¹, Taku Wakabayashi¹, Jieun Jung¹, Susumu Saito^1,2 (1. Grad. Sch. Sci., Nagoya Univ., 2. IRCCS, Nagoya Univ.)

[Lang.] Japanese

4:50 PM - 5:00 PM

[K504-2vn-05] Photocatalytic CO₂ Reduction Using Manganese Complexes Bearing Ferrocenyl Groups and an Organic Photosensitizer

^○Eimi Tanahashi¹, Taku Wakabayashi¹, Jieun Jung¹, Susumu Saito^1,2 (1. Grad.Sch.Sci.,Nagoya Univ., 2. IRCCS, Nagoya Univ.)

[Lang.] Japanese

5:00 PM - 5:10 PM

[K504-2vn-06] Synthesis of Manganese Complexes having a PN Ligand and Application to Hydrogenation of Carbonyl Compounds

^○Ninna Saito¹, Takanori Iwasaki², Kyoko Nozaki² (1. The Univ. of Tokyo, 2. Grad. Sch. of Eng., The Univ. of Tokyo)

[Lang.] Japanese

5:10 PM - 5:20 PM

[K504-2vn-07] Photochemical CO₂ Reduction by Framework Catalysts Based on Metal Porphyrin Complexes Bearing Pyrene Moieties

^○Marc Alec Dominic Ong Yau¹, Kento Kosugi¹, Maho Imai¹, Yutaka Saga¹, Mio Kondo^1,2, Shigeyuki Masaoka¹ (1. Osaka University, 2. JST PRESTO)

[Lang.] English

Break （5:20 PM - 5:30 PM）

5:30 PM - 5:40 PM

[K504-2vn-08] Photocatalytic CO₂ reduction using a supramolecular photocatalyst with ring-shaped Re(I) trinuclear complex as a photosensitizer unit

^○Yutaro Fujita¹, Yusuke Tamaki¹, Osamu Ishitani^1,2 (1. Tokyo Institute of Technology, 2. Hiroshima University)

[Lang.] Japanese

5:40 PM - 5:50 PM

[K504-2vn-09] Electrochemical reduction of low concentration CO₂ by using a Re(I) complex in the presence of secondary amine

^○Kenshu Nemoto¹, Masahiko Miyaji¹, Yusuke Tamaki¹, Osamu Ishitani^1,2 (1. Tokyo Institute of Technology, 2. Hiroshima University)

[Lang.] Japanese

5:50 PM - 6:00 PM

[K504-2vn-10] Synthesis and Reactivity of Anionic Cp Rhenium Complexes via Re → C Silyl Migration

^○Yuto Morita¹, Jun Takaya¹ (1. Tokyo Tech)

[Lang.] Japanese

6:00 PM - 6:10 PM

[K504-2vn-11] Photochemical CO₂ Reduction Catalyzed by a Rhenium Complex Substituted by an Anthryl Group

^○Takimoto Sho¹, Shota Sakurai¹, Takashi Nakazono², Yusuke Tamaki³, Osamu Ishitani^3,4, Tohru Wada¹ (1. Department of Chemistry, Graduate School of Science, Rikkyo University, 2. Research Center for Artificial Photosynthesis, Osaka Metropolitan University, 3. Department of Chemistry, School of Science, Tokyo Institute of Technology, 4. Graduate School of Advanced Science and Engineering, Hiroshima University)

[Lang.] Japanese

6:10 PM - 6:20 PM

[K504-2vn-12] Investigation of reaction mechanism of photocatalytic CO₂ reduction

^○Zuyi Xue^1,2, Yasuomi Yamazaki^1,2, Yoshiaki Nishibayashi^1,2 (1. The university of Tokyo, 2. School of Engineering)

[Lang.] English

6:20 PM - 6:30 PM

[K504-2vn-13] Synthesis and Reactivity of Rhenium–Dinitrogen Complex Bearing Carbene-based PCP-type Pincer Ligands toward Nitrogen Fixation

^○Hiroki Takekuma¹, Shogo Kuriyama¹, Yoshiaki Nishibayashi¹ (1. School of Engineering, The University of Tokyo)

[Lang.] Japanese

6:30 PM - 6:40 PM

[K504-2vn-14] Solvent effects on substrate oxidation by an isolated ruthenium(IV)-oxo complex

^○Yuta Yamasaki¹, Hiroaki Kotani¹, Tomoya Ishizuka¹, Takahiko Kojima¹ (1. Univ. of Tsukuba)

[Lang.] Japanese

6:40 PM - 6:50 PM

[K504-2vn-15] Development of Efficient Ruthenium Catalysts toward Electrocatalytic Ammonia Oxidation

^○Ryo Takabatake¹, Kaito Kuroki¹, Shogo Kuriyama¹, Yoshiaki Nishibayashi¹ (1. School of Engineering, The University of Tokyo)

[Lang.] Japanese

Academic Program [Oral A]

[K503-3am] 09. Coordination Chemistry, Organometallic Chemistry

Fri. Mar 24, 2023 9:00 AM - 11:40 AM K503 (K503, Lecture Hall Bldg. [5F])

Chair: Hiroaki Iguchi, Tsubasa Hatanaka

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9:00 AM - 9:10 AM

[K503-3am-01] Synthesis and characterization of heterometallic multinuclear complexes with various kinds of metal ions

^○Masaya SAKAMOTO¹, Misa TOMODA^1,2,3, Yutaka SAGA¹, Mio KONDO^1,4, Shigeyuki MASAOKA¹ (1. Osaka University, 2. IMS, 3. SOKENDAI, 4. JST PRESTO)

[Lang.] Japanese

9:10 AM - 9:20 AM

[K503-3am-02] Synthesis of a N,N-Bis(2-pyridylmethyl)methylamine osmium(III) complex and its reactivity toward halide ions

^○Naoki OMURA¹, Hideki SUGIMOTO¹, Shinobu ITOH¹ (1. Osaka University)

[Lang.] Japanese

9:20 AM - 9:30 AM

[K503-3am-03] Synthesis of Pd(Ⅱ) Complex Cages with Oxa[5]helicene Subunits

^○Amika Ido¹, Akihiro Tsurusaki¹, Ken Kamikawa¹ (1. Osaka Metropolitan University)

[Lang.] Japanese

9:30 AM - 9:40 AM

[K503-3am-04] Synthesis of Pd Nanoclusters Coordinated by Multiple [2.2]Paracyclophane Ligands

^○Shunichi Kataoka¹, Tsubasa Omoda¹, Koji Yamamoto², Shigeyoshi Sakaki³, Tetsuro Murahashi¹ (1. Tokyo Tech, 2. National Defense Academy, 3. Kyoto Univ.)

[Lang.] Japanese

9:40 AM - 9:50 AM

[K503-3am-05] Synthesis of 2,3'-Bipyridyl Bridged Trinuclear Pd Complex

^○Yoji Fukui¹, Kento Iwai¹, Nagatoshi Nishiwaki¹ (1. Kochi University of Technology)

[Lang.] Japanese

9:50 AM - 10:00 AM

[K503-3am-06] Structures and reaction with Ag(I) ion of mixed-ligand triplatinum and mixed-metal diplatinum rhodium complexes bearing triply bridging sulfide and diplatinum unit with methylene-bridged bis-NHC ligands

^○Natsuki yabune¹, Hiroshi Nakajima², Takanori Nishioka² (1. Osaka City Univ., 2. Osaka Metropolitan Univ.)

[Lang.] Japanese

10:00 AM - 10:10 AM

[K503-3am-07] Selective synthesis of the geometrical isomers of unsymmetric Pt(II) complex having two different pyrazoles and N^C chelate ligand and their reactions with Ag(I) ions

^○Yiming Yang¹, Shinnosuke Horiuchi², Eri Sakuda¹, Yasuhiro Arikawa¹, Keisuke Umakoshi¹ (1. Nagasaki Univ, 2. The Univ. of Tokyo)

[Lang.] Japanese

10:10 AM - 10:20 AM

[K503-3am-08] Chemical Behavior of Anticancer Pd and Pt Complexes Containing an Amino Sugar Moiety under Physiological Conditions

^○Kazumichi Nakashima¹, Ayumi Yoshida¹, Laurenzo De Vera ALBA², Tsubasa Hatanaka¹, Akihiro Nomoto³, Misaki Nakai⁴, Shunichiro Ogura⁵, Shigenobu Yano⁶, Yasuhiro Funahashi¹ (1. Osaka Univ., 2. DLSU, 3. Osaka Metropol. Univ., 4. Kansai Univ., 5. Tokyo Tech., 6. Nara Women’s Univ.)

[Lang.] Japanese

10:20 AM - 10:30 AM

[K503-3am-09] Dimerization and properties of platinum complexes containing biphenylate as a co-ligand.

^○Ryunosuke Tomita¹, Shota Kanamori², Atsushi Takamori³, Kazuhiro Uemura¹ (1. Faculty of Engineering, Gifu University, 2. Graduate School of Natural Science and Technology, Gifu University, 3. Graduate School of Engineering, Gifu University)

[Lang.] Japanese

Break （10:30 AM - 10:40 AM）

10:40 AM - 10:50 AM

[K503-3am-10] Structural Conversion by Ligand Exchange in Silver(I)-Thiol Coordination Polymer at the solid-liquid interface

^○Myu Fukuoka¹, Takashima Yohei¹, Akamatsu Kensuke¹, Tsuruoka Takaaki¹ (1. Konan University)

[Lang.] Japanese

10:50 AM - 11:00 AM

[K503-3am-11] Bottom-Up Synthesis of Metallic Nanoclusters Precisely Controlled by Interligand Hydorogen Bonding

^○Ryohei Saito¹, Katsuhiro Isozaki¹, Masaharu Nakamura¹ (1. Kyoto university)

[Lang.] Japanese

11:00 AM - 11:10 AM

[K503-3am-12] Synthesis of Water-Soluble Gold Nanocluster Bearing Hydrogen-Bonding Supramolecular Reaction Field

^○HAOZHI YIN¹, Katsuhiro ISOZAKI¹, Masaharu NAKAMURA¹ (1. Kyoto University)

[Lang.] English

11:10 AM - 11:20 AM

[K503-3am-13] Synthesis of Gold(I)-NHC Complexes Bearing Gold– Metal Hetero-Interactions

^○akito kitabayashi¹, yuriko ono², tetuya taketsugu^1,2, Kosuke Higashida², Masaya Sawamura^1,2 (1. Faculty of Science, Hokkaido University, 2. WPI-ICReDD, Hokkaido University)

[Lang.] Japanese

Academic Program [Oral A]

[K502-3am] 09. Coordination Chemistry, Organometallic Chemistry

Fri. Mar 24, 2023 9:00 AM - 11:20 AM K502 (K502, Lecture Hall Bldg. [5F])

Chair: Kohei Takahashi, Yutaka Saga

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9:00 AM - 9:10 AM

[K502-3am-01] Immobilization of Ru-NHC complexes as oxidation catalysts on solid surface toward improvement of their durability

^○Haruka Seta¹ (1. University of Tsukuba)

[Lang.] Japanese

9:10 AM - 9:20 AM

[K502-3am-02] Photocatalytic substrate oxidation with a heteroaromatic ligand bound to ruthenium complex using dioxygen as a terminal oxidant

^○Taichiro Nishi¹, Tomoya Ishizuka¹, Nanase Namura¹, Takahiko Kojima¹ (1. University of Tsukuba)

[Lang.] Japanese

9:20 AM - 9:30 AM

[K502-3am-03] Synthesis and Photocatalytic Property of Organic–Inorganic Hybrid Ruthenium(II) Complexes with a Linked Rotaxane Structure

^○Qichun JIANG¹, Yuka IMANISHI², Hiromichi MIYAGISHI², Nobutaka YOSHIMURA⁴, Atsushi KOBAYASHI³, Hiroshi MASAI², Shin-ya TAKIZAWA², Tomohiro IWAI², Jun TERAO² (1. Graduate School of Science, The University of Tokyo, 2. Graduate School of Arts and Sciences, The University of Tokyo, 3. Faculty of Science, Hokkaido University, 4. Graduate School of Chemical Sciences and Engineering, Hokkaido University)

[Lang.] English

9:30 AM - 9:40 AM

[K502-3am-04] Reactivity of Diruthenium Bis(μ-ethylidyne) Complex Possessing a Dual Aromatic Ru₂C₂ Core

^○Naoya Noguchi¹, Toshiro Takao¹ (1. Tokyo Institute of Technology)

[Lang.] Japanese

9:40 AM - 9:50 AM

[K502-3am-05] Preparation and Property of a 50-electron Triangular Ruthenium Cluster Containing a µ₃–Methylidyne Ligand

^○Shu Egawa¹, Toshiro Takao¹ (1. Tokyo Institute of Technology)

[Lang.] Japanese

9:50 AM - 10:00 AM

[K502-3am-06] Syntheses and Properties of Triruthenium Polyhydrido Complexes Composed of 1, 2, 3, 4, 5-pentamethylcyclopentadienyl and p-Cymene Ruthenium Units

^○Yuji Shibata¹, Toshiro Takao¹, Takuya Kosukegawa¹ (1. Tokyo Institute of Technology)

[Lang.] Japanese

10:00 AM - 10:10 AM

[K502-3am-07] Substituent Effect on Light-Driven Organic Hydride Storage Reaction of NAD⁺-Type Ru(II) Complexes

^○Kazuki SHIBAHARA¹, Kiyoshi TSUGE¹, Hideki OHTSU¹ (1. Grad. Sch. of Sci. and Eng., Univ. of Toyama)

[Lang.] Japanese

Break （10:10 AM - 10:20 AM）

10:20 AM - 10:30 AM

[K502-3am-08] Visible light driven carbon dioxide reduction in water catalyzed by biologically relevant metal complexes

^○Minoru Hayakawa¹, Kaito Sasaki², Yu Hoshino², Hisashi Shimakoshi² (1. Faculty of Engineering, Kyushu University, 2. Graduate School of Engineering, Kyushu University)

[Lang.] Japanese

10:30 AM - 10:40 AM

[K502-3am-09] Photocatalytic Water Oxidation by Carbon Nitride Modified with a Cobalt Polymolybdate Catalyst

^○Yuki Tomita¹, Natsuki Taira¹, Hironobu Ozawa¹, Ken Sakai¹ (1. Dept. Chem. Kyushu Univ.)

[Lang.] Japanese

10:40 AM - 10:50 AM

[K502-3am-10] Co Porphyrin Catalyst Modified TiO₂ Cathode Toward Low Overpotential CO₂ Reduction

^○Yuki Goya¹, Ken Sakai¹, Hironobu Ozawa¹ (1. Dept. Chem. Kyushu Univ.)

[Lang.] Japanese

10:50 AM - 11:00 AM

[K502-3am-11] Syntheses and Reactivities of Rhodium-Palladium Bimetallic Complexes Utilizing 6,6”-Bisphosphinoterpyridine as a Scaffold for the Metal-Metal Bond

^○Kengo Tanaka¹, Nobuharu Iwasawa¹, Jun Takaya¹ (1. Tokyo Institute of Technology)

[Lang.] Japanese

11:00 AM - 11:10 AM

[K502-3am-12] Reactivity of Heptadentated Schiff-base Ligated Cerium(IV) Enolate Complexes with N-Oxyl and Phenoxy Radicals

^○Daisuke Senga¹, Kazushi Mashima², Hayato Tsurugi¹ (1. Graduate School of Engineering Science, Osaka University, 2. Graduate School of Pharmaceutical Sciences, Osaka University)

[Lang.] Japanese

11:10 AM - 11:20 AM

[K502-3am-13] Hydroaminoalkylation of Allyl Ethers with N-Methylaniline Catalyzed by Half-titanocene Complexes Activated with Organometallic Reagents

^○Tokiya Teraishi¹, Yu Kuroda¹, Mariko Inoue¹, Hayato Tsurugi¹, Kazushi Mashima² (1. Graduate School of Engineering Science, Osaka University, 2. Graduate School of Pharmaceutical Sciences, Osaka University)

[Lang.] Japanese

Academic Program [Oral A]

[K504-3am] 09. Coordination Chemistry, Organometallic Chemistry

Fri. Mar 24, 2023 9:00 AM - 11:30 AM K504 (K504, Lecture Hall Bldg. [5F])

Chair: Fumiya Kobayashi, Hidetaka Nakai

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9:00 AM - 9:10 AM

[K504-3am-01] Analysis of interaction between prolinol-based iron dithiocarbamate complexes and Lewis bases

^○Natsuki Maki¹, Bungo Ochiai¹ (1. Yamagata university)

[Lang.] Japanese

9:10 AM - 9:20 AM

[K504-3am-02] Synthesis of photo-responsive Werner-type metal complexes with halogen substituents

^○Yun Chen¹, Xin Zheng², Kiyonori Takahashi³, Takayoshi Nakamura³, Shin-ichiro Noro^1,2 (1. Graduate school of Env.Science, Hokkaido University, 2. Faculty of Env.Earth Science, Hokkaido University, 3. RIES, Hokkaido University)

[Lang.] Japanese

9:20 AM - 9:30 AM

[K504-3am-03] Structures and luminescence properties for visible-excitable visible/NIR lumiescencent lanthanide complexes

^○Hitomi Ohmagari¹, Nicolas Marets¹, Jun Kamata¹, Miki Hasegawa¹ (1. Aoyama Gakuin University)

[Lang.] Japanese

9:30 AM - 9:40 AM

[K504-3am-04] Phosphorescence Associated with Halogen Interactions in Luminescent Zn(II) Clusters

^○Yuta Takatsu¹, Fumiya Kobayashi¹, Makoto Tadokoro¹ (1. Tokyo Univ. of Sci.)

[Lang.] Japanese

9:40 AM - 9:50 AM

[K504-3am-05] Mechanistic Studies on CO2 Reduction to Formate by Ni-NHC Catalysts

^○Chen Liao¹, Kosei Yamauchi¹, Ken Sakai¹ (1. Dept. Chem., Kyushu Univ.)

[Lang.] English

9:50 AM - 10:00 AM

[K504-3am-06] Synthesis and Structure of Bis(pinacolatoboryl)methylgold(I) Complexes

^○Matsuzaki Kouma¹, Mashima kazushi², tsurugi hayato¹ (1. Graduate School of Engineering Science, Osaka University, 2. Graduate School of Pharmaceutical Science, Osaka University)

[Lang.] Japanese

10:00 AM - 10:10 AM

[K504-3am-07] Theoretical study of effect on frontier orbital by hydrogen bonds around P-cluster of Nitrogenase

^○Kazuki Honjo¹, Naoka Amamizu², Yuta Hayashi², Keisuke Sasaki², Masahiro Tsuda², Mitsuhiro Nishida¹, Koki Masuda¹, Ryohei Kishi^2,3,4,5, Yasutaka Kitagawa^2,3,4,5,6 (1. Faculty of Engineering Science, Osaka University, 2. Graduate School of Engineering Science, Osaka University, 3. QIQB, Osaka University, 4. RCSEC, Osaka University, 5. ICS-OTRI, Osaka University, 6. SRN-OTRI, Osaka University)

[Lang.] Japanese

Break （10:10 AM - 10:20 AM）

10:20 AM - 10:30 AM

[K504-3am-08] Investigation of proton conductivity switching using metal complex with multi light-responsive units

^○Kentaro Aoki¹, Yuki Nagao¹ (1. JAIST)

[Lang.] English

10:30 AM - 10:40 AM

[K504-3am-09] Red emissive Cu(I)-pyridinophane-arylamide complexes and their application as mechanophores for mechanoresponsive polymers

^○Tatiana Gridneva¹, Ayumu Karimata¹, Richa Bansal¹, Julia R Khusnutdinova¹ (1. Okinawa Institute of Science and Technology)

[Lang.] English

10:40 AM - 10:50 AM

[K504-3am-10] Immobilization of Terbium Complex on Solid Surface with Chiral Moiety

^○Sora Shirai¹, Satoshi Muratsugu¹, Hidetaka Nakai², Mizuki Tada^1,3 (1. Dept. Chem. Nagoya Univ., 2. Grad. Sch. Sci. Eng. Kindai Univ., 3. RCMS, Nagoya Univ.)

[Lang.] English

10:50 AM - 11:00 AM

[K504-3am-11] Encapsulation-induced Charge-transfer Interactions by a Ferrocene-based Capsule

^○Kazuki Toyama¹, Yuya Tanaka¹, Michito Yoshizawa¹ (1. Lab. for Chem. & Life Sci., Tokyo Tech)

[Lang.] Japanese

11:00 AM - 11:10 AM

[K504-3am-12] Development of crystalline molecular rotors using NHC multi-metallic complexes possessing Au(Ⅰ) and Cu(Ⅰ) with solid-state emissive properties

^○Yusuke Fujisawa¹, Rempei Ando¹, Mingoo Jin², Hajime Ito^1,2 (1. Graduate School of Engineering, Hokkaido University , 2. WPI-ICReDD, Hokkaido University)

[Lang.] Japanese

11:10 AM - 11:20 AM

[K504-3am-13] Synthesis, Structure, and Optical Property of Tris(biaryldiyl)rhodate(III) and -iridate(III) Complexes

^○Masaki Hara¹, Yuko Hirooka, Takanori Iwasaki¹, Kyoko Nozaki¹ (1. The University of Tokyo)

[Lang.] Japanese

11:20 AM - 11:30 AM

[K504-3am-14] Synthesis of Sulfonate-Protected High-Nuclearity Silver Cluster and Effect of Extra Silver Atom on Photoluminescence

^○Aoi Akiyama¹, Mana Nakamoto², Mai Ishimi², Sakiat Hossain², Yoshiki Niihori², Tokuhisa Kawawaki^1,2, Daiji Ogata², Pei Zhao³, Junpei Yuasa^1,2, Masahiro Ehara³, Yuichi Negishi^1,2 (1. Undergraduate School of Science, Tokyo University of Science, 2. Graduate School of Science, Tokyo University of Science, 3. Institute for Molecular Science)

[Lang.] Japanese

Academic Program [Oral A]

[K502-3pm] 09. Coordination Chemistry, Organometallic Chemistry

Fri. Mar 24, 2023 1:00 PM - 3:40 PM K502 (K502, Lecture Hall Bldg. [5F])

Chair: Hayato Tsurugi, Yasuyuki Ura

+Add all to schedule

1:00 PM - 1:10 PM

[K502-3pm-01] Catalytic Asymmetric Hydrogenation of Imines by Tethered Iridium Complexes with N-Sulfonyldiamine Ligands

^○Suzuki Teruya¹, Yoshida Minori¹, Kuwata Shigeki², Kayaki Yoshihito¹ (1. Tokyo Institute of Technology, 2. Ritsumeikan University)

[Lang.] Japanese

1:10 PM - 1:20 PM

[K502-3pm-02] Development of Lewis Acidic Weakly Coordinating Anions and their Application to Catalytic Regioselective C-H Functionalization

^○Ryo Mandai¹, Takanori Iwasaki¹, Kyoko Nozaki¹ (1. The Univ. of Tokyo)

[Lang.] Japanese

1:20 PM - 1:30 PM

[K502-3pm-03] Hydrogenation of carboxylic acids using the iridium complex bearing the PNCP-type tetradentate ligand

^○Koichiro Nishimoto¹, Yohei Kametani³, Yoshihito Shiota³, Kazunari Yoshizawa³, Naoki Noto², Susumu Saito^1,2 (1. Grad. Sch. Sci., Nagoya Univ., 2. IRCCS, Nagoya Univ., 3. IMCE, Kyushu Univ.)

[Lang.] Japanese

1:30 PM - 1:40 PM

[K502-3pm-04] Electrochemical reduction of CO₂ to formic acid at a low overpotential using a heterogenized molecular iridium complex

^○Keun Woo Lee¹, Selvam Kaliyamoorthy¹, Jieun Jung¹, Susumu Saito^1,2 (1. Grad. Sch. Sci., Nagoya Univ., 2. IRCCS, Nagoya Univ.)

[Lang.] English

1:40 PM - 1:50 PM

[K502-3pm-05] Electrochemical Hydrogen Generation by a Four-Coordinate Square-Planar Ni(II) Complex with N2P2-Type Ligand

^○Hidenori Miyake¹, Kenichi Nakao¹, Takuma Kato¹, Ryo Tatematsu¹, Yuko Wasada¹, Tomohiko Inomata¹, Tomohiro Ozawa¹, Hideki Masuda² (1. Graduate School of Engineering, Nagoya Institute of Technology, 2. Aichi Institute of Technology)

[Lang.] Japanese

1:50 PM - 2:00 PM

[K502-3pm-06] Photoinduced Radical Coupling by Visible Light Activation of NHC-Palladium Catalysts

^○Masashi Yamashita¹, Fumitoshi Shibahara¹ (1. Faculty of Engineering, Gifu University)

[Lang.] Japanese

2:00 PM - 2:10 PM

[K502-3pm-07] Expression of the Reaction Selectivity by Reducing the Catalyst Loading

Misa Kawase¹, ^○Tomohiro Shibata¹, Shohei Masuu¹, Masaki Yamaguchi¹, Osamu Shimomura¹, Atsushi Ohtaka¹ (1. Osaka Institute of Technology)

[Lang.] Japanese

Break （2:10 PM - 2:20 PM）

2:20 PM - 2:30 PM

[K502-3pm-08] Palladium/Iron-Catalyzed Wacker-type Oxidation of Terminal and Internal Alkenes

^○Mayu Miyazaki¹, Yasuyuki Ura¹ (1. Nara Women's University)

[Lang.] Japanese

2:30 PM - 2:40 PM

[K502-3pm-09] Catalytic Asymmetric Friedel-Crafts reaction of Indoles and N-Boc imine using chiral NCN pincer complex

^○Tomoya Yokota¹, Takayoshi Arai¹ (1. Chiba University)

[Lang.] Japanese

2:40 PM - 2:50 PM

[K502-3pm-10] Palladium-Catalyzed One-Pot Cross-Coupling/C–H Bromination Based on OFF/ON Switching of Electric Current

^○Yamato Hirota¹, Mao Kikuchi¹, Takuya Kochi¹, Fumitoshi Kakiuchi¹ (1. Keio University)

[Lang.] Japanese

2:50 PM - 3:00 PM

[K502-3pm-11] Synthesis and H₂-Evolving Property of Metal Complexes having N-2-Pyridylimidoyl-2-pyridylamidine

^○Toma Kunikubo¹, Jaclyn Brusso², Kosei Yamauchi¹, Ken Sakai¹ (1. Dept. Chem. Kyushu Univ., 2. University of Ottawa)

[Lang.] Japanese

3:00 PM - 3:10 PM

[K502-3pm-12] Ag-Catalyzed Synthesis of Indole-Fused 8-Membered Ring Compounds by Ring Expansion

^○Yukino Sato¹, Mamoru Ito¹, Takanori Shibata¹ (1. Waseda University)

[Lang.] Japanese

3:10 PM - 3:20 PM

[K502-3pm-13] Cyclization of Alkynoic Acids Catalyzed by Au₂₅ Nanoclusters Bearing Peptide Dendron Supramolecular Reaction Field

^○Kyosuke UEDA¹, Kenta ISERI¹, Katsuhiro ISOZAKI¹, Masaharu NAKAMURA¹ (1. Kyoto University)

[Lang.] Japanese

3:20 PM - 3:30 PM

[K502-3pm-14] Methane oxidation catalyzed by dicopper(II) complex with hexadentate dinucleating ligand

^○Seina Shinomiya¹, Kyousuke Fujikawa¹, Yutaka Hitomi¹, Masato Kodera¹ (1. Doshisha University)

[Lang.] Japanese

3:30 PM - 3:40 PM

[K502-3pm-15] Multicopper Complexes Having a Hydrophobic Pocket to Enhance Methane Oxidation

^○Keiichiro Harada¹, Natumi Itikawa¹, kyousuke Fujikawa¹, Yutaka Hitomi¹, Masahito Kodera¹ (1. Doshisha Univ.)

[Lang.] Japanese

Academic Program [Oral A]

[K503-3pm] 09. Coordination Chemistry, Organometallic Chemistry

Fri. Mar 24, 2023 2:30 PM - 3:40 PM K503 (K503, Lecture Hall Bldg. [5F])

Chair: Kosei Yamauchi, Shinjiro Takano

+Add all to schedule

2:30 PM - 2:40 PM

[K503-3pm-01] Synthesis and Reactions of Chalcogen-Bridged Dicopper Complexes with a Macrocyclic Ligand

^○Kenta Ochiai¹, Nozomu Okura¹, Tsubasa Hatanaka¹, Yasuhiro Funahashi¹ (1. Osaka Univ.)

[Lang.] Japanese

2:40 PM - 2:50 PM

[K503-3pm-02] Synthesis of porous nanofiber gels self-assembled from metal-organic polyhedra

^○Ayana Miyata¹, Shun Tokuda¹, Shuhei Furukawa¹ (1. Kyoto University)

[Lang.] Japanese

2:50 PM - 3:00 PM

[K503-3pm-03] Synthesis and Characterization of Heteroleptic Dinuclear Copper(I) Complexes Containing Benzothienobenzothiophene Moieties

^○Takashi Ikeda¹, Keishiro Tahara¹, Tomofumi Kadoya², Yoshiki Ozawa¹, Masaaki Abe¹ (1. University of Hyogo, 2. Konan University)

[Lang.] Japanese

3:00 PM - 3:10 PM

[K503-3pm-04] Synthesis and photochromism of a tetrathiazole ligand with oligopyridine moieties

^○Kaito Takahata¹, Mayuko Nozawa¹, Mihoko Yamada¹, Tsuyoshi Kawai¹ (1. Nara Institute of Science and Technology)

[Lang.] Japanese

3:10 PM - 3:20 PM

[K503-3pm-05] Synthesis and photochromism of a tetrathiazole copper(II) complex with oligopyridine moieties

^○Mihoko Yamada¹, Mayuko Nozawa¹, Kaito Takahata¹, Tsuyoshi Kawai¹ (1. NAIST)

[Lang.] Japanese

3:20 PM - 3:30 PM

[K503-3pm-06] Large acceleration of DNA double strand break by tetracopper complexes

^○Kazuki Matsuse¹, Masahito Kodera¹, Yutaka Hitomi¹ (1. Doshisha univ.)

[Lang.] Japanese

3:30 PM - 3:40 PM

[K503-3pm-07] Controlling the Photofunctionality of a Water-soluble Copper(I) Photosensitizer by the Ion-pair Formation

^○Fumika Sueyoshi¹, Xian Zhang¹, Kosei Yamauchi¹, Ken Sakai¹ (1. Dept. Chem. Kyushu Univ.)

[Lang.] Japanese

Academic Program [Oral A]

[K504-3vn] 09. Coordination Chemistry, Organometallic Chemistry

Fri. Mar 24, 2023 4:10 PM - 6:50 PM K504 (K504, Lecture Hall Bldg. [5F])

Chair: Shun Ohta, Takashi Nakazono

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4:10 PM - 4:20 PM

[K504-3vn-01] Cytotoxicity of Dicopper(Ⅱ) Complexes with Amidate Ligands

^○Ayano Nakashima¹, Jin Ueno¹, Machi Hata¹, Yutaka Hitomi¹, Masahito Kodera¹ (1. Doshisha University)

[Lang.] Japanese

4:20 PM - 4:30 PM

[K504-3vn-02] Synthesis and Photoproperties of Insulated π-Conjugated Bipyridine–Metal Complexes with a Linked Rotaxane Structure

^○Shinsuke Abe¹, Hiromichi V. Miyagishi¹, Hiroshi Masai¹, Shin-ya Takizawa¹, Tomohiro Iwai¹, Jun Terao¹ (1. Grad. Sch. Arts and Sci., The Univ. of Tokyo)

[Lang.] Japanese

4:30 PM - 4:40 PM

[K504-3vn-03] Photophysical and photosensitizing properties of ion pairs comprising cationic and anionic iridiun(Ⅲ) complexes

^○Suguru Yamazaki¹, Shin-ya Takizawa¹, Hiroshi Masai¹, Tomohiro Iwai¹, Jun Terao¹ (1. The Univ. of Tokyo)

[Lang.] Japanese

4:40 PM - 4:50 PM

[K504-3vn-04] Development of Capillary Crystalline Sponge Method (cap-CS method) and Device-Oriented Molecular Structural Analysis

^○Ryo Yakushiji¹, Satoshi Yoshida², Sota Sato², Makoto Fujita^2,3 (1. The Univ. of Tokyo, 2. School of Engineering, TheUniv. of Tokyo, 3. IMS)

[Lang.] Japanese

4:50 PM - 5:00 PM

[K504-3vn-05] Adsorption Behavior of Pyridine by a Bis(benzimidazole)-Coordinated Nickel Dichlorido Complex

^○Tatsunari Murakami¹, Takahiro Homma¹, Atsunobu Masuno¹, Masaaki Okazaki¹, Shun Ohta¹ (1. Grad. Sch. of Sci. and Tech., Hirosaki Univ.)

[Lang.] Japanese

5:00 PM - 5:10 PM

[K504-3vn-06] Cyanosilylation of Aryl aldehydes by a Silicon Porphyrin Complex

^○Keitaro Watanabe¹, Shintaro Ishida¹, Takeaki Iwamoto¹ (1. Graduate School of Science, Tohoku University)

[Lang.] Japanese

5:10 PM - 5:20 PM

[K504-3vn-07] Activation of silicon-oxygen double bond by triarylboranes

^○Kengo Sakamoto¹, Ryo Kobayashi¹, Shintaro Ishida¹, Takeaki Iwamoto¹ (1. Tohoku University)

[Lang.] Japanese

5:20 PM - 5:30 PM

[K504-3vn-08] Synthesis, Functionalization, and Oligomerization of an Unsymmetrically-substituted Bicyclo[1.1.1]pentasilane

^○Yukihiro Morino¹, Shintaro Ishida¹, Takeaki Iwamoto¹ (1. Graduate School of Science, Tohoku University)

[Lang.] Japanese

Break （5:30 PM - 5:40 PM）

5:40 PM - 5:50 PM

[K504-3vn-09] Synthetic Study of a Stable Compound with an Inverted Ge=Ge Bond

^○Takuro Shiojima¹, Takeaki Iwamoto¹ (1. Graduate School of Science, Tohoku University)

[Lang.] Japanese

5:50 PM - 6:00 PM

[K504-3vn-10] Crystal structures and electrochemical behavior of coordination isomers of [Rh^III(SCN)_6-x(NCS)_x]^3–(x = 0 or 1)

^○Seiya Hagiwara¹, Miki Mukai¹, Rika Tanaka¹, Takashi Nakazono², Yusuke Yamada^1,2 (1. Graduate School of Engineering, Osaka Metropolitan University , 2. Research Center for Artificial Photosynthesis, Osaka Metropolitan University)

[Lang.] Japanese

6:00 PM - 6:10 PM

[K504-3vn-11] Proton Conduction in a Hydrogen-Bonded Cobalt(II) Spin Crossover Complex

^○Sho Aoshima¹, Fumiya Kobayashi¹, Makoto Tadokoro¹ (1. Tokyo Univ. of Sci.)

[Lang.] Japanese

6:10 PM - 6:20 PM

[K504-3vn-12] Synthesis and evaluation of redox properties of 2-hydroxypyridine-bridged paddlewheel-type Ru₂ complexes

^○Taku Kitayama^1,2, Haruka Yoshino², Wataru Kosaka², Hitoshi Miyasaka² (1. Tohoku University, 2. IMR)

[Lang.] Japanese

6:20 PM - 6:30 PM

[K504-3vn-13] Interlayer Distance Reduction Effect on Ferromagnetic Phase Transition of Dithiooxalato-Bridged Iron Mixed-Valence Complexes

^○Tsubasa Endo¹, Takuya Kanetomo¹, Masaya Enomoto¹ (1. Tokyo univ. of sci.)

[Lang.] Japanese

6:30 PM - 6:40 PM

[K504-3vn-14] Photoluminescence and arrangement of macrocyclic-platinum complexes in solid phase

^○Yukatsu Shichibu¹, Kasei Ryu¹, Shogo Shimada¹, Katsuaki Konishi¹ (1. Hokkaido University)

[Lang.] Japanese

6:40 PM - 6:50 PM

[K504-3vn-15] Reactions of Hexa-tert-butylbicyclo[1.1.0]tetragermane

^○Ryoga IGUCHI¹, Shintaro ISHIDA², Soichiro KYUSHIN¹ (1. Graduate School of Science and Technology, Gunma Univ., 2. Graduate School of Science, Tohoku Univ.)

[Lang.] Japanese

Academic Program [Oral A]

[K502-3vn] 09. Coordination Chemistry, Organometallic Chemistry

Fri. Mar 24, 2023 4:10 PM - 5:30 PM K502 (K502, Lecture Hall Bldg. [5F])

Chair: Takuya Kochi, Yohei Shimizu

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4:10 PM - 4:20 PM

[K502-3vn-01] Reactivity of Di(µ-oxido)dinickel(III) Complexes Supported by Dinucleating Ligands Containing Different Alkylene Bridging Groups

^○Ryotaro Noguchi¹, Ryoichiro Ogumo¹, Yuma Morimoto², Shinobu Itoh¹ (1. Osaka University, 2. Nagoya University)

[Lang.] Japanese

4:20 PM - 4:30 PM

[K502-3vn-02] Photocatalytic oxidation of gaseous alkanes using dioxygen as an oxidant under mild conditions

^○Hayao Shimomura¹, Bongki Shin², Takahiko Kojima^1,2 (1. Univ. of Tsukuba , 2. CREST)

[Lang.] Japanese

4:30 PM - 4:40 PM

[K502-3vn-03] Synthesis, structure, and catalytic activity in the alkane oxidation of new amidate dicopper complexes

^○Kazuki Shimomura¹, Natsumi Itikawa², Kyosuke Fujikawa², Yutaka Hitomi^1,2, Masahito Kodera^1,2 (1. Department of Molecular Chemistry Doshisha University, 2. Graduate School of Science abd Engineering Doshisha University)

[Lang.] Japanese

4:40 PM - 4:50 PM

[K502-3vn-04] Multinuclear Cu-catalyzed enantioselective conjugated addition for the construction of CF₃-substituted quaternary carbon center

^○Taiyo Yamamoto¹, Kohei Endo² (1. Department of Chemistry, Faculty of Science of Division I, Tokyo University of Science, 2. Department of Chemistry, Faculty of Science, Tokyo University of Science)

[Lang.] Japanese

4:50 PM - 5:00 PM

[K502-3vn-05] Development of electrode-supported catalysts with CO₂ reduction ability using electrochemical polymerization

^○Senri Katsuhira¹, Takumi Matsuzaki¹, Yutaka Saga¹, Mio Kondo^1,2, Shigeyuki Masaoka¹ (1. Osaka University, 2. JST PRESTO)

[Lang.] Japanese

5:00 PM - 5:10 PM

[K502-3vn-06] Autoxidation Mechanism of Alkanes Catalyzed by Copper Complexes in the Presence of Aldehyde

^○RIN Itoh¹, Kohei Yamaguchi¹, Hideki Sugimoto¹, Shinobu Itoh¹ (1. Osaka University)

[Lang.] Japanese

5:10 PM - 5:20 PM

[K502-3vn-07] Multinuclear Cu-catalyzed enantioselective conjugate addition for the synthesis of chiral allylsilane derivatives

^○Taketo Toda¹, Kohei Endo² (1. Tokyo University of Science, 2. Department of Chemistry, Faculty of Science, Tokyo University of Science)

[Lang.] Japanese

5:20 PM - 5:30 PM

[K502-3vn-08] Theoretical study of reduction of NO to N₂O catalyzed by a copper complex

^○Ryoga Toyoshima¹, Yohei Kametani¹, Yoshihito Shiota¹, Kazunari Yoshizawa¹ (1. IMCE, Kyushu Univ.)

[Lang.] Japanese

Academic Program [Oral A]

[K504-4am] 09. Coordination Chemistry, Organometallic Chemistry

Sat. Mar 25, 2023 9:00 AM - 11:40 AM K504 (K504, Lecture Hall Bldg. [5F])

Chair: Shinpei Kusaka, Yohei Takashima

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9:00 AM - 9:10 AM

[K504-4am-01] In-situ time-resolved X-ray spectroimaging of gas adsorption process in MOF-74 single particles

^○Wakana Igarashi¹, Emina Yamada¹, Hirotoshi Sakamoto², Hirosuke Matsui¹, Tomoya Uruga⁴, Mizuki Tada³ (1. Nagoya University Graduate school of science, 2. Kyoto University iCeMS , 3. Nagoya University RCMS, 4. JASRI/SPring-8)

[Lang.] Japanese

9:10 AM - 9:20 AM

[K504-4am-02] Structural Control and Magnetic Properties of Hydrogen-Bonded Honeycomb Networks Composed of Trinuclear Ruthenium Cluster

^○Shoki Ikeda¹, Kazuki Takamura¹, Yoshiki Ozawa¹, Keishiro Tahara¹, Akira Yamaguchi¹, Yu Yamane¹, Akihiko Sumiyama¹, Masaaki Abe¹ (1. Univ. of Hyogo)

[Lang.] Japanese

9:20 AM - 9:30 AM

[K504-4am-03] Construction and Characterization of Hydrogen-Bonded Honeycomb Networks Using Trinuclear Chromium(III) Complexes

^○Shun Sumikawa¹, Shoki ikeda¹, Kazuki Takamura¹, Yoshiki Ozawa¹, Keishiro Tahara¹, Akira Yamaguchi¹, Yu Yamane¹, Akihiko Sumiyama¹, Masaaki Abe¹ (1. University of Hyogo)

[Lang.] Japanese

9:30 AM - 9:40 AM

[K504-4am-04] Nuclearity-conversion equilibrium between tetranuclear and hexanuclear core structures in iminothiolato-copper(I) complexes

^○Kohei Nomoto¹, Masahiro Kubo¹, Kaori Mori¹, Yoshiki Ozawa¹, Keishiro Tahara¹, Masaaki Abe¹ (1. Univ. of Hyogo)

[Lang.] Japanese

9:40 AM - 9:50 AM

[K504-4am-05] Spectral analysis on solid-state ²H NMR for hierarchical water clusters confined to paramagnetic nanoporous crystals

^○Tomoya Namiki¹, Akira Saito¹, Shunichi Obana¹, Fumiya Kobayashi¹, Takuya Kurihara², Motohiro Mizuno², Makoto Tadokoro¹ (1. Tokyo Univ. of Sci., 2. Kanazawa Univ.)

[Lang.] Japanese

9:50 AM - 10:00 AM

[K504-4am-06] Defect Formation in Three-Dimensional Hofmann-Type Coordination Polymers

^○Daiki Umeyama¹, Atsuro Takai¹, Kazutaka Sonobe¹ (1. National Institute for Materials Science)

[Lang.] Japanese

10:00 AM - 10:10 AM

[K504-4am-07] Thermal Conductivity of Flexible Pillared-Layer Type Nanoporous Metal Complexes

^○Shunya Asai¹, Shinpei Kusaka¹, Hiroaki Iguchi¹, Ryotaro Matsuda¹ (1. Nagoya Univ.)

[Lang.] Japanese

10:10 AM - 10:20 AM

[K504-4am-08] Creation of assemblies of flexible MOF nanoparticles and evaluation of adsorption properties

^○Kohei Negita¹, Shinpei Kusaka¹, Hiroaki Iguchi¹, Ryotaro Matsuda¹ (1. Nagoya Univ.)

[Lang.] Japanese

Break （10:20 AM - 10:30 AM）

10:30 AM - 10:40 AM

[K504-4am-09] Structures and Properties of Cage-shaped Nanoporous Metal Complexes Using Ligands with Electron-rich π-Plane

^○Takumi Kurono¹, Shinpei Kusaka¹, Hiroaki Iguchi ¹, Ryotaro Matsuda¹ (1. Nagoya Univ.)

[Lang.] Japanese

10:40 AM - 10:50 AM

[K504-4am-10] H/D Isotope Effect for Reverse Spin Transition Behavior of Hydrogen-Bonded Cobalt(II)-Organic Framework

^○Keisuke Yamato¹, Zhen Ni¹, Takuya Kanetomo¹, Masaya Enomoto¹ (1. Graduate School of Science, Tokyo University of Science)

[Lang.] Japanese

10:50 AM - 11:00 AM

[K504-4am-11] Superprotonic Conduction in a POM-Based Porous Framework

^○Shunji Oya¹, Fumiya Kobayashi¹, Makoto Tadokoro¹ (1. Tokyo Univ. of Sci.)

[Lang.] Japanese

11:00 AM - 11:10 AM

[K504-4am-12] Precise Control of Reversible Structural Transformation Reactions using Al-MOF based on Defect Engineering

^○Shintaro Tanaka¹, Yohei Takashima², Takaaki Tsuruoka², Kensuke Akamatsu² (1. Konan graduate school , 2. Konan University)

[Lang.] Japanese

11:10 AM - 11:20 AM

[K504-4am-13] Construction of a honeycomb two-dimensional metal-organic framework composed of C₁-symmetric macrocyclic ligands and interlayer molecular arrangement

^○Keiichi Nakagawa¹, Shohei TASHIRO¹, Mitsuhiko SHIONOYA¹ (1. Grad. Sch. of Sci.; The Univ. of Tokyo)

[Lang.] English

11:20 AM - 11:30 AM

[K504-4am-14] Stimuli-responsive reversible dissociation and regeneration of a multinuclear copper(I) capsule complex encapsulating an anion

^○Yoshihiko YAMADA¹, Shohei TASHIRO¹, Mitsuhiko SHIONOYA¹ (1. Grad. Sch. of Sci.; The Univ. of Tokyo)

[Lang.] Japanese

11:30 AM - 11:40 AM

[K504-4am-15] Structurally rigid trisphosphine Cu(I) complexes with sharp red emission enabled by introduction of strains

^○Shota Fukuma¹, Rui Shang¹, Eiichi Nakamura¹ (1. The University of Tokyo)

[Lang.] English

Academic Program [Oral A]

[K503-4am] 09. Coordination Chemistry, Organometallic Chemistry

Sat. Mar 25, 2023 9:00 AM - 10:20 AM K503 (K503, Lecture Hall Bldg. [5F])

Chair: Mihoko Yamada, Ryoji Mitsuhashi

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9:00 AM - 9:10 AM

[K503-4am-01] Unique supramolecular formation of substituted silantriols

^○Ryoji Tanaka¹ (1. Sagami Chemical Research Institute)

[Lang.] Japanese

9:10 AM - 9:20 AM

[K503-4am-02] Control of emission properties of cis-bis(iminomethylindole)platinum(II) complexes by their torsion structure

^○Sakura Goto¹, Soichiro Kawamorita¹, Takeshi Naota¹ (1. The Univ. of Osaka)

[Lang.] Japanese

9:20 AM - 9:30 AM

[K503-4am-03] Synthesis and photophysical properties of aggregate-formed Eu(III) complex with amide group in solvents

^○Yusaku Yamaguchi¹, Sunao Shoji^2,3, Wang Menfei³, Yuichi Kitagawa², Koji Fushimi², Yasuchika Hasegawa^2,3 (1. School of Engineering, Hokkaido University , 2. Faculty of Engineering, Hokkaido University, 3. Institute for Chemical Reaction Design and Discovery, Hokkaido University)

[Lang.] English

9:30 AM - 9:40 AM

[K503-4am-04] Syntheses and Photophysical Properties of Yb(III) Coordination Compounds by Porphyrin Ligand with Two Phosphine Oxides

^○Kota Inage¹, Sunao Shoji^2,3, Koji Fushimi², Yuichi Kitagawa², Yasuchika Hasegawa^2,3 (1. School of Engineering, Hokkaido University, 2. Faculty of Engineering, Hokkaido University, 3. WPI-ICReDD, Hokkaido University)

[Lang.] English

9:40 AM - 9:50 AM

[K503-4am-05] Circularly polarized luminescence of chiral Eu(III) complexes with phenanthrene unit

^○Kosuke Itaya¹, Makoto Tsurui², Sunao Shoji^3,4, Koji Fushimi³, Yasuchika Hasegawa^3,4, Yuichi Kitagawa³ (1. School of Engineering, Hokkaido University , 2. Graduate School of Chemical Sciences and Engineering, Hokkaido University , 3. Faculty of Engineering, Hokkaido University , 4. WPI-ICReDD, Hokkaido University)

[Lang.] English

9:50 AM - 10:00 AM

[K503-4am-06] Fluctuating coordination geometry of copper(II) ion in trigonal hydrogen-bonded networks of Zr–Mo cluster

^○Ryoji Mitsuhashi¹, Yuya Imai¹, Saori Suda¹, Yuji Kikukawa¹, Yoshihito Hayashi¹ (1. Kanazawa University)

[Lang.] English

10:00 AM - 10:10 AM

[K503-4am-07] Operando XAFS Measurement for Electrochromic Ru-based Metallo-Supramolecular Polymer Devise

^○Takefumi Yoshida^1,2,3, Masayoshi Higuchi³, Yasuhiro Iwasawa^1,2 (1. The University of Electro-Communications, 2. Institute of Physical and Chemical Research, 3. National Institute for Materials Science)

[Lang.] English

10:10 AM - 10:20 AM

[K503-4am-08] Development of plate-CS method for molecular structure analysis

^○Yusuke Takata^1,2, Hideo Okumura³, Sota Sato¹, Makoto Fujita¹ (1. The Univ. of Tokyo, 2. SHIONOGI & CO., LTD., 3. JASRI)

[Lang.] English

Sessions

09. Coordination Chemistry, Organometallic Chemistry » Oral A

[K504-1pm] 09. Coordination Chemistry, Organometallic Chemistry

[K506-1pm] 09. Coordination Chemistry, Organometallic Chemistry

[K503-1pm] 09. Coordination Chemistry, Organometallic Chemistry

[K503-1vn] 09. Coordination Chemistry, Organometallic Chemistry

[K504-1vn] 09. Coordination Chemistry, Organometallic Chemistry

[K504-2am] 09. Coordination Chemistry, Organometallic Chemistry

[K503-2am] 09. Coordination Chemistry, Organometallic Chemistry

[K504-2pm] 09. Coordination Chemistry, Organometallic Chemistry

[K503-2pm] 09. Coordination Chemistry, Organometallic Chemistry

[K503-2vn] 09. Coordination Chemistry, Organometallic Chemistry